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Oxidation of benzene to phenol, catechol, and 1,2,3-trihydroxybenzene by toluene 4-monooxygenase of Pseudomonas mendocina KR1 and toluene 3-monooxygenase of Ralstonia pickettii PKO1.
Tao Y, Fishman A, Bentley WE, Wood TK. Tao Y, et al. Appl Environ Microbiol. 2004 Jul;70(7):3814-20. doi: 10.1128/AEM.70.7.3814-3820.2004. Appl Environ Microbiol. 2004. PMID: 15240250 Free PMC article.
The catechol and 1,2,3-trihydroxybenzene products were identified by both high-pressure liquid chromatography and mass spectrometry. When analogous plasmid constructs were used, E. coli TG1/pBS(Kan)T3MO expressing T3MO formed phenol, catechol, and 1 …
The catechol and 1,2,3-trihydroxybenzene products were identified by both high-pressure liquid chromatography an …
Unexpected Mechanism of Biodegradation and Defluorination of 2,2-Difluoro-1,3-Benzodioxole by Pseudomonas putida F1.
Bygd MD, Aukema KG, Richman JE, Wackett LP. Bygd MD, et al. mBio. 2021 Dec 21;12(6):e0300121. doi: 10.1128/mBio.03001-21. Epub 2021 Nov 16. mBio. 2021. PMID: 34781746 Free PMC article.
The major route of DFBD-4,5-dihydrodiol decomposition produced fluoride and 1,2,3-trihydroxybenzene, or pyrogallol, and that was shown to be the source of the dark colors in the medium. ...
The major route of DFBD-4,5-dihydrodiol decomposition produced fluoride and 1,2,3-trihydroxybenzene, or pyrogall …
Pyrogallol protects against influenza A virus-triggered lethal lung injury by activating the Nrf2-PPAR-γ-HO-1 signaling axis.
Zhou B, Wang L, Yang S, Liang Y, Zhang Y, Liu X, Pan X, Li J. Zhou B, et al. MedComm (2020). 2024 Apr 12;5(4):e531. doi: 10.1002/mco2.531. eCollection 2024 Apr. MedComm (2020). 2024. PMID: 38617435 Free PMC article.
Pyrogallol, a natural polyphenol compound (1,2,3-trihydroxybenzene), has shown efficacy in the therapeutic treatment of disorders associated with inflammation. ...
Pyrogallol, a natural polyphenol compound (1,2,3-trihydroxybenzene), has shown efficacy in the therapeutic treat …
[Synthesis and characterization of the oxidation product of the 1, 2, 3-trihydroxybenzene and its metallic complexes].
Yang R, Cai J, Sun Y, Zhang H. Yang R, et al. Guang Pu Xue Yu Guang Pu Fen Xi. 2000 Oct;20(5):645-7. Guang Pu Xue Yu Guang Pu Fen Xi. 2000. PMID: 12945404 Chinese.
The oxidation reaction mechanism of the 1,2,3-trihydroxybenzene was studied by the Ab initio calculation of the quantum chemistry. The derivative of the hydrazine and THBO(the reaction product of the 1,2,3-trihydroxybenzene …
The oxidation reaction mechanism of the 1,2,3-trihydroxybenzene was studied by the Ab initio calculation of the …
Multifunctional 5-hydroxyconiferaldehyde O-methyltransferases (CAldOMTs) in plant metabolism.
Lam LPY, Lui ACW, Bartley LE, Mikami B, Umezawa T, Lo C. Lam LPY, et al. J Exp Bot. 2024 Mar 14;75(6):1671-1695. doi: 10.1093/jxb/erae011. J Exp Bot. 2024. PMID: 38198655 Review.
Furthermore, neofunctionalization of CAldOMTs occurred repeatedly during evolution, generating unique O-methyltransferases (OMTs) with novel catalytic activities and/or accepting novel substrates, including lignans, 1,2,3-trihydroxybenzene, and phenylp …
Furthermore, neofunctionalization of CAldOMTs occurred repeatedly during evolution, generating unique O-methyltransferases (OMTs) with novel …
Multiple activation pathways of benzene leading to products with varying genotoxic characteristics.
Glatt H, Padykula R, Berchtold GA, Ludewig G, Platt KL, Klein J, Oesch F. Glatt H, et al. Environ Health Perspect. 1989 Jul;82:81-9. doi: 10.1289/ehp.898281. Environ Health Perspect. 1989. PMID: 2676505 Free PMC article. Review.
However, other potential benzene metabolites showed genotoxic effects in V79 cells, as well: sister chromatid exchange was induced by the syn-diol epoxide, 1,2,4-trihydroxybenzene, hydroquinone, catechol, and 1,2,3-trihydroxybenzene. Elevated frequenci …
However, other potential benzene metabolites showed genotoxic effects in V79 cells, as well: sister chromatid exchange was induced by the sy …
Rapid acyl migration between pyrogallyl 1,2- and 1,3-dipivaloates.
Shan Y, Liu J, Rath NP, Gokel GW. Shan Y, et al. Nat Prod Commun. 2012 Mar;7(3):333-6. Nat Prod Commun. 2012. PMID: 22545406
Pyrogallol[4]arenes are tetrameric macrocycles that form from 1,2,3-trihydroxybenzene and aldehydes under acidic conditions. Pyrogallol was treated with two equivalents of pivaloyl chloride to form pyrogallyl dipivaloate. ...
Pyrogallol[4]arenes are tetrameric macrocycles that form from 1,2,3-trihydroxybenzene and aldehydes under acidic …
Dual magnetic behavior of an Fe(III)-dioxolene complex with tri-substituted catechol.
Chegerev MG, Demidov OP, Kubrin SP, Vasiliev PN, Efimov NN, Yue LT, Piskunov AV, Arsenyev MV, Starikova AA. Chegerev MG, et al. Dalton Trans. 2025 May 6;54(18):7434-7448. doi: 10.1039/d5dt00437c. Dalton Trans. 2025. PMID: 40223784
Synthesis and comprehensive characterization of a family of ionic ferric-dioxolene complexes [(TPA)Fe(HO-DBCat)]ClO(4) (1), [(TPA)Fe(NO(2)-DBCat)]ClO(4) (2) and [(TPA)Fe(MeOCH(2)-DBCat)]ClO(4) (3) (TPA = tris(2-pyridylmethyl)amine; HO-DBCat = dianion of 4,6-di-tert-butyl-1 …
Synthesis and comprehensive characterization of a family of ionic ferric-dioxolene complexes [(TPA)Fe(HO-DBCat)]ClO(4) (1), [(TPA)Fe(NO(2)-D …
Bioavailability of mango (poly)phenols: An evaluation of the impact of the colon, and phenylalanine and tyrosine on the production of phenolic catabolites.
Cáceres-Jiménez S, Pereira-Caro G, Dobani S, Pourshahidi K, Gill CIR, Moreno-Rojas JM, Ordoñez-Díaz JL, Almutairi TM, Clifford MN, Crozier A. Cáceres-Jiménez S, et al. Free Radic Biol Med. 2024 Nov 20;225:605-616. doi: 10.1016/j.freeradbiomed.2024.10.289. Epub 2024 Oct 18. Free Radic Biol Med. 2024. PMID: 39426756 Clinical Trial.
This indicates that a portion of these phenolics, including the hydroxybenzene derivatives, originate from substrates absorbed in the upper GI tract and are principally products of endogenous metabolism rather than being derived from colonic microbiota-mediated catabolism. 1 …
This indicates that a portion of these phenolics, including the hydroxybenzene derivatives, originate from substrates absorbed in the upper …
Hydrogen peroxide scavenging, antioxidant and anti-radical activity of some phenolic acids.
Sroka Z, Cisowski W. Sroka Z, et al. Food Chem Toxicol. 2003 Jun;41(6):753-8. doi: 10.1016/s0278-6915(02)00329-0. Food Chem Toxicol. 2003. PMID: 12738180
The strongest antioxidant, scavenging of H(2)O(2) and DPPH(*) radical activity was exhibited by 3,4,5-trihydroxybenzoic (gallic) acid and 1,2,3-trihydroxybenzene (pyrogallol) with three hydroxyl groups bonded to the aromatic ring in an ortho position i …
The strongest antioxidant, scavenging of H(2)O(2) and DPPH(*) radical activity was exhibited by 3,4,5-trihydroxybenzoic (gallic) acid and …
53 results