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Quoted phrase not found in phrase index: "sevoflurane related compound C"
Page 1
Difunctionalization Processes Enabled by Hexafluoroisopropanol.
Piejko M, Moran J, Lebœuf D. Piejko M, et al. ACS Org Inorg Au. 2024 Mar 4;4(3):287-300. doi: 10.1021/acsorginorgau.3c00067. eCollection 2024 Jun 5. ACS Org Inorg Au. 2024. PMID: 38855339 Free PMC article. Review.
In the past 5 years, hexafluoroisopropanol (HFIP) has been used as a unique solvent or additive to enable challenging transformations through substrate activation and stabilization of reactive intermediates. ...
In the past 5 years, hexafluoroisopropanol (HFIP) has been used as a unique solvent or additive to enable challenging transformations …
Generation of Magnesium Pentafluoropropen-2-olate from Hexafluoroisopropanol and Synthesis of 2,2,4,4,4-Pentafluoro-3,3-dihydroxyketones.
Hazlitt RA, Tran QL, Sowaileh MF, Colby DA. Hazlitt RA, et al. J Org Chem. 2017 Feb 17;82(4):2231-2236. doi: 10.1021/acs.joc.6b02863. Epub 2017 Jan 31. J Org Chem. 2017. PMID: 28107014 Free PMC article.
Specifically, aldehydes are treated with pentafluoropropen-2-olate, generated from a new fragmentation of hexafluoroisopropanol with a mixed Mg/Li amide, to give pentafluoroalcohols. A subsequent oxidation with Dess-Martin periodinane provides the targets in good isolated …
Specifically, aldehydes are treated with pentafluoropropen-2-olate, generated from a new fragmentation of hexafluoroisopropanol with …
Solvent-dependent formation kinetics of L,L-diphenylalanine micro/nanotubes.
Bandeira CCS, Foiani LMC, Carlos GB, Ishikawa MS, Ferreira PMGL, da Silva Martinho H. Bandeira CCS, et al. Phys Chem Chem Phys. 2023 Feb 8;25(6):5107-5113. doi: 10.1039/d2cp03491c. Phys Chem Chem Phys. 2023. PMID: 36722992
Our results indicated that the self-assembly in this case competes with the water evaporation process contrary to what is reported by samples prepared with widely used solvent 1,1,1,3,3,3-hexafluoro-2-propanol. We note that exclusi …
Our results indicated that the self-assembly in this case competes with the water evaporation process contrary to what is reported by sample …
Intramolecular Friedel-Crafts Acylation Reaction Promoted by 1,1,1,3,3,3-Hexafluoro-2-propanol.
Motiwala HF, Vekariya RH, Aubé J. Motiwala HF, et al. Org Lett. 2015 Nov 6;17(21):5484-7. doi: 10.1021/acs.orglett.5b02851. Epub 2015 Oct 23. Org Lett. 2015. PMID: 26496158
Simple dissolution of an arylalkyl acid chloride in 1,1,1,3,3,3-hexafluoro-2-propanol promotes an intramolecular Friedel-Crafts acylation without additional catalysts or reagents. ...
Simple dissolution of an arylalkyl acid chloride in 1,1,1,3,3,3-hexafluoro-2-propanol promo …
Trp-cage-1,1,1,3,3,3-Hexafluoro-2-propanol-Water Interactions in a Nanosphere at 298 K.
Gerig JT. Gerig JT. J Phys Chem B. 2024 Sep 26;128(38):9094-9101. doi: 10.1021/acs.jpcb.4c03707. Epub 2024 Sep 17. J Phys Chem B. 2024. PMID: 39288008 Free PMC article.
MD simulations of the peptide Trp-cage dissolved in a solvent composed of 28% 1,1,1,3,3,3-hexafluoroisopropanol-water and contained within a nanosphere of 4.2 nm radius are described. ...
MD simulations of the peptide Trp-cage dissolved in a solvent composed of 28% 1,1,1,3,3,3-hexafluoroisopropanol-water and contained w …
Hexafluoro-2-propanol represses colorectal cancer proliferation by regulating transaminases.
Shao Z, Sun L, Lin W. Shao Z, et al. Acta Biochim Pol. 2023 Feb 23;70(1):145-152. doi: 10.18388/abp.2020_6367. Acta Biochim Pol. 2023. PMID: 36821417 Free article.
Hexafluoro-2-propanol (HFIP) is a metabolite of sevoflurane used as part of the general anaesthesia technique. ...
Hexafluoro-2-propanol (HFIP) is a metabolite of sevoflurane used as part of the general anaesthesia technique. ...
Synthesis of Indoline- and 1,2,3,4-Tetrahydroquinoline-Based Symmetrical Triarylmethanes.
Taskesenligil Y, Aslan M, Ardahanli R, Saracoglu N. Taskesenligil Y, et al. J Org Chem. 2025 Jul 18;90(28):9954-9964. doi: 10.1021/acs.joc.5c00960. Epub 2025 Jul 6. J Org Chem. 2025. PMID: 40619676 Free PMC article.
We present a novel and efficient, metal-free methodology for the regioselective synthesis of symmetrical triarylmethanes through C-H alkylation of indolines and 1,2,3,4-tetrahydroquinolines with aryl aldehydes. The transformation employs 1,1,1,3,3,3- …
We present a novel and efficient, metal-free methodology for the regioselective synthesis of symmetrical triarylmethanes through C-H alkylat …
Biotransformation of sevoflurane by rat neonate liver slices.
Payne AK, Morgan SE, Gandolfi AJ, Brendel K. Payne AK, et al. Drug Metab Dispos. 1995 Apr;23(4):497-500. Drug Metab Dispos. 1995. PMID: 7600918
Although no hexafluoroisopropanol-glucuronide was generated by slices from 4-, 6-, and 8-day-old neonates, by day 21, 17% of the total hexafluoroisopropanol is glucuronidated. This contrasts with the lower levels of free hexafluoroisopropanol typically seen i …
Although no hexafluoroisopropanol-glucuronide was generated by slices from 4-, 6-, and 8-day-old neonates, by day 21, 17% of the tota …
Aromatic C-H amination in hexafluoroisopropanol.
D'Amato EM, Börgel J, Ritter T. D'Amato EM, et al. Chem Sci. 2019 Jan 11;10(8):2424-2428. doi: 10.1039/c8sc04966a. eCollection 2019 Feb 28. Chem Sci. 2019. PMID: 30881670 Free PMC article.
Hydrogen bonding by the solvent hexafluoroisopropanol to anions of cationic species is responsible for increased reactivity and can rationalize the enhancement in substrate scope. ...
Hydrogen bonding by the solvent hexafluoroisopropanol to anions of cationic species is responsible for increased reactivity and can r …
1,281 results