Unexpected migratory insertion reactions of M(alkyl)2 (M=Zn, Cd) and diamidocarbenes.
Collins LR, Hierlmeier G, Mahon MF, Riddlestone IM, Whittlesey MK.
Collins LR, et al.
Chemistry. 2015 Feb 16;21(8):3215-8. doi: 10.1002/chem.201406406. Epub 2015 Jan 8.
Chemistry. 2015.
PMID: 25572627
Herein, we report that metal coordinated DACs also exhibit electrophilic reactivity, undergoing attack by Zn and Cd dialkyl precursors to afford the migratory insertion products [(6-MesDAC-R)MR] (M=Zn, Cd; R=Et, Me; Mes=mesityl). These species were formed via the spectrosc …
Herein, we report that metal coordinated DACs also exhibit electrophilic reactivity, undergoing attack by Zn and Cd dialkyl precursors to af …