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51 results

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Quoted phrase not found in phrase index: "2-chlorobenzenecarbonal"
Page 1
Using 2-(2-Chlorophenyl)thiazolidine-4-carboxylic Acid as a Novel Biomarker for 2-Chlorobenzalmalononitrile Exposure.
Pan G, Tse HT, Chan HW, Chan W. Pan G, et al. Chem Res Toxicol. 2024 Oct 21;37(10):1747-1754. doi: 10.1021/acs.chemrestox.4c00304. Epub 2024 Oct 5. Chem Res Toxicol. 2024. PMID: 39367858
Using liquid chromatographic and mass spectrometric techniques, we found that CS underwent rapid hydrolysis into 2-chlorobenzaldehyde (2-CBA), a highly reactive intermediate that reacted swiftly with endogenous cysteine (Cys) and Cys residues in proteins, pro …
Using liquid chromatographic and mass spectrometric techniques, we found that CS underwent rapid hydrolysis into 2-chlorobenzaldeh …
Synthesis of some new pyrimido[2',1':2,3]thiazolo[4,5-b]quinoxaline derivatives as anti-inflammatory and analgesic agents.
Abu-Hashem AA, Gouda MA, Badria FA. Abu-Hashem AA, et al. Eur J Med Chem. 2010 May;45(5):1976-81. doi: 10.1016/j.ejmech.2010.01.042. Epub 2010 Jan 28. Eur J Med Chem. 2010. PMID: 20149490
Compound 4 was utilized as a key intermediate for the synthesis of a new pyrimido[2',1':2,3]thiazolo[4,5-b]quinoxaline derivatives 5-14via the reaction with 2-chlorobenzaldehyde, 2-chlorocyclohex-1-enecarbaldehyde, 2-chlorobenzoic acid, 2,4-dichlorobenzoic ac …
Compound 4 was utilized as a key intermediate for the synthesis of a new pyrimido[2',1':2,3]thiazolo[4,5-b]quinoxaline derivatives 5-14via t …
Synthesis and Aminomethylation of 2-Amino-4-(2-chlorophenyl)-6-(dicyanomethyl)-1,4-dihydropyridine-3,5-dicarbonitrile N-Methylmorpholinium Salt.
Kurskova AO, Dotsenko VV, Frolov KA, Aksenov NA, Aksenova IV, Krivokolysko BS, Peresypkina AA, Chigorina EA, Krivokolysko SG. Kurskova AO, et al. Russ J Gen Chem. 2022;92(5):779-790. doi: 10.1134/S1070363222050061. Epub 2022 Jun 14. Russ J Gen Chem. 2022. PMID: 35729943 Free PMC article.
Sequential reaction of 2-chlorobenzaldehyde, cyanothioacetamide, and malononitrile dimer in the presence of an excess of N-methylmorpholine resulted in the formation of N-methylmorphlinium salt of 2-amino-4-(2-chlorophenyl)-6-(dicyanomethyl)-1,4-dihydropyridine-3,5- …
Sequential reaction of 2-chlorobenzaldehyde, cyanothioacetamide, and malononitrile dimer in the presence of an excess of N-met …
Synthesis of novel biologically active heterocyclic compounds from 2-oxo-2H-benzopyran-6-yl-imidazolidine.
Mulwad VV, Langi BP, Chaskar AC. Mulwad VV, et al. Acta Pol Pharm. 2011 Jan-Feb;68(1):39-47. Acta Pol Pharm. 2011. PMID: 21485700 Free article.
6-Aminocoumarin on treatment with oxalyl chloride gives coumarinyl-6-isocynate (1a-c) which on treatment with glycine gives 1H-3-[2'-oxo-2'H-benzopyran-6'-yl]-5-imidazolidine-2, 4-dione (2a-c). (2a-c) when refluxed with o-chlorobenzaldehyde, m-hydroxybenzaldehyde, 3 …
6-Aminocoumarin on treatment with oxalyl chloride gives coumarinyl-6-isocynate (1a-c) which on treatment with glycine gives 1H-3-[2'-oxo-2'H …
Synthesis, Purity Check, Hydrolysis and Removal of o-Chlorobenzyliden Malononitrile (CBM) by Biological Selective Media.
Gheorghe V, Gheorghe CG, Popovici DR, Mihai S, Calin C, Sarbu EE, Doukeh R, Grigoriu N, Toader CN, Epure C, Matei V. Gheorghe V, et al. Toxics. 2023 Aug 4;11(8):672. doi: 10.3390/toxics11080672. Toxics. 2023. PMID: 37624177 Free PMC article.
In the parallel samples, a hydrolysis process of CBM at room temperature, without biological treatment, revealed two main metabolites, malononitrile and o-chlorobenzaldehyde, respectively. This study is focused on evaluating the biodegradation capacity of o-chlorobe …
In the parallel samples, a hydrolysis process of CBM at room temperature, without biological treatment, revealed two main metabolites, malon …
The fate of 2-chlorobenzylidene malononitrile (CS) in rats.
Brewster K, Harrison JM, Leadbeater L, Newman J, Upshall DG. Brewster K, et al. Xenobiotica. 1987 Aug;17(8):911-24. doi: 10.3109/00498258709044190. Xenobiotica. 1987. PMID: 3118582
It is concluded that CS in vivo is hydrolysed mainly to 2-chlorobenzaldehyde which is then either oxidized to 2-chlorobenzoic acid for subsequent glycine conjugation, or reduced to 2-chlorobenzyl alcohol for ultimate excretion as 2-chlorobenzyl acetyl cysteine or 1- …
It is concluded that CS in vivo is hydrolysed mainly to 2-chlorobenzaldehyde which is then either oxidized to 2-chlorobenzoic …
Varying Projection Quality of Good Local Electric Field Gradients of Monochlorobenzaldehydes.
Dohmen R, Arnold S, Garrett J, Kempken B, Hartwig B, Schröder B, Pinacho P, Schnell M, Brown GG, Obenchain DA. Dohmen R, et al. J Phys Chem A. 2025 Jan 30;129(4):860-873. doi: 10.1021/acs.jpca.4c04915. Epub 2025 Jan 17. J Phys Chem A. 2025. PMID: 39823215 Free PMC article.
We identified two conformers for 3-chlorobenzaldehyde and one conformer each for 2-chlorobenzaldehyde and 4-chlorobenzaldehyde. Rigorous structure fitting of 4-chlorobenzaldehyde was performed to determine bond lengths for r(0), r(s), r(e)(se), and r(m)((1)) structu …
We identified two conformers for 3-chlorobenzaldehyde and one conformer each for 2-chlorobenzaldehyde and 4-chlorobenzaldehyde …
Metabolic engineering of bacteria for environmental applications: construction of Pseudomonas strains for biodegradation of 2-chlorotoluene.
Haro MA, de Lorenzo V. Haro MA, et al. J Biotechnol. 2001 Feb 13;85(2):103-13. doi: 10.1016/s0168-1656(00)00367-9. J Biotechnol. 2001. PMID: 11165359
The assembled pathway includes one catabolic segment encoding the toluene dioxygenase of the TOD system of Pseudomonas putida F1 (todC1C2BA), which affords the bioconversion of 2-chlorotoluene into 2-chlorobenzaldehyde by virtue of its residual methyl-monooxygenase …
The assembled pathway includes one catabolic segment encoding the toluene dioxygenase of the TOD system of Pseudomonas putida F1 (todC1C2BA) …
51 results