In this research, novel heterogeneous cation exchange membranes based on thermoplastic polyurethane (TPU) have been prepared by the solution casting technique. The effects of incorporation level of sulfonated polystyrene divinyl-benzene (PSS/DVB) resin on water uptake, ion exchange capacity, membrane potential and salt extraction have been elucidated. Morphological and water uptake studies suggested a two-phase heterogeneous membrane morphology owing to the presence of hard and soft segments in the TPU backbone and swelling of PSS/DVB particles. This morphology was shifted to a semi-gelled morphology throughout the membrane bulk when resin loading exceeded 50 wt%. The physically cross-linked hard segments in the TPU backbone ensured a compact membrane morphology and prevented the formation of water channels. The membrane potential showed that increasing the resin content increased the membrane transport number (max. 0.95) up to 50 wt% resin loading and beyond this, the transport number started decreasing showing a pronounced effect of voids and water flow channels developing on excessive swelling. The permselectivity reached a maximum (up to 0.92) and salt extraction values also increased (by varying voltage) up to 50 wt% loading and started decreasing beyond this optimum content. This study shows successful development of low-cost heterogeneous cation exchange membranes based on TPU with acceptable electrochemical properties.
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