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Page 1
Redox properties of a mononuclear copper(II)-superoxide complex.
Tano T, Okubo Y, Kunishita A, Kubo M, Sugimoto H, Fujieda N, Ogura T, Itoh S. Tano T, et al. Inorg Chem. 2013 Sep 16;52(18):10431-7. doi: 10.1021/ic401261z. Epub 2013 Sep 5. Inorg Chem. 2013. PMID: 24004030
On the basis of the reactivity toward a series of one-electron reductants, the reduction potential of (L)Cu(II)-OO() was estimated to be 0.19 0.07 V vs SCE in acetone at 298 K (cf. Tahsini et al. Chem.-Eur. J. 2012, 18, 1084-1093). In the reaction of TEMPO-H (2,2,6, …
On the basis of the reactivity toward a series of one-electron reductants, the reduction potential of (L)Cu(II)-OO() was estimated to be 0.1 …
Synthesis, Characterization, and Spectroscopic Studies of 2,6-Dimethylpyridyl-Linked Cu(I)-CNC Complexes: The Electronic Influence of Aryl Wingtips on Copper Centers.
Minnick JL, Raincrow J, Meinders G, Latifi R, Tahsini L. Minnick JL, et al. Inorg Chem. 2023 Oct 2;62(39):15912-15926. doi: 10.1021/acs.inorgchem.3c01973. Epub 2023 Sep 16. Inorg Chem. 2023. PMID: 37715709
The fast monomer-dimer equilibrium of the Cu-CNC complexes at room temperature is reflected in their simple (1)H NMR spectra in acetonitrile. However, both mono- and binuclear forms were identifiable in (1)H diffusion-ordered spectroscopy (DOSY) at low temperatures. …
The fast monomer-dimer equilibrium of the Cu-CNC complexes at room temperature is reflected in their simple (1)H NMR spectra in aceto …
Oxidative properties of a nonheme Ni(II)(O2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation.
Latifi R, Tahsini L, Kumar D, Sastry GN, Nam W, de Visser SP. Latifi R, et al. Chem Commun (Camb). 2011 Oct 14;47(38):10674-6. doi: 10.1039/c1cc13993b. Epub 2011 Sep 2. Chem Commun (Camb). 2011. PMID: 21892444
Density functional theory calculations on the reactivity of a Ni(II)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(II)-superoxo complex is able to react with substrates with weak C-H bon …
Density functional theory calculations on the reactivity of a Ni(II)-superoxo complex in C-H bond activation, aromatic hydroxylation …
Storage-induced mechanical changes of porcine lenses assessed with optical coherence elastography and inverse finite element modeling.
Tahsini V, Gil IC, Kling S. Tahsini V, et al. Front Bioeng Biotechnol. 2024 Jun 13;12:1398659. doi: 10.3389/fbioe.2024.1398659. eCollection 2024. Front Bioeng Biotechnol. 2024. PMID: 38938986 Free PMC article.
In the first three groups, the lens within the intact eye was preserved for 24 h by: (i) freezing at -80C (n = 12), (ii) freezing at -20C (n = 12), and (iii) refrigeration at +8C (n = 12). In the remaining groups, the lenses were immediately extracted and treated as follow …
In the first three groups, the lens within the intact eye was preserved for 24 h by: (i) freezing at -80C (n = 12), (ii) freezing at …
Fundamental differences of substrate hydroxylation by high-valent iron(IV)-oxo models of cytochrome P450.
Tahsini L, Bagherzadeh M, Nam W, de Visser SP. Tahsini L, et al. Inorg Chem. 2009 Jul 20;48(14):6661-9. doi: 10.1021/ic900593c. Inorg Chem. 2009. PMID: 19469505
.; Kang, Y.; Han, A.-R.; Lee, Y.-M.; Kotani, H.; Fukuzumi, S.; Nam, W. Angew. Chem., Int. Ed. 2008, 47, 7321-7324]. By contrast, theoretical studies on camphor hydroxylation by these two oxidants concluded that the one-electron reduced form of Compound I is a sluggish oxid …
.; Kang, Y.; Han, A.-R.; Lee, Y.-M.; Kotani, H.; Fukuzumi, S.; Nam, W. Angew. Chem., Int. Ed. 2008, 47, 7321-7324]. By contrast, theo …
K⋅⋅⋅F/O interactions bridge copper(I) fluorinated alkoxide complexes and facilitate dioxygen activation.
Lum JS, Tahsini L, Golen JA, Moore C, Rheingold AL, Doerrer LH. Lum JS, et al. Chemistry. 2013 May 10;19(20):6374-84. doi: 10.1002/chem.201204275. Epub 2013 Mar 19. Chemistry. 2013. PMID: 23512253
Intramolecular hydroxylation of ligand aryl and alkyl C-H bonds is observed. Nucleophilic reactivity with CO2 is observed for the oxygenated Cu complexes and a Cu(II) carbonate has been isolated and characterized....
Intramolecular hydroxylation of ligand aryl and alkyl C-H bonds is observed. Nucleophilic reactivity with CO2 is observed for the oxy …
Synthesis, characterization, and photoluminescent studies of three-coordinate Cu(i)-NHC complexes bearing unsymmetrically-substituted dipyridylamine ligands.
Glinton K, Latifi R, Cockrell DS, Bardeaux M, Nguyen B, Tahsini L. Glinton K, et al. RSC Adv. 2019 Jul 19;9(39):22417-22427. doi: 10.1039/c9ra04886c. eCollection 2019 Jul 17. RSC Adv. 2019. PMID: 35519490 Free PMC article.
The complexes [Cu(IPr)(3,4'-Me(2)Hdpa)]PF(6), 1; [Cu(IPr)(3,5'-Me(2)Hdpa)]PF(6), 2; [Cu(IPr)(3,6'-Me(2)Hdpa)]PF(6), 3; [Cu(IPr)(mesBIAN)]PF(6), 6; [Cu(SIPr)(3,4'-Me(2)Hdpa)]PF(6), 7; [Cu(SIPr)(3,5'-Me(2)Hdpa)]PF(6), 8; and [Cu(SIPr)(3,3'-Me(2)Hdpa)]PF(6), 11 have been characteriz …
The complexes [Cu(IPr)(3,4'-Me(2)Hdpa)]PF(6), 1; [Cu(IPr)(3,5'-Me(2)Hdpa)]PF(6), 2; [Cu(IPr)(3,6'-Me(2)Hdpa)]PF(6), 3; [Cu(IPr)(mesBIAN)]PF( …
C-X (X = N, O) Cross-Coupling Reactions Catalyzed by Copper-Pincer Bis(N-Heterocyclic Carbene) Complexes.
Minnick JL, Domyati D, Ammons R, Tahsini L. Minnick JL, et al. Front Chem. 2019 Jan 31;7:12. doi: 10.3389/fchem.2019.00012. eCollection 2019. Front Chem. 2019. PMID: 30766865 Free PMC article.
With Cs(2)CO(3) and K(2)CO(3), the oxygen-generated catalyst is more reactive than the catalyst formed under argon in a short reaction time (12 h). However, the difference in reactivity is compromised after a 24 h reaction with K(2)CO(3). ...
With Cs(2)CO(3) and K(2)CO(3), the oxygen-generated catalyst is more reactive than the catalyst formed under argon in a short reaction time …
Manganese substituted Compound I of cytochrome P450 biomimetics: a comparative reactivity study of Mn(V)-oxo versus Mn(IV)-oxo species.
Latifi R, Tahsini L, Karamzadeh B, Safari N, Nam W, de Visser SP. Latifi R, et al. Arch Biochem Biophys. 2011 Mar 1;507(1):4-13. doi: 10.1016/j.abb.2010.12.035. Epub 2011 Jan 7. Arch Biochem Biophys. 2011. PMID: 21216220
Recent experimental studies [J.Y. Lee, Y.-M. Lee, H. Kotani, W. Nam, S. Fukuzumi, Chem. Commun. (2009) 704] showed that Mn(V)-oxo porphyrins react rapidly with 10-methyl-9,10-dihydroacridine (AcrH(2)) via a proton-coupled-electron-transfer followed by an electron transfer. …
Recent experimental studies [J.Y. Lee, Y.-M. Lee, H. Kotani, W. Nam, S. Fukuzumi, Chem. Commun. (2009) 704] showed that Mn(V)-oxo por …
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