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Refoldable Foldamers: Global Conformational Switching by Deletion or Insertion of a Single Hydrogen Bond.
Le Bailly BA, Byrne L, Clayden J. Le Bailly BA, et al. Angew Chem Int Ed Engl. 2016 Feb 5;55(6):2132-6. doi: 10.1002/anie.201510605. Epub 2016 Jan 14. Angew Chem Int Ed Engl. 2016. PMID: 26762559 Free PMC article.
We show that the simple insertion or deletion of a single hydrogen bond by changes in pH or by photochemical deprotection is sufficient to refold a helical oligomer, interconverting M and P screw-sense preference. As a consequence of the switch, information may be transmit …
We show that the simple insertion or deletion of a single hydrogen bond by changes in pH or by photochemical deprotection is sufficient to r …
Inducing a pH-dependent conformational response by competitive binding to Zn2+ of a series of chiral ligands of disparate basicity.
Wootten MM, Le Bailly BAF, Tshepelevitsh S, Leito I, Clayden J. Wootten MM, et al. Among authors: le bailly baf. Chem Sci. 2022 Jan 17;13(8):2258-2269. doi: 10.1039/d1sc06812a. eCollection 2022 Feb 23. Chem Sci. 2022. PMID: 35310487 Free PMC article.
The pH-dependent conformational response was used to transduce a signal by appending to the binding site a 2-aminoisobutyric acid (Aib) oligomer, whose M or P helical conformation depended on the chirality of the bound ligand, and was reported by a remote (13)C-labelled NM …
The pH-dependent conformational response was used to transduce a signal by appending to the binding site a 2-aminoisobutyric acid (Aib) olig …
Flaws in foldamers: conformational uniformity and signal decay in achiral helical peptide oligomers.
Le Bailly BAF, Byrne L, Diemer V, Foroozandeh M, Morris GA, Clayden J. Le Bailly BAF, et al. Chem Sci. 2015 Apr 1;6(4):2313-2322. doi: 10.1039/c4sc03944k. Epub 2015 Jan 21. Chem Sci. 2015. PMID: 29308146 Free PMC article.
This conformational signal is a perturbation of the racemic mixture of M and P helices that such oligomers typically adopt by the inclusion of an N or C terminal chiral inducer. ...
This conformational signal is a perturbation of the racemic mixture of M and P helices that such oligomers typically adopt by the inc …
Behavioral risks for West Nile virus disease, northern Colorado, 2003.
Gujral IB, Zielinski-Gutierrez EC, LeBailly A, Nasci R. Gujral IB, et al. Emerg Infect Dis. 2007 Mar;13(3):419-25. doi: 10.3201/eid1303.060941. Emerg Infect Dis. 2007. PMID: 17552095 Free PMC article.
After we adjusted for identified risk factors, Loveland residents were 39% more likely to report seldom or never using N,N-diethyl-m-toluamide (DEET), and approximately 30% were more likely to report being outdoors during prime mosquito-biting hours than Fort Collins resid …
After we adjusted for identified risk factors, Loveland residents were 39% more likely to report seldom or never using N,N-diethyl-m- …