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Quoted phrases not found in phrase index: "2,2-dimethyl-1-propanol", "2,2-dimethylpropan-1-ol", "neoamyl alcohol", "tert-butylcarbinol"
Page 1
Synthesis of α,δ-Disubstituted Tetraphosphates and Terminally-Functionalized Nucleoside Pentaphosphates.
Shepard SM, Kim H, Bang QX, Alhokbany N, Cummins CC. Shepard SM, et al. J Am Chem Soc. 2021 Jan 13;143(1):463-470. doi: 10.1021/jacs.0c11884. Epub 2020 Dec 29. J Am Chem Soc. 2021. PMID: 33375782 Free PMC article.
Treatment under anhydrous conditions with an alkylamine base and a nucleophile (HNuc(1)), such as an alcohol (neopentanol, cyclohexanol, 4-methylumbelliferone, and Boc-Tyr-OMe), an amine (propargylamine, diethylamine, morpholine, 3,5-dimethylaniline, and isopropylamine), d …
Treatment under anhydrous conditions with an alkylamine base and a nucleophile (HNuc(1)), such as an alcohol (neopentanol, cyclohexan …
Syntheses and crystal structures of two di-naph-tho[2,1-d:1',2'-f][1,3]dithiepine atropisomers.
Beare N, Painter GF, McAdam CJ. Beare N, et al. Acta Crystallogr E Crystallogr Commun. 2023 Jan 24;79(Pt 2):107-111. doi: 10.1107/S2056989023000476. eCollection 2023 Jan 1. Acta Crystallogr E Crystallogr Commun. 2023. PMID: 36793408 Free PMC article.
The closely related title compounds, 1-(di-naphtho-[2,1-d:1',2'-f][1,3]dithiepin-4-yl)-2,2-di-methyl-propan-1-ol, C(26)H(24)OS(2), 1 and 2-(di-naphtho-[2,1-d:1',2'-f][1,3]dithiepin-4-yl)-3,3-di-methyl-butan-2-ol, C(27)H(26)OS(2), 2, both comprise an atrop-isomeric binaphthyl di-t …
The closely related title compounds, 1-(di-naphtho-[2,1-d:1',2'-f][1,3]dithiepin-4-yl)-2,2-di-methyl-propan-1-ol, C(26)H(24)OS(2), 1 and 2-( …
Substrate oxidation by copper-dioxygen adducts: mechanistic considerations.
Shearer J, Zhang CX, Zakharov LN, Rheingold AL, Karlin KD. Shearer J, et al. J Am Chem Soc. 2005 Apr 20;127(15):5469-83. doi: 10.1021/ja045191a. J Am Chem Soc. 2005. PMID: 15826184
Detailed mechanistic studies have been carried out, including investigation of 1(R)() thermodynamic redox properties, 1(R)() tetrahydrofuran (THF) and N,N'-dimethylaniline (DMA) oxidation kinetics (including analyses of substrate dicopper binding equilibria), and application of m …
Detailed mechanistic studies have been carried out, including investigation of 1(R)() thermodynamic redox properties, 1(R)() tetrahydrofuran …
CGP7930: a positive allosteric modulator of the GABAB receptor.
Adams CL, Lawrence AJ. Adams CL, et al. CNS Drug Rev. 2007 Fall;13(3):308-16. doi: 10.1111/j.1527-3458.2007.00021.x. CNS Drug Rev. 2007. PMID: 17894647 Free PMC article. Review.
CGP7930 (3-(3',5'-Di-tert-butyl-4'-hydroxy)phenyl-2,2-dimethylpropanol) is a positive allosteric modulator of the metabotropic GABAB receptor. ...
CGP7930 (3-(3',5'-Di-tert-butyl-4'-hydroxy)phenyl-2,2-dimethylpropanol) is a positive allosteric modulator of the metab …
High-Temperature Dissociation of Neopentanol: Shock Tube/Photoionization Mass Spectrometry Studies.
Banyon C, Tranter RS. Banyon C, et al. J Phys Chem A. 2023 Feb 9;127(5):1293-1301. doi: 10.1021/acs.jpca.2c07358. Epub 2023 Jan 30. J Phys Chem A. 2023. PMID: 36716350
The pyrolysis mechanism of 2,2-dimethylpropan-1-ol (neopentanol) has been investigated at high temperatures (1128-1401K) and high pressures (5 and 15 bar). ...There are two possible roaming radical reactions for neopentanol. However, no experimental evidence for the …
The pyrolysis mechanism of 2,2-dimethylpropan-1-ol (neopentanol) has been investigated at high temperatures (1128-1401K) and high pre …
Cut-off phenomenon in the protective effect of alcohols against lysophosphatidylcholine-induced calcium overload.
Bordeleau LJ, Gailis L, Fournier D, Morissette M, Di Paolo T, Daleau P. Bordeleau LJ, et al. Pflugers Arch. 2005 Aug;450(5):292-7. doi: 10.1007/s00424-005-1425-3. Epub 2005 May 21. Pflugers Arch. 2005. PMID: 15909177
The presence of 88 mM n-propanol, n-butanol, tert-butanol, or 2,2-dimethylpropanol significantly increased the delay by 94-213%. However, n-pentanol at 2 mM or 88 mM had no protective effect. ...Chain length, rather than molecular weight determines the effect …
The presence of 88 mM n-propanol, n-butanol, tert-butanol, or 2,2-dimethylpropanol significantly increased the delay by …
Titanium(IV) Surface Complexes Bearing Chelating Catecholato Ligands for Enhanced Band-Gap Reduction.
Sonström A, Boldrini B, Werner D, Maichle-Mössmer C, Rebner K, Casu MB, Anwander R. Sonström A, et al. Inorg Chem. 2023 Jan 16;62(2):715-729. doi: 10.1021/acs.inorgchem.2c02838. Epub 2023 Jan 3. Inorg Chem. 2023. PMID: 36595489
Protonolysis reactions between dimethylamido titanium(IV) catecholate [Ti(CAT)(NMe(2))(2)](2) and neopentanol or tris(tert-butoxy)silanol gave catecholato-bridged dimers [(Ti(CAT)(OCH(2)tBu)(2))(HNMe(2))](2) and [Ti(CAT){OSi(OtBu)(3)}(2)(HNMe(2))(2)](2), respectively. ...
Protonolysis reactions between dimethylamido titanium(IV) catecholate [Ti(CAT)(NMe(2))(2)](2) and neopentanol or tris(tert-butoxy)sil …
Samarium- and Ytterbium-Grafted Periodic Mesoporous Silica for Carbon Dioxide Capture and Conversion.
Poolwong J, Kracht F, Moinet E, Liang Y, D'Elia V, Anwander R. Poolwong J, et al. Inorg Chem. 2023 Oct 30;62(43):17972-17984. doi: 10.1021/acs.inorgchem.3c02995. Epub 2023 Oct 19. Inorg Chem. 2023. PMID: 37856826
The surface complexes are readily accessible by the grafting of the bis(trimethylsilyl)amide precursors Ln(II)[N(SiMe(3))(2)](2)(THF)(2) (Ln = Sm, Yb) and Sm(III)[N(SiMe(3))(2)](3), followed by ligand exchange with alcohols (ethanol and neopentanol). The use of periodic me …
The surface complexes are readily accessible by the grafting of the bis(trimethylsilyl)amide precursors Ln(II)[N(SiMe(3))(2)](2)(THF)(2) (Ln …
Substrate specificity of human cutaneous alcohol dehydrogenase and erythema provoked by lower aliphatic alcohols.
Wilkin JK, Stewart JH. Wilkin JK, et al. J Invest Dermatol. 1987 Apr;88(4):452-4. doi: 10.1111/1523-1747.ep12469846. J Invest Dermatol. 1987. PMID: 3559273 Free article.
The substrate utilization rates of human cutaneous alcohol dehydrogenase were determined for 7 lower aliphatic primary alcohols: ethanol, propanol, butanol, pentanol, 2-methylpropanol, 3-methylbutanol, and 2,2-dimethyl-propanol. 1-Pentanol gave the highest relative activity and …
The substrate utilization rates of human cutaneous alcohol dehydrogenase were determined for 7 lower aliphatic primary alcohols: ethanol, pr …
Study of supercooled orientationally disordered binary solid solutions II: cyclohexyl derivatives, neopentanol and neopentylglycol.
Singh LP, Murthy SS, Singh G. Singh LP, et al. Phys Chem Chem Phys. 2009 Oct 28;11(40):9278-92. doi: 10.1039/b907215b. Epub 2009 Aug 17. Phys Chem Chem Phys. 2009. PMID: 19812849
The former group is the two-component system of cyclohexanol (CHXOL) + 2,2-dimethyl-1-propanol or neopentanol (NPOL); cyclohexanol (CHXOL) + cycloheptanol (CHPOL) & neopentanol (NPOL) + neopentylglycol (NPGOL) systems, and the lone non H-bonded pair that has bee …
The former group is the two-component system of cyclohexanol (CHXOL) + 2,2-dimethyl-1-propanol or neopentanol (NPOL); cyclohexanol (C …
24 results