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Quoted phrases not found in phrase index: "1,3,2-dioxathiolan-2-oxide", "ethylene sulphite"
Page 1
Designed Synergetic Effect of Electrolyte Additives to Improve Interfacial Chemistry of MCMB Electrode in Propylene Carbonate-Based Electrolyte for Enhanced Low and Room Temperature Performance.
Wotango AS, Su WN, Haregewoin AM, Chen HM, Cheng JH, Lin MH, Wang CH, Hwang BJ. Wotango AS, et al. ACS Appl Mater Interfaces. 2018 Aug 1;10(30):25252-25262. doi: 10.1021/acsami.8b02185. Epub 2018 Jul 17. ACS Appl Mater Interfaces. 2018. PMID: 29741362
Herein, a new electrolyte additive, 4-chloromethyl-1,3,2-dioxathiolane-2-oxide (CMDO), is prepared to improve the properties of commonly used electrolyte constituents-ethylene carbonate (EC), and fluoroethylene carbonate. ...
Herein, a new electrolyte additive, 4-chloromethyl-1,3,2-dioxathiolane-2-oxide (CMDO), is prepared to imp …
Atomic thermodynamics and microkinetics of the reduction mechanism of electrolyte additives to facilitate the formation of solid electrolyte interphases in lithium-ion batteries.
Liu X, Zhou J, Xu Z, Wang Y. Liu X, et al. RSC Adv. 2020 Apr 24;10(28):16302-16312. doi: 10.1039/d0ra01412e. eCollection 2020 Apr 23. RSC Adv. 2020. PMID: 35498873 Free PMC article.
To further our understanding in this regard, the density functional theory (DFT) B3PW91/6-311++G(3df,3pd) together with the implicit solvent model and the transition state theory were used for the first time to comprehensively explore the electroreduction mechanism of a novel add …
To further our understanding in this regard, the density functional theory (DFT) B3PW91/6-311++G(3df,3pd) together with the implicit solvent …
Formation of Iron (Hydr)Oxide Nanoparticles with a pH-Clock.
Kürsteiner R, Ding Y, Ritter M, Panzarasa G. Kürsteiner R, et al. Nanomaterials (Basel). 2022 Oct 25;12(21):3743. doi: 10.3390/nano12213743. Nanomaterials (Basel). 2022. PMID: 36364518 Free PMC article.
We demonstrate the autonomous synthesis of iron (hydr)oxide (green rust, magnetite, and lepidocrocite) nanoparticles by precipitating iron(II) ions using hydroxide ions generated in situ with the methylene glycol-sulfite (MGS) reaction, a pH-clock. We show that the …
We demonstrate the autonomous synthesis of iron (hydr)oxide (green rust, magnetite, and lepidocrocite) nanoparticles by precipitating iron(I …
Negative ions of ethylene sulfite.
Robertson WD, Hammer NI, Bartmess JE, Compton RN, Diri K, Jordan KD. Robertson WD, et al. J Chem Phys. 2005 May 22;122(20):204319. doi: 10.1063/1.1913578. J Chem Phys. 2005. PMID: 15945736
The formation of negative ions in molecular beams of ethylene sulfite (ES, alternately called glycol sulfite or ethylene glycol, C(2)H(4)SO(3)) molecules has been studied using both Rydberg electron transfer (RET) and free electron attachment methods. …
The formation of negative ions in molecular beams of ethylene sulfite (ES, alternately called glycol sulfite or …
Asymmetric Solvents Regulated Crystallization-Limited Electrolytes for All-Climate Lithium Metal Batteries.
Wang Y, Li Z, Xie W, Zhang Q, Hao Z, Zheng C, Hou J, Lu Y, Yan Z, Zhao Q, Chen J. Wang Y, et al. Angew Chem Int Ed Engl. 2024 Feb 5;63(6):e202310905. doi: 10.1002/anie.202310905. Epub 2024 Jan 2. Angew Chem Int Ed Engl. 2024. PMID: 38100193
We demonstrate that, although the high melting points of ethylene sulfite (ES, -17 C) and fluoroethylene carbonate (FEC, 23 C), their mixtures can avoid crystallization at low temperatures, which can be attributed to low intermolecular interactions and altered mo …
We demonstrate that, although the high melting points of ethylene sulfite (ES, -17 C) and fluoroethylene carbonate (FEC, 23 …
Methylene glycol-sulfite pH-clocks for the time-programming of soft materials: advantages, limitations, and yet unexplored opportunities.
Panzarasa G. Panzarasa G. Soft Matter. 2024 Aug 7;20(31):6092-6102. doi: 10.1039/d4sm00604f. Soft Matter. 2024. PMID: 39027927 Review.
In this regard, clock reactions are especially useful triggers since they allow to autonomously generate in situ chemical stimuli such as pH changes. The methylene glycol-sulfite (MGS) is a well-known acid-to-base pH-clock reaction which is able to produce sharp and …
In this regard, clock reactions are especially useful triggers since they allow to autonomously generate in situ chemical stimuli such as pH …
Time-domain Tollens reaction: synthesising silver nanoparticles with the formaldehyde clock.
Kürsteiner R, Ritter M, Sologubenko A, Stricker L, Panzarasa G. Kürsteiner R, et al. Nanoscale Adv. 2023 Mar 16;5(8):2175-2179. doi: 10.1039/d3na00121k. eCollection 2023 Apr 11. Nanoscale Adv. 2023. PMID: 37056627 Free PMC article.
The addition of silver(i) ions to the methylene glycol-sulphite (MGS) clock reaction results in the sudden formation of metallic silver nanoparticles. ...
The addition of silver(i) ions to the methylene glycol-sulphite (MGS) clock reaction results in the sudden formation of metall …
Chemomechanical oscillations with a non-redox non-oscillatory reaction.
Horváth J. Horváth J. Chem Commun (Camb). 2017 May 2;53(36):4973-4976. doi: 10.1039/c7cc02497e. Chem Commun (Camb). 2017. PMID: 28425528
Periodic length changes, over 20%, were sustained in a pH-responsive gel by associating the methylene glycol-sulphite OH-producing clock-reaction with variations of the exchange time induced between the core of the gel and a steady chemical environment. ...
Periodic length changes, over 20%, were sustained in a pH-responsive gel by associating the methylene glycol-sulphite OH-produ …
Density Functional Theory Research into the Reduction Mechanism for the Solvent/Additive in a Sodium-Ion Battery.
Liu Q, Mu D, Wu B, Wang L, Gai L, Wu F. Liu Q, et al. ChemSusChem. 2017 Feb 22;10(4):786-796. doi: 10.1002/cssc.201601356. Epub 2017 Jan 25. ChemSusChem. 2017. PMID: 27897399
The mechanism for the reduction of ethylene carbonate (EC), propylene carbonate (PC), vinylene carbonate (VC), ethylene sulfite (ES), 1,3-propylene sulfite (PS), and fluorinated ethylene carbonate (FEC) is studied by DFT. ...
The mechanism for the reduction of ethylene carbonate (EC), propylene carbonate (PC), vinylene carbonate (VC), ethylene sulfite …
Application of a chemical clock in material design: chemically programmed synthesis of zeolitic imidazole framework-8.
Német N, Holló G, Schuszter G, Horváth D, Tóth Á, Rossi F, Lagzi I. Német N, et al. Chem Commun (Camb). 2022 May 10;58(38):5777-5780. doi: 10.1039/d2cc01139e. Chem Commun (Camb). 2022. PMID: 35451438
Here we show a time-programmed and autonomous synthesis of zeolitic imidazole framework-8 (ZIF-8) using a methylene glycol-sulfite clock reaction. The induction period of the driving clock reaction, thus, the appearance of the ZIF-8 can be adjusted by the initial co …
Here we show a time-programmed and autonomous synthesis of zeolitic imidazole framework-8 (ZIF-8) using a methylene glycol-sulfite …
24 results