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Page 1
Palladium-Catalyzed Reductive Aminocarbonylation of o-Iodophenol-Derived Allyl Ethers with o-Nitrobenzaldehydes to 3-Alkenylquinolin-2(1H)-ones.
Liu JL, Wang W, Qi X, Wu XF. Liu JL, et al. Org Lett. 2022 Mar 25;24(11):2248-2252. doi: 10.1021/acs.orglett.2c00648. Epub 2022 Mar 10. Org Lett. 2022. PMID: 35271283
With Mo(CO)(6) as both CO surrogate and reductant, a variety of 3-alkenylquinolin-2(1H)-ones were obtained in good to excellent yields from o-iodophenol-derived allyl ethers with o-nitrobenzaldehydes as the nitrogen sources. ...
With Mo(CO)(6) as both CO surrogate and reductant, a variety of 3-alkenylquinolin-2(1H)-ones were obtained in good to excellent yields from …
Intermediate and mechanism of hydroxylation of o-iodophenol by salicylate hydroxylase.
Suzuki K, Gomi T, Itagaki E. Suzuki K, et al. J Biochem. 1991 May;109(5):791-7. doi: 10.1093/oxfordjournals.jbchem.a123458. J Biochem. 1991. PMID: 1917904 Free article.
The mechanisms for the deiodination and oxygenation of o-iodophenol were investigated in detail by the use of I(+)-trapping reagents such as DL-methionine, 2-chlorodimedone, and L-tyrosine. ...This suggests that o-benzoquinone is formed in the oxidation of o- …
The mechanisms for the deiodination and oxygenation of o-iodophenol were investigated in detail by the use of I(+)-trapping re …
Pd-Catalyzed Migratory 1,1-Cycloannulation Reaction of Alkenes.
Wang JP, Liu T, Wu Y, Wang P. Wang JP, et al. J Am Chem Soc. 2025 Jan 8;147(1):69-77. doi: 10.1021/jacs.4c14153. Epub 2024 Dec 18. J Am Chem Soc. 2025. PMID: 39692582
The key to the realization of this reaction is the use of 4-iodophenol or 2-iodophenol derivatives where the phenolic hydroxyl group plays a critical role in controlling the direction of migration and the ring-size of the heterocycles through the formation of a quin …
The key to the realization of this reaction is the use of 4-iodophenol or 2-iodophenol derivatives where the phenolic hydroxyl …
Removal of 2-fluoro and 2-iodophenol from aqueous solutions using industrial wastes.
Jain AK, Suhas, Jain S, Bhatnagar A. Jain AK, et al. Environ Technol. 2004 Jan;25(1):15-22. doi: 10.1080/09593330409355434. Environ Technol. 2004. PMID: 15027646
A comparative study of the adsorbents prepared from several industrial wastes for the removal of 2-fluorophenol and 2-iodophenol has been carried out. The results show that maximum adsorption on carbonaceous adsorbent prepared from fertilizer industry waste has been …
A comparative study of the adsorbents prepared from several industrial wastes for the removal of 2-fluorophenol and 2-iodophenol …
Regiospecific carbonylative annulation of iodophenol acetates and acetylenes to construct the flavones by a new catalyst of palladium-thiourea-dppp complex.
Miao H, Yang Z. Miao H, et al. Org Lett. 2000 Jun 15;2(12):1765-8. doi: 10.1021/ol000087t. Org Lett. 2000. PMID: 10880221
[reaction: see text] Regiospecific carbonylative annulation of o-iodophenol acetates and acetylenes mediated by palladium-thiourea-dppp complex in the presence of base at 40 degrees C under a balloon pressure of CO generates diversified flavones in high yields. ...
[reaction: see text] Regiospecific carbonylative annulation of o-iodophenol acetates and acetylenes mediated by palladium-thio …
Active Site Binding Is Not Sufficient for Reductive Deiodination by Iodotyrosine Deiodinase.
Ingavat N, Kavran JM, Sun Z, Rokita SE. Ingavat N, et al. Biochemistry. 2017 Feb 28;56(8):1130-1139. doi: 10.1021/acs.biochem.6b01308. Epub 2017 Feb 16. Biochemistry. 2017. PMID: 28157283 Free PMC article.
In this example, discrimination was not based on affinity since 4-cyano-2-iodophenol bound to the bacterial deiodinase with a K(d) lower than that of iodotyrosine and yet was not detectably deiodinated. ...A cocrystal structure of bacterial deiodinase and 2- …
In this example, discrimination was not based on affinity since 4-cyano-2-iodophenol bound to the bacterial deiodinase with a …
Fast speciation analysis of iodophenol compounds in river waters by capillary electrophoresis-inductively coupled plasma-mass spectrometry with off-line solid-phase microextraction.
Kannamkumarath SS, Wuilloud RG, Jayasinghe S, Caruso JA. Kannamkumarath SS, et al. Electrophoresis. 2004 Jun;25(12):1843-51. doi: 10.1002/elps.200305855. Electrophoresis. 2004. PMID: 15213983
Based on the element-specific and highly sensitive detection provided by ICP-MS, the methodology has been applied to the analysis of 2-iodophenol, 4-iodophenol, and 2,4,6-triiodophenol. The use of solid-phase microextraction (SPME), after proper optimization, improv …
Based on the element-specific and highly sensitive detection provided by ICP-MS, the methodology has been applied to the analysis of 2 …
Regioselective synthesis of 1,3,5-substituted benzenes via the InCl(3)/2-iodophenol-catalyzed cyclotrimerization of alkynes.
Xu YL, Pan YM, Wu Q, Wang HS, Liu PZ. Xu YL, et al. J Org Chem. 2011 Oct 21;76(20):8472-6. doi: 10.1021/jo201010d. Epub 2011 Sep 26. J Org Chem. 2011. PMID: 21916477
A novel indium(III)-catalyzed cyclotrimerization of alkynes in the presence of 2-iodophenol gave 1,3,5-substituted benzenes in excellent yields with complete regioselectivity. ...
A novel indium(III)-catalyzed cyclotrimerization of alkynes in the presence of 2-iodophenol gave 1,3,5-substituted benzenes in …
[Development of Efficient Methods for Benzyne Generation].
Takagi A. Takagi A. Yakugaku Zasshi. 2018;138(1):27-35. doi: 10.1248/yakushi.17-00157. Yakugaku Zasshi. 2018. PMID: 29311462 Free article. Review. Japanese.
2-[(Neopentyl glycolato)boryl]phenyl triflates, readily synthesized from 2-iodophenol derivatives via halogen-magnesium exchange or Miyaura borylation, were developed as new benzyne precursors. ...
2-[(Neopentyl glycolato)boryl]phenyl triflates, readily synthesized from 2-iodophenol derivatives via halogen-magnesium exchan …
Hydroxylation of o-halogenophenol and o-nitrophenol by salicylate hydroxylase.
Suzuki K, Gomi T, Kaidoh T, Itagaki E. Suzuki K, et al. J Biochem. 1991 Feb;109(2):348-53. J Biochem. 1991. PMID: 1864847 Free article.
Kinetic parameters of these reactions were determined by spectrophotometric and polarographic methods. Hydroxylation of o-nitro- or o-iodophenol proceeds with the unusual stoichiometry of 2:1:1 for consumed NADH, O2-uptake, and catechol formed. ...
Kinetic parameters of these reactions were determined by spectrophotometric and polarographic methods. Hydroxylation of o-nitro- or o …
54 results