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Quoted phrases not found in phrase index: "1,2-dimethyloxyethane", "2,5-dioxahexane", "dimethyl cellosolve", "ethyleneglycol dimethyl ether"
Page 1
Bis-(di-meth-oxy-ethane-1κ2O,O')penta-kis-(1,1,1,3,3,3-hexa-fluoro-propan-2-olato)-2κ3O,3κ2O-μ-hy-droxido-1:3κ2O-μ3-oxido-1:2:3κ3O-magnesiumdialuminium.
Lozinšek M, Pavčnik T, Bitenc J. Lozinšek M, et al. IUCrdata. 2023 Sep 8;8(Pt 9):x230716. doi: 10.1107/S2414314623007162. eCollection 2023 Sep. IUCrdata. 2023. PMID: 37818472 Free PMC article.
Partial hydrolysis of a sample of [Mg(dme)(3)][Al(hfip)(4)](2) crystals led to the formation of the title complex, [Mg(dme)(2){HOAl(hfip)(2)OAl(hfip)(3)}] (dme = di-meth-oxy-ethane and hfipH = hexa-fluoro-iso-propanol) or [Mg(C(4)H(10)O(2))(2)O(OH)Al(2)(C(3)H …
Partial hydrolysis of a sample of [Mg(dme)(3)][Al(hfip)(4)](2) crystals led to the formation of the title complex, [Mg(dme)(2) …
(mu-1,2-dimethoxyethane-kappa2O:O')bis[(1,2-dimethoxyethane-kappa2O,O')tris(1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olato-kappa2O,O')cerium(III)].
Fatila EM, Jennings MC, Lough A, Preuss KE. Fatila EM, et al. Acta Crystallogr C. 2012 Apr;68(Pt 4):m100-3. doi: 10.1107/S0108270112010402. Epub 2012 Mar 14. Acta Crystallogr C. 2012. PMID: 22476137
Dalton Trans. 41, 1352-1362] of the title complex, [Ce(2)(C(5)HF(6)O(2))(6)(C(4)H(10)O(2))(3)], had identified it as Ce(hfac)(3)(dme)(1.5) according to the (1)H NMR integration [hfac = 1,1,1,5,5,5-hexafluoroacetylacetonate (1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate) an …
Dalton Trans. 41, 1352-1362] of the title complex, [Ce(2)(C(5)HF(6)O(2))(6)(C(4)H(10)O(2))(3)], had identified it as Ce(hfac)(3)(dme) …
Bis(1,2-dimethoxyethane)-1kappa(2)O,O';3kappa(2)O,O'-tetra-kis-(mu-1,1,1,3,3,3-hexa-fluoro-2-methyl-propan-2-olato)-1:2kappa(4)O:O;2:3kappa(4)O:O-1,3-dilithium-2-magnesium.
Wurst K, Buchmeiser MR. Wurst K, et al. Acta Crystallogr Sect E Struct Rep Online. 2012 Aug 1;68(Pt 8):m1106. doi: 10.1107/S1600536812032679. Epub 2012 Jul 25. Acta Crystallogr Sect E Struct Rep Online. 2012. PMID: 22904761 Free PMC article.
The title compound, [Li(2)Mg(C(4)H(3)F(6)O)(4)(C(4)H(10)O(2))(2)], forms as a white crystalline powder by-product of the reaction of lithium 1,1,1,3,3,3-hexa-fluoro-2-methyl-2-propoxide with Mo(N-2,6-Me(2)-C(6)H(3))(CHCMe(2)Ph)(O(3)SCF(3))(2).2DME (DME is 1,2 …
The title compound, [Li(2)Mg(C(4)H(3)F(6)O)(4)(C(4)H(10)O(2))(2)], forms as a white crystalline powder by-product of the reaction of lithium …
Analysis of Cooperativity and Group Additivity in the Hydration of 1,2-Dimethoxyethane.
Utiramerur S, Paulaitis M. Utiramerur S, et al. J Phys Chem B. 2021 Feb 18;125(6):1660-1666. doi: 10.1021/acs.jpcb.0c10729. Epub 2021 Feb 5. J Phys Chem B. 2021. PMID: 33545001
We calculate hydration free energies of 1,2-dimethoxyethane (DME) conformations in water at 298 K and 1 bar. We find that the preference for the two most abundant tgt and tgg conformations derives from favorable nonspecific (i.e., long-range) solute-wa …
We calculate hydration free energies of 1,2-dimethoxyethane (DME) conformations in water at 298 K and 1 bar. We …
Carbene Complexes of Neptunium.
Goodwin CAP, Wooles AJ, Murillo J, Lu E, Boronski JT, Scott BL, Gaunt AJ, Liddle ST. Goodwin CAP, et al. J Am Chem Soc. 2022 Jun 8;144(22):9764-9774. doi: 10.1021/jacs.2c02152. Epub 2022 May 24. J Am Chem Soc. 2022. PMID: 35609882 Free PMC article.
Separate treatment of in situ prepared 3Np with benzyl potassium in 1,2-dimethoxyethane (DME) affords [(BIPM(TMS))Np(III)(I)(DME)] (5Np, BIPM(TMS) = {C(PPh(2)NSiMe(3))(2)}(2-)). ...
Separate treatment of in situ prepared 3Np with benzyl potassium in 1,2-dimethoxyethane (DME) affords [(BIPM(TMS …
(dme)MCl3(NNPh2) (dme = dimethoxyethane; M = Nb, Ta): a versatile synthon for [Ta=NNPh2] hydrazido(2-) complexes.
Tonks IA, Bercaw JE. Tonks IA, et al. Inorg Chem. 2010 May 17;49(10):4648-56. doi: 10.1021/ic1004193. Inorg Chem. 2010. PMID: 20402474
Complexes (dme)TaCl(3)(NNPh(2)) (1) and (dme)NbCl(3)(NNPh(2)) (2) (dme =1,2-dimethoxyethane) were synthesized from MCl(5) and diphenylhydrazine via a Lewis-acid assisted dehydrohalogenation reaction. ...
Complexes (dme)TaCl(3)(NNPh(2)) (1) and (dme)NbCl(3)(NNPh(2)) (2) (dme =1,2-dimethoxyethane) were …
Mononuclear Rare-Earth Metalloligands Exploiting a Divergent Ligand.
Bazi M, Bracciotti E, Fioravanti L, Marchetti F, Rancan M, Armelao L, Samaritani S, Labella L. Bazi M, et al. Inorg Chem. 2024 Apr 29;63(17):7678-7691. doi: 10.1021/acs.inorgchem.3c04532. Epub 2024 Apr 16. Inorg Chem. 2024. PMID: 38623915
Rare-earth tris-diketonato [RE(dike)(3)pyterpy] metalloligands can be prepared reacting at room temperature [RE(dike)(3)dme] (dme = 1,2-dimethoxyethane; dike = tta with Htta = 2-thenoyltrifluoroacetone and RE = La, 1; Y, 2; Eu, 3; Dy, 4; or dike …
Rare-earth tris-diketonato [RE(dike)(3)pyterpy] metalloligands can be prepared reacting at room temperature [RE(dike)(3)dme] (dme …
A redox-active Mn(0) dicarbene metalloradical.
Karagiannis A, Tyryshkin AM, Lalancette RA, Spasyuk DM, Washington A, Prokopchuk DE. Karagiannis A, et al. Chem Commun (Camb). 2022 Nov 22;58(93):12963-12966. doi: 10.1039/d2cc04677f. Chem Commun (Camb). 2022. PMID: 36322000
We report a rare redox-active Mn(0) metalloradical [Mn(CO)(3)(Ph(2)B((tBu)NHC)(2))](-) (NHC = N-heterocyclic carbene) with countercations [K(2.2.2)crypt](+), [Na(2.2.2)crypt](+), or [Li(DME)(12-crown-4)](+) (DME = 1,2-dimethoxyethane), all chara …
We report a rare redox-active Mn(0) metalloradical [Mn(CO)(3)(Ph(2)B((tBu)NHC)(2))](-) (NHC = N-heterocyclic carbene) with countercations [K …
Reproductive toxicity of the glycol ethers.
Hardin BD. Hardin BD. Toxicology. 1983 Jun;27(2):91-102. doi: 10.1016/0300-483x(83)90014-8. Toxicology. 1983. PMID: 6351353 Review.
Recent studies have demonstrated that ethylene glycol monomethyl ether (EGME), ethylene glycol dimethyl ether (EGdiME), ethylene glycol monoethyl ether (EGEE), and ethylene glycol monoethyl ether acetate (EGEEA) are teratogenic. Other studies have demo …
Recent studies have demonstrated that ethylene glycol monomethyl ether (EGME), ethylene glycol dimethyl ether (E …
Liquid-free lithium-oxygen batteries.
Balaish M, Peled E, Golodnitsky D, Ein-Eli Y. Balaish M, et al. Angew Chem Int Ed Engl. 2015 Jan 7;54(2):436-40. doi: 10.1002/anie.201408008. Epub 2014 Oct 5. Angew Chem Int Ed Engl. 2015. PMID: 25283299
The proposed SPE-based Li-O2 cell is compared to Li-O2 cells based on ethylene glycol dimethyl ether (glyme) through potentiodynamic and galvanostatic studies, showing a higher cell discharge voltage by 80 mV and most significantly, a charge vol …
The proposed SPE-based Li-O2 cell is compared to Li-O2 cells based on ethylene glycol dimethyl ether (glyme …
7,582 results