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Quoted phrase not found in phrase index: "1,2,3,4,5,6-hexafluorobenzene"
Page 1
N-Heterocyclic Carbenes with Polyfluorinated Groups at the 4- and 5-Positions from [3 + 2] Cycloadditions between Formamidinates and cis-1,2-Difluoroalkene Derivatives.
Ohashi M, Ando K, Murakami S, Michigami K, Ogoshi S. Ohashi M, et al. J Am Chem Soc. 2023 Oct 25;145(42):23098-23108. doi: 10.1021/jacs.3c06331. Epub 2023 Sep 25. J Am Chem Soc. 2023. PMID: 37749910
Thus, employing octafluorocyclopentene and hexafluorobenzene led to the formation of 4,4,5,5,6,6-hexafluoro-1,3-diaryl-3,4,5,6-tetrahydrocyclopenta[d]imidazolium (CypIPr(F).HBF(4)) and 4,5,6,7-tetrafluoro-1,3-diarylbenzimidazolium (BIPr(F).HBF(4)) salts, respectively. ...
Thus, employing octafluorocyclopentene and hexafluorobenzene led to the formation of 4,4,5,5,6,6-hexafluoro-1,3-diaryl-3,4,5,6-tetrah …
Reversible CO2 activation by a N-phosphinoamidinato digermyne.
Fan J, Quek S, Yang MC, Zhang ZF, Su MD, So CW. Fan J, et al. Chem Commun (Camb). 2022 Jan 20;58(7):1033-1036. doi: 10.1039/d1cc05391d. Chem Commun (Camb). 2022. PMID: 34951421
Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO(2), [LG eC(Ph) = C(Ph) G eL] (8), [LG eF] (9) and [LG eC(6)F(5)] (10), respectively....
Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to …
Progressive Hydrophobicity of Fluorobenzenes.
Kumar A, Mahato J, Dixit M, Patwari GN. Kumar A, et al. J Phys Chem B. 2019 Nov 27;123(47):10083-10088. doi: 10.1021/acs.jpcb.9b08057. Epub 2019 Nov 18. J Phys Chem B. 2019. PMID: 31661279
The potentials of mean force for the dimers of fluorobenzenes sample both pi-stacked and T-shaped structures for partially fluorinated benzenes, namely, 1,4-difluorobenzene, 1,3,5-trifluorobenzene, and 1,2,4,5-tetrafluorobenzene, and sample only the T-shaped structures for benzen …
The potentials of mean force for the dimers of fluorobenzenes sample both pi-stacked and T-shaped structures for partially fluorinated benze …
19F Oximetry with semifluorinated alkanes.
Kegel S, Chacon-Caldera J, Tsagogiorgas C, Theisinger B, Glatting G, Schad LR. Kegel S, et al. Artif Cells Nanomed Biotechnol. 2016 Dec;44(8):1861-1866. doi: 10.3109/21691401.2015.1111228. Epub 2015 Dec 2. Artif Cells Nanomed Biotechnol. 2016. PMID: 26631543 Free article.
Hexafluorobenzene under Extreme Conditions.
Pravica M, Sneed D, Wang Y, Smith Q, White M. Pravica M, et al. J Phys Chem B. 2016 Mar 17;120(10):2854-8. doi: 10.1021/acs.jpcb.6b00497. Epub 2016 Mar 8. J Phys Chem B. 2016. PMID: 26910443
We report the results from three high pressure experiments on hexafluorobenzene (C6F6). In the first experiment, Raman spectra were recorded up to 34.4 GPa. ...
We report the results from three high pressure experiments on hexafluorobenzene (C6F6). In the first experiment, Raman spectra were r …
Photochemical mechanistic study of hexafluorobenzene involving the low-lying states.
Li D, Song X, Liu J, Zhang S. Li D, et al. Phys Chem Chem Phys. 2024 Feb 22;26(8):6638-6645. doi: 10.1039/d3cp04184k. Phys Chem Chem Phys. 2024. PMID: 38221873
The photochemical isomerization and nonradiative decay processes of hexafluorobenzene (HFB) were investigated theoretically to gain insights into its photochemical mechanism and the perfluoro effect. ...
The photochemical isomerization and nonradiative decay processes of hexafluorobenzene (HFB) were investigated theoretically to gain i …
Intermolecular π-π Stacking Interactions Made Visible.
Timmer BJJ, Mooibroek TJ. Timmer BJJ, et al. J Chem Educ. 2021 Feb 9;98(2):540-545. doi: 10.1021/acs.jchemed.0c01252. Epub 2020 Dec 4. J Chem Educ. 2021. PMID: 33583952 Free PMC article.
Mixing the liquids hexafluorobenzene (1) and 1,3,5-trimethylbenzene (mesitylene, 2) results in a crystalline solid with a melting point of 34 C. ...
Mixing the liquids hexafluorobenzene (1) and 1,3,5-trimethylbenzene (mesitylene, 2) results in a crystalline solid with a melting poi …
On the hydrolysis of diethyl 2-(perfluorophenyl)malonate.
Taydakov IV, Kiskin MA. Taydakov IV, et al. Beilstein J Org Chem. 2020 Jul 28;16:1863-1868. doi: 10.3762/bjoc.16.153. eCollection 2020. Beilstein J Org Chem. 2020. PMID: 32802203 Free PMC article.
Diethyl 2-(perfluorophenyl)malonate was synthesized in 47% isolated yield by the reaction of sodium diethyl malonate and hexafluorobenzene. The resulting compound was considered as a starting material for synthesizing 2-(perfluorophenyl)malonic acid by hydrolysis. ...
Diethyl 2-(perfluorophenyl)malonate was synthesized in 47% isolated yield by the reaction of sodium diethyl malonate and hexafluorobenzen …
Anion Photoelectron Imaging Spectroscopy of C6HF5-, C6F6-, and the Absence of C6H2F4.
McGee CJ, McGinnis KR, Jarrold CC. McGee CJ, et al. J Phys Chem A. 2023 Oct 19;127(41):8556-8565. doi: 10.1021/acs.jpca.3c04016. Epub 2023 Oct 10. J Phys Chem A. 2023. PMID: 37816145
Chem. 2017, 188, e25504] that pentafluorobenzene has a positive electron affinity, as hexafluorobenzene was already known to have. The PE spectrum of C(6)HF(5)(-) exhibits a broad and vibrationally unresolved band due to significant differences between the structure of the …
Chem. 2017, 188, e25504] that pentafluorobenzene has a positive electron affinity, as hexafluorobenzene was already known to have. Th …
Anion-π interactions suppress phase impurities in FAPbI3 solar cells.
Huang Z, Bai Y, Huang X, Li J, Wu Y, Chen Y, Li K, Niu X, Li N, Liu G, Zhang Y, Zai H, Chen Q, Lei T, Wang L, Zhou H. Huang Z, et al. Nature. 2023 Nov;623(7987):531-537. doi: 10.1038/s41586-023-06637-w. Epub 2023 Oct 18. Nature. 2023. PMID: 37853122
Herein, we demonstrate an alternative approach to modulate reaction kinetics by anion-pi interaction between AX and hexafluorobenzene (HFB). Notably, these two approaches are independent but work together to establish 'dual-site regulation', which achieves a delicate contr …
Herein, we demonstrate an alternative approach to modulate reaction kinetics by anion-pi interaction between AX and hexafluorobenzene …
314 results