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1971 1
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1alpha,25-dihydroxy-16-ene-23-yne-vitamin D3 and 1alpha,25-dihydroxy-16-ene-23-yne-20-epi-vitamin D3: analogs of 1alpha,25-dihydroxyvitamin D3 that resist metabolism through the C-24 oxidation pathway are metabolized through the C-3 epimerization pathway.
Reddy GS, Rao DS, Siu-Caldera ML, Astecker N, Weiskopf A, Vouros P, Sasso GJ, Manchand PS, Uskokovic MR. Reddy GS, et al. Among authors: manchand ps. Arch Biochem Biophys. 2000 Nov 15;383(2):197-205. doi: 10.1006/abbi.2000.2074. Arch Biochem Biophys. 2000. PMID: 11185554
Synthesis of vitamin A via sulfones: A C15 sulfone route.
Manchand PS, Rosenberger M, Saucy G, Wehrli PA, Wong H, Chambers L, Ferro MP, Jackson W. Manchand PS, et al. Helv Chim Acta. 1976 Mar 10;59(2):387-96. doi: 10.1002/hlca.19760590207. Helv Chim Acta. 1976. PMID: 1254496 No abstract available.