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Quoted phrases not found in phrase index: "2,2-dimethylpropanenitrile", "2-cyano-2-methylpropane", "a,a'-dimethylpropionitrile", "t-butyl cyanide", "tert-butyl cyanide"
Page 1
C-H Activation by Isolable Cationic Bis(phosphine) Cobalt(III) Metallacycles.
Whitehurst WG, Kim J, Koenig SG, Chirik PJ. Whitehurst WG, et al. J Am Chem Soc. 2022 Oct 19;144(41):19186-19195. doi: 10.1021/jacs.2c08865. Epub 2022 Oct 4. J Am Chem Soc. 2022. PMID: 36194198 Free PMC article.
Five- and six-coordinate cationic bis(phosphine) cobalt(III) metallacycle complexes were synthesized with the general structures, [(depe)Co(cycloneophyl)(L)(L')][BAr(F)(4)] (depe = 1,2-bis(diethylphosphino)ethane; cycloneophyl = [kappa-C:C-(CH(2)C(Me)(2))C(6)H(4)]; L/L' = pyridin …
Five- and six-coordinate cationic bis(phosphine) cobalt(III) metallacycle complexes were synthesized with the general structures, [(depe)Co( …
Octa-μ3-selenido-penta-kis-(tri-ethyl-phos-phane-κP)(tri-methyl-aceto-nitrile-κN)-octa-hedro-hexa-rhenium(III) bis-(hexa-fluorido-anti-monate) tri-methyl-aceto-nitrile monosolvate.
Ren Y, Bruck AM, Szczepura LF. Ren Y, et al. Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 4;70(Pt 7):m242-3. doi: 10.1107/S1600536814011982. eCollection 2014 Jul 1. Acta Crystallogr Sect E Struct Rep Online. 2014. PMID: 25161513 Free PMC article.
No significant interactions are observed between the cationic cluster, the SbF6 (-) anions and the trimethylacetonitrile solvent molecule....
No significant interactions are observed between the cationic cluster, the SbF6 (-) anions and the trimethylacetonitrile solvent mole …
Intermolecular C(sp3 )-H Amination of Complex Molecules.
Chiappini ND, Mack JBC, Du Bois J. Chiappini ND, et al. Angew Chem Int Ed Engl. 2018 Apr 23;57(18):4956-4959. doi: 10.1002/anie.201713225. Epub 2018 Mar 22. Angew Chem Int Ed Engl. 2018. PMID: 29484792
This technology allows for efficient functionalization of complex molecules, including numerous pharmaceutical targets. The combination of pivalonitrile as a solvent, Al(2) O(3) as an additive, and phenyl sulfamate as a nitrogen source affords differential reaction perform …
This technology allows for efficient functionalization of complex molecules, including numerous pharmaceutical targets. The combination of …
Spatially Informed Qualitative Design of Weakly Solvating Electrolytes for Fast-Charging Sodium-Ion Batteries.
Liu G, Shan P, Xiao D, Zhang K, Cao Y, Zhao Z, Fan Y, Chen R, Wang Y, Yang Y, Dong X, Xia Y. Liu G, et al. J Am Chem Soc. 2026 Mar 25;148(11):12061-12072. doi: 10.1021/jacs.5c23021. Epub 2026 Mar 11. J Am Chem Soc. 2026. PMID: 41810715
Herein, Molar volume and Sterimol parameters are employed to qualitatively assess steric effects in alkyl mononitriles, a class of solvents capable of supporting high-ionic-conductivity electrolytes. Using this approach, trimethylacetonitrile (TMAN) is identified as a ster …
Herein, Molar volume and Sterimol parameters are employed to qualitatively assess steric effects in alkyl mononitriles, a class of solvents …
Long bonds and short barriers: ionization and isomerization of alkyl nitriles.
Mayer PM, Guest MF, Cooper L, Shpinkova LG, Rennie EE, Holland DM, Shaw DA. Mayer PM, et al. J Phys Chem A. 2010 Jan 21;114(2):867-78. doi: 10.1021/jp9096524. J Phys Chem A. 2010. PMID: 20000591
Threshold photoelectron spectroscopy and threshold photoelecton photoion coincidence spectroscopy were employed to study the ionization and dissociation of two alkyl nitriles, in particular, pentanenitrile and 2,2-dimethylpropanenitrile. Threshold ionization is shown to re …
Threshold photoelectron spectroscopy and threshold photoelecton photoion coincidence spectroscopy were employed to study the ionization and …
Unveiling Hydrogen Bonding and Solvent Effects on Directed Nitrile Oxide [3 + 2] Cycloaddition Reactions: Selectivity of 2,2-Dimethylpropane Nitrile Oxide with Cyclopentenylbenzamide: An MEDT Study.
Benmetir S, Benhamed L, Tchouar N, Mohammad-Salim H, de Julián-Ortiz JV, Ríos-Gutiérrez M, Domingo LR. Benmetir S, et al. ACS Omega. 2025 Apr 3;10(14):13868-13879. doi: 10.1021/acsomega.4c07794. eCollection 2025 Apr 15. ACS Omega. 2025. PMID: 40256558 Free PMC article.
The role of hydrogen bond and solvent effects on the regio- and diastereoselectivity of the [3 + 2] cycloaddition reaction (32CA) between 2,2-dimethylpropanenitrile oxide (NO) and N-(cyclopent-2-en-1-yl)benzamide has been theoretically studied at the B3LYP/6-311++G(d,p) le …
The role of hydrogen bond and solvent effects on the regio- and diastereoselectivity of the [3 + 2] cycloaddition reaction (32CA) between 2, …
Photodegradation of haloacetonitriles in water by vacuum ultraviolet irradiation: Mechanisms and intermediate formation.
Kiattisaksiri P, Khan E, Punyapalakul P, Ratpukdi T. Kiattisaksiri P, et al. Water Res. 2016 Jul 1;98:160-7. doi: 10.1016/j.watres.2016.04.010. Epub 2016 Apr 11. Water Res. 2016. PMID: 27101477
Degradation intermediates of HANs such as 2-chloropropionitrile, 2,2-dimethylpropanenitrile, and fumaronitrile were produced from the substitution, addition, and polymerization reactions. ...
Degradation intermediates of HANs such as 2-chloropropionitrile, 2,2-dimethylpropanenitrile, and fumaronitrile were produced from the …
Diverse reactions of 1,4-dilithio-1,3-dienes with nitriles: facile access to tricyclic Delta1-bipyrrolines, multiply substituted pyridines, siloles, and (Z,Z)-dienylsilanes by tuning of substituents on the butadienyl skeleton.
Yu N, Wang C, Zhao F, Liu L, Zhang WX, Xi Z. Yu N, et al. Chemistry. 2008;14(18):5670-9. doi: 10.1002/chem.200701742. Chemistry. 2008. PMID: 18418837
Seven-membered-ring fused dilithiodienes reacted with PhCN or trimethylacetonitrile to afford the corresponding pyridines in good yield. When 1,2,3,4-tetrasubstituted dilithio reagents (Type I) were treated with Me3SiCN, a tandem silylation/intramolecular substitution proc …
Seven-membered-ring fused dilithiodienes reacted with PhCN or trimethylacetonitrile to afford the corresponding pyridines in good yie …
MgO Modified by X2, HX, or Alkyl Halide (X = Cl, Br, or I) Catalytic Systems and Their Activity in Chemoselective Transfer Hydrogenation of Acrolein into Allyl Alcohol.
Gliński M, Ulkowska U, Kaszkur Z, Łomot D, Winiarek P. Gliński M, et al. Molecules. 2024 Jul 3;29(13):3180. doi: 10.3390/molecules29133180. Molecules. 2024. PMID: 38999133 Free PMC article.
The obtained systems were characterized using a number of methods: determination of the concentration of X(-) ions, surface area determination, powder X-ray diffraction (PXRD), surface acid-base strength measurements, TPD of probe molecules (acetonitrile, pivalonitrile, tr …
The obtained systems were characterized using a number of methods: determination of the concentration of X(-) ions, surface area determinati …
A one-pot access to 6-substituted phenanthridines from fluoroarenes and nitriles via 1,2-arynes.
Pawlas J, Begtrup M. Pawlas J, et al. Org Lett. 2002 Aug 8;4(16):2687-90. doi: 10.1021/ol026197c. Org Lett. 2002. PMID: 12153210
Aryl- and hetaryl nitriles, cyanamides, and trimethylacetonitrile gave phenanthridine products. The method was extended to provide bisphenanthridine 10 by a one-pot bis-cyclization, using 1,3-dicyanobenzene and PhF in 1:5 ratio. ...
Aryl- and hetaryl nitriles, cyanamides, and trimethylacetonitrile gave phenanthridine products. The method was extended to provide bi …
31 results