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Page 1
Adsorption of acrolein and its hydrogenation products on Cu(111).
Islam A, Molina DL, Trenary M. Islam A, et al. Phys Chem Chem Phys. 2022 Oct 12;24(39):24383-24393. doi: 10.1039/d2cp03817j. Phys Chem Chem Phys. 2022. PMID: 36184973
Upon annealing to 160 K, the OH stretches of both 2-propenol and 1-propanol disappear, indicating the hydrogen bonding in the multilayers is not present in the monolayers. For 2-propenol, the hydrogen bonding in the multilayer correlates with the observation of the …
Upon annealing to 160 K, the OH stretches of both 2-propenol and 1-propanol disappear, indicating the hydrogen bonding in the multila …
Infrared Spectra of Gas-Phase 1- and 2-Propenol Isomers.
Shaw MF, Osborn DL, Jordan MJT, Kable SH. Shaw MF, et al. J Phys Chem A. 2017 May 18;121(19):3679-3688. doi: 10.1021/acs.jpca.7b02323. Epub 2017 May 5. J Phys Chem A. 2017. PMID: 28436675
Fourier transform infrared spectra of isolated 1-propenol and 2-propenol in the gas-phase have been collected in the range of 900-3800 cm(-1), and the absolute infrared absorption cross sections reported for the first time. ...Electronic structure calculations were …
Fourier transform infrared spectra of isolated 1-propenol and 2-propenol in the gas-phase have been collected in the range of …
Adsorption properties of acrolein, propanal, 2-propenol, and 1-propanol on Ag(111).
Muir M , Molina DL , Islam A , Abdel-Rahman MK , Trenary M . Muir M , et al. Phys Chem Chem Phys. 2020 Nov 21;22(43):25011-25020. doi: 10.1039/d0cp04634e. Epub 2020 Oct 28. Phys Chem Chem Phys. 2020. PMID: 33112308
This suggests that 1-propanol forms a highly orderded monolayer and adsorbs as a single conformer. For 2-propenol, hydrogen bonding in the multilayer correlates with observation of the C[double bond, length as m-dash]C stretch at 1646 cm(-1), which is invisible for the mon …
This suggests that 1-propanol forms a highly orderded monolayer and adsorbs as a single conformer. For 2-propenol, hydrogen bonding i …
Sulfur-containing compounds from Clinacanthus siamensis.
Tuntiwachwuttikul P, Pootaeng-on Y, Pansa P, Srisanpang T, Taylor WC. Tuntiwachwuttikul P, et al. Chem Pharm Bull (Tokyo). 2003 Dec;51(12):1423-5. doi: 10.1248/cpb.51.1423. Chem Pharm Bull (Tokyo). 2003. PMID: 14646322 Free article.
Two new sulfur-containing compounds, trans-3-methylsulfonyl-2-propenol (1) and trans-3-methylsulfinyl-2-propenol (2) were isolated together with trans-3-methylthioacrylamide (3), entadamide A (4) and entadamide C (5) from the leaves of Clinacanthus siamensis. ...
Two new sulfur-containing compounds, trans-3-methylsulfonyl-2-propenol (1) and trans-3-methylsulfinyl-2-propenol (2) were isol …
Synthesis of sulfonyl 2-aryl-5-methylenyltetrahydropyrans.
Chang MY, Chen KT. Chang MY, et al. RSC Adv. 2023 Oct 13;13(43):29894-29903. doi: 10.1039/d3ra06370d. eCollection 2023 Oct 11. RSC Adv. 2023. PMID: 37842677 Free PMC article.
In this study, the present research describes a high-yield method for the synthesis of sulfonyl 2-aryl-5-methylenetetrahydropyrans by one-pot straightforward DABCO-promoted intramolecular Michael addition of beta-sulfonyl styrene with 2-chloromethyl-1-propenol followed by …
In this study, the present research describes a high-yield method for the synthesis of sulfonyl 2-aryl-5-methylenetetrahydropyrans by one-po …
Surface chemistry of propanal, 2-propenol, and 1-propanol on Ru(001).
Esan DA, Trenary M. Esan DA, et al. Phys Chem Chem Phys. 2017 May 3;19(17):10870-10877. doi: 10.1039/c6cp08893g. Phys Chem Chem Phys. 2017. PMID: 28327733
Adsorption and thermal chemistry of propanal, 2-propenol, and 1-propanol on Ru(001) were studied using temperature programmed reaction spectroscopy (TPRS) and reflection absorption infrared spectroscopy (RAIRS). The results show that each molecule adsorbs molecularly at 90 …
Adsorption and thermal chemistry of propanal, 2-propenol, and 1-propanol on Ru(001) were studied using temperature programmed reactio …
Unraveling the electrocatalytic reduction mechanism of enols on copper in aqueous media.
Cui Z, Dong X, Cho SG, Tegomoh MN, Dai W, Dong F, Co AC. Cui Z, et al. Nat Commun. 2022 Oct 3;13(1):5840. doi: 10.1038/s41467-022-33620-2. Nat Commun. 2022. PMID: 36192409 Free PMC article.
In this manuscript, direct electrochemical conversion of vinyl alcohol and acetaldehyde on polycrystalline Cu to ethanol, ethylene and ethane; and propenol and propionaldehyde to propanol, propene and propane is reported. Sensitive detection was achieved using a rotating d …
In this manuscript, direct electrochemical conversion of vinyl alcohol and acetaldehyde on polycrystalline Cu to ethanol, ethylene and ethan …
Selective Hydrogenation of Acrolein Over Pd Model Catalysts: Temperature and Particle-Size Effects.
O'Brien CP, Dostert KH, Schauermann S, Freund HJ. O'Brien CP, et al. Chemistry. 2016 Oct 24;22(44):15856-15863. doi: 10.1002/chem.201602021. Epub 2016 Sep 13. Chemistry. 2016. PMID: 27621113
While Pd(111) shows nearly 100 % selectivity towards the desired hydrogenation of the C=O bond to produce propenol, Pd nanoparticles were found to be much less selective towards this product. In situ detection of surface species by using IR-reflection absorption spectrosco …
While Pd(111) shows nearly 100 % selectivity towards the desired hydrogenation of the C=O bond to produce propenol, Pd nanoparticles …
The photochemistry of 4-chlorophenol in water revisited: the effect of cyclodextrins on cation and carbene reactions.
Manet I, Monti S, Bortolus P, Fagnoni M, Albini A. Manet I, et al. Chemistry. 2005 Jul 4;11(14):4274-82. doi: 10.1002/chem.200401227. Chemistry. 2005. PMID: 15861376
Specific trapping of both intermediates has been achieved. The cation adds to 2-propenol, k(add) approximately 1.3 x 10(8) m(-1) s(-1), to form the long-lived phenonium ion 11 (with lambda(max) = 290 nm), which then converts to 3-(4-hydroxyphenyl)propane-1,2-diol (10). ... …
Specific trapping of both intermediates has been achieved. The cation adds to 2-propenol, k(add) approximately 1.3 x 10(8) m(-1) s(-1 …
Chemiluminescent determination of esterases in monocytes.
da Fonseca LM, Yavo B, Catalani LH, Falcão RP, Brunetti IL, Campa A. da Fonseca LM, et al. J Biolumin Chemilumin. 1998 Jul-Aug;13(4):195-200. doi: 10.1002/(SICI)1099-1271(199807/08)13:4<195::AID-BIO497>3.0.CO;2-P. J Biolumin Chemilumin. 1998. PMID: 9743443
Esterase from monocytes promotes the hydrolysis of 2-methyl-1-propenylbenzoate (MPB) yielding 2-methyl-1-propenol, which is oxidized by horseradish peroxidase/H2O2 producing triplet acetone. The chemiluminescence of this reaction can be enhanced by the addition of 9,10-dib …
Esterase from monocytes promotes the hydrolysis of 2-methyl-1-propenylbenzoate (MPB) yielding 2-methyl-1-propenol, which is oxidized …
45 results