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Page 1
A Study of 2-Iodobutane by Rotational Spectroscopy.
Arsenault EA, Obenchain DA, Choi YJ, Blake TA, Cooke SA, Novick SE. Arsenault EA, et al. J Phys Chem A. 2016 Sep 15;120(36):7145-51. doi: 10.1021/acs.jpca.6b06938. Epub 2016 Sep 1. J Phys Chem A. 2016. PMID: 27556339
Rotational transitions belonging to 2-iodobutane (sec-butyl-iodide, CH3CHICH2CH3) were measured over the frequency range 5.5-16.5 GHz via jet-pulsed Fourier transform microwave spectroscopy. ...Changes in chi of the iodine nucleus, resulting from conformation …
Rotational transitions belonging to 2-iodobutane (sec-butyl-iodide, CH3CHICH2CH3) were measured over the frequency rang …
[Determination of trace iodide in drinking water in Shanghai by two columns and gas chromatography with electron capture detection].
Wei X, Zhang YY, Zhang D, Wang X, Sheng YJ, Zhang J, Guo S, Zheng WW, Chen X, Qu WD. Wei X, et al. Zhonghua Yu Fang Yi Xue Za Zhi. 2010 Jul;44(7):591-5. Zhonghua Yu Fang Yi Xue Za Zhi. 2010. PMID: 21055072 Chinese.
RESULTS: The results of mass spectrometry showed that iodide would form iodobutane which could generate 1-iodo-2-butanone and 3-iodo-2-butanone isomers by derivatization. The data of qualitative analysis by two capillary columns revealed that iodobutane was separate …
RESULTS: The results of mass spectrometry showed that iodide would form iodobutane which could generate 1-iodo-2-butanone and 3-iodo- …
Synchrotron photoionization mass spectrometry measurements of product formation in low-temperature n-butane oxidation: toward a fundamental understanding of autoignition chemistry and n-C4H9 + O2/s-C4H9 + O2 reactions.
Eskola AJ, Welz O, Savee JD, Osborn DL, Taatjes CA. Eskola AJ, et al. J Phys Chem A. 2013 Nov 27;117(47):12216-35. doi: 10.1021/jp408467g. Epub 2013 Nov 12. J Phys Chem A. 2013. PMID: 24125058
Oxidation was triggered either by 351 nm photolysis of Cl2 and subsequent fast Cl + n-butane reaction or by 248 nm photolysis of 1-iodobutane or 2-iodobutane. Iodobutane photolysis allowed isomer-specific preparation of either n-C4H9 or s-C4H9 radicals …
Oxidation was triggered either by 351 nm photolysis of Cl2 and subsequent fast Cl + n-butane reaction or by 248 nm photolysis of 1- …
Formation of 1-[123I]iodobutane in labeling [123I]iomazenil by iododestannylation: implications for the reaction mechanism.
Zea-Ponce Y, Baldwin RM, Zoghbi SS, Innis RB. Zea-Ponce Y, et al. Appl Radiat Isot. 1994 Jan;45(1):63-8. doi: 10.1016/0969-8043(94)90149-x. Appl Radiat Isot. 1994. PMID: 8287059
The volatile byproduct from the [123I]IMZ preparations was identified as I-[123I]iodobutane by its trapping characteristics and by its retention time in two different HPLC systems. ...
The volatile byproduct from the [123I]IMZ preparations was identified as I-[123I]iodobutane by its trapping characteristics and by it …
Perfluoro-n-butyl iodide: acute toxicity, subchronic toxicity and genotoxicity evaluations.
Dodd D, Hoffman G, Hardy C. Dodd D, et al. Int J Toxicol. 2004 Jul-Aug;23(4):249-58. doi: 10.1080/10915810490502050. Int J Toxicol. 2004. PMID: 15371169
Perfluoro-n-butyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations, because it cleans well, has zero ozone depletion potential, and has extremel …
Perfluoro-n-butyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maint …
Anhydrous Hydrogen Iodide-Mediated Reductive Indolization of In Situ-Generated Cyclopropyl Hydrazones.
Yasui M, Fujioka H, Takeda N, Ueda M. Yasui M, et al. Org Lett. 2022 Jan 14;24(1):43-47. doi: 10.1021/acs.orglett.1c03607. Epub 2021 Dec 9. Org Lett. 2022. PMID: 34881907
Fischer-type indolization of N-aryl-C-cyclopropyl hydrazones generated in situ followed by chemoselective reduction using tert-butyl iodide as an anhydrous HI generator was developed. This protocol provides indoles bearing carboxylic acid derivative units. ...
Fischer-type indolization of N-aryl-C-cyclopropyl hydrazones generated in situ followed by chemoselective reduction using tert-butyl …
CH stretching vibrational overtone spectra of tert-butylbenzene, tert-butyl chloride, and tert-butyl iodide.
Petryk MW, Henry BR. Petryk MW, et al. J Phys Chem A. 2005 May 12;109(18):4081-91. doi: 10.1021/jp040710h. J Phys Chem A. 2005. PMID: 16833730
The vapor phase CH stretching vibrational overtone spectra of tert-butylbenzene and tert-butyl chloride are measured in the Delta upsilon(CH) = 2-7 region, while the spectrum of tert-butyl iodide is recorded in the Delta upsilon(CH) = 2-6 region. The overtone spectr …
The vapor phase CH stretching vibrational overtone spectra of tert-butylbenzene and tert-butyl chloride are measured in the Delta upsilon(CH …
A 13-week nose-only inhalation toxicity study for perfluoro-n-butyl iodide (PFBI) in rats with recommended occupational exposure levels.
Mattie DR, Hoffman GM, Narayanan L, Sterner TR, Wagner MJ, Dodd DE. Mattie DR, et al. Inhal Toxicol. 2010 Aug;22(10):847-60. doi: 10.3109/08958378.2010.487291. Inhal Toxicol. 2010. PMID: 20507216
A 13-week study was conducted to develop occupational exposure limits (OELs) for the solvent perfluoro-n-butyl iodide (PFBI). Fischer 344 rats (15 males & 10 females per group) were exposed for 6 h/day to 0 (air control), 500, 1500, or 5000 ppm PFBI vapor …
A 13-week study was conducted to develop occupational exposure limits (OELs) for the solvent perfluoro-n-butyl iodide ( …
Properties of the tert-butyl halide solvolysis transition states.
Abraham MH , Martins F , Elvas-Leitão R , Moreira L . Abraham MH , et al. Phys Chem Chem Phys. 2021 Feb 7;23(5):3311-3320. doi: 10.1039/d0cp05099g. Epub 2021 Feb 2. Phys Chem Chem Phys. 2021. PMID: 33527930
We show that all three transition states, in both protic and in aprotic solvents, are highly dipolar and are strong hydrogen bond acids and strong hydrogen bond bases, except for the tert-butyl iodide transition state in aprotic solvents, which has a rather low hydr …
We show that all three transition states, in both protic and in aprotic solvents, are highly dipolar and are strong hydrogen bond acids and …
Unnatural Oligoaminosaccharides with N-1,2-Glycosidic Bonds Prepared by Cationic Ring-Opening Polymerization of 2-Oxazoline-Based Heterobicyclic Sugar Monomers.
Koda Y, Terashima T, Ouchi M. Koda Y, et al. ACS Macro Lett. 2019 Nov 19;8(11):1456-1460. doi: 10.1021/acsmacrolett.9b00674. Epub 2019 Oct 15. ACS Macro Lett. 2019. PMID: 35651175
This monomer was polymerized using a binary initiating system of tert-butyl iodide (t-BuI) and GaCl(3) to afford oligo[Glc(MeOx)]. The resulting structure corresponded to the condensation product of GlcN with N-1,2-glycosidic bonds. ...
This monomer was polymerized using a binary initiating system of tert-butyl iodide (t-BuI) and GaCl(3) to afford oligo[Glc(MeO …
73 results