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1946 1
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16 results

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Page 1
Diastereoselective Synthesis and Two-Step Photocleavage of Ruthenium Polypyridyl Complexes Bearing a Bis(thioether) Ligand.
Meijer MS, Bonnet S. Meijer MS, et al. Inorg Chem. 2019 Sep 3;58(17):11689-11698. doi: 10.1021/acs.inorgchem.9b01669. Epub 2019 Aug 21. Inorg Chem. 2019. PMID: 31433170 Free PMC article.
Here, we introduce a novel symmetric chelating bis(thioether) ligand scaffold, based on 1,3-bis(methylthio)-2-propanol (4) and report the synthesis and stereochemical characterization of the series of novel ruthenium(II) polypyridyl complexes [Ru(bpy)(2)(L)](PF(6))(2) ([1]-[3](PF …
Here, we introduce a novel symmetric chelating bis(thioether) ligand scaffold, based on 1,3-bis(methylthio)-2-propanol (4) and report the sy …
Biodegradation of tetrabromobisphenol A by oxidases in basidiomycetous fungi and estrogenic activity of the biotransformation products.
Uhnáková B, Ludwig R, Pěknicová J, Homolka L, Lisá L, Šulc M, Petříčková A, Elzeinová F, Pelantová H, Monti D, Křen V, Haltrich D, Martínková L. Uhnáková B, et al. Bioresour Technol. 2011 Oct;102(20):9409-15. doi: 10.1016/j.biortech.2011.07.036. Epub 2011 Jul 26. Bioresour Technol. 2011. PMID: 21865031
Laccase was used to prepare TBBPA metabolites 2,6-dibromo-4-(2-hydroxypropane-2-yl) phenol (1), 2,6-dibromo-4-(2-methoxypropane-2-yl) phenol (2) and 1-(3,5-dibromo-4-hydroxyphen-1-yl)-2,2',6,6'-tetrabromo-4,4'-isopropylidene diphenol (3). ...
Laccase was used to prepare TBBPA metabolites 2,6-dibromo-4-(2-hydroxypropane-2-yl) phenol (1), 2,6-dibromo-4-(2-methoxypropane …
Differential modulatory actions of the volatile convulsant flurothyl and its anesthetic isomer at inhibitory ligand-gated ion channels.
Krasowski MD. Krasowski MD. Neuropharmacology. 2000 Apr 27;39(7):1168-83. doi: 10.1016/s0028-3908(99)00221-x. Neuropharmacology. 2000. PMID: 10760360 Free PMC article.
This study focused on flurothyl (bis[2,2, 2-trifluoroethyl] ether), a potent volatile convulsant, and its anesthetic isomer, 'iso-flurothyl' (1,1,1,3,3, 3-hexafluoro-2-methoxypropane). The effects of flurothyl and iso-flurothyl were studied using the whole-cell patc …
This study focused on flurothyl (bis[2,2, 2-trifluoroethyl] ether), a potent volatile convulsant, and its anesthetic isomer, 'iso-flurothyl' …
Sevoflurane Promotes Neurodegeneration Through Inflammasome Formation in APP/PS1 Mice.
Li G, Wang Y, Cao F, Wang D, Zhou L, Jin Y. Li G, et al. Front Neurosci. 2021 Dec 2;15:647136. doi: 10.3389/fnins.2021.647136. eCollection 2021. Front Neurosci. 2021. PMID: 34924922 Free PMC article.
Sevoflurane (SEVO) is a highly fluorinated methyl isopropyl ether used as an inhalational anesthetic for general anesthesia. Previous studies have shown that SEVO may induce impaired memory and recognition ability and may be associated with neurodegenerative …
Sevoflurane (SEVO) is a highly fluorinated methyl isopropyl ether used as an inhalational anesthetic for general anesth …
[Sevoflurane].
Gilsanz F, Celemín R, Blanc G, Orts MM. Gilsanz F, et al. Rev Esp Anestesiol Reanim. 1996 Aug-Sep;43(7):243-8. Rev Esp Anestesiol Reanim. 1996. PMID: 8966352 Review. Spanish.
Sevoflurane is a fluoridated derivative of methyl isopropyl ether. Its administration does not require the use of sophisticated vaporizers and its blood/gas partition coefficient is 0.69. ...
Sevoflurane is a fluoridated derivative of methyl isopropyl ether. Its administration does not require the use of sophi …
Regulating Electrostatic Interaction between Hydrofluoroethers and Carbonyl Cathodes toward Highly Stable Lithium-Organic Batteries.
Lu Y, Yang Z, Zhang Q, Xie W, Chen J. Lu Y, et al. J Am Chem Soc. 2024 Jan 10;146(1):1100-1108. doi: 10.1021/jacs.3c12358. Epub 2023 Dec 21. J Am Chem Soc. 2024. PMID: 38127285
Notably, when using the electrolyte based on 1,1,1,3,3,3-hexafluoro-2-methoxypropane with a certain coordination ability, PTO exhibits excellent cycling stability with a high capacity retention of 78% after 1000 cycles. ...
Notably, when using the electrolyte based on 1,1,1,3,3,3-hexafluoro-2-methoxypropane with a certain coordination ability, PTO …
Effect of sevoflurane treatment on microglia activation, NF-kB and MAPK activities.
Yu X, Zhang F, Shi J. Yu X, et al. Immunobiology. 2019 Sep;224(5):638-644. doi: 10.1016/j.imbio.2019.07.004. Epub 2019 Aug 3. Immunobiology. 2019. PMID: 31451204
Microglia activation has been implicated in neurodegenerative disease. Sevoflurane is fluorinated methyl isopropyl ether with anti-inflammatory activity. In this study, we evaluated the potential effects of sevoflurane on lipopolysaccharides (LPS)-induced mic …
Microglia activation has been implicated in neurodegenerative disease. Sevoflurane is fluorinated methyl isopropyl ether …
17O NMR spectroscopic characterization and the mechanism of formation of alkyl hydrotrioxides (ROOOH) and hydrogen trioxide (HOOOH) in the low-temperature ozonation of isopropyl alcohol and isopropyl methyl ether: water-assisted decomposition.
Plesnicar B, Cerkovnik J, Tekavec T, Koller J. Plesnicar B, et al. Chemistry. 2000 Mar 3;6(5):809-19. doi: 10.1002/(sici)1521-3765(20000303)6:5<809::aid-chem809>3.0.co;2-8. Chemistry. 2000. PMID: 10826603
Low-temperature ozonation of isopropyl alcohol (1a) and isopropyl methyl ether (1b) in [D6]acetone, methyl acetate, and tert-butyl methyl ether at -78 degrees C produced the corresponding hydrotrioxides, Me2C(OH)(OOOH) (2a) and Me2C(OMe)(OOOH) (2b), along wit …
Low-temperature ozonation of isopropyl alcohol (1a) and isopropyl methyl ether (1b) in [D6]acetone, methyl acetate, and …
Synthesis and reactions of (E)- and (Z)-1,3-dibromo-2-methoxypropene.
Edvardsen KR, Benneche T, Tius MA. Edvardsen KR, et al. J Org Chem. 2000 May 19;65(10):3085-9. doi: 10.1021/jo991822l. J Org Chem. 2000. PMID: 10814200
(Z)-1,3-Dibromo-2-methoxypropene is prepared in 90% yield by dehydrohalogenation of 1,2,3-tribromo-2-methoxypropane with diisopropylamine in dichloromethane. The E-isomer can be obtained as the only product in almost quantitative yield by UV irradiation of the Z-iso …
(Z)-1,3-Dibromo-2-methoxypropene is prepared in 90% yield by dehydrohalogenation of 1,2,3-tribromo-2-methoxypropane with diiso …
Rate constant calculations of H-atom abstraction reactions from ethers by HȮ2 radicals.
Mendes J, Zhou CW, Curran HJ. Mendes J, et al. J Phys Chem A. 2014 Feb 27;118(8):1300-8. doi: 10.1021/jp412496g. Epub 2014 Feb 17. J Phys Chem A. 2014. PMID: 24483837
In this work, we detail hydrogen atom abstraction reactions from six ethers by the hydroperoxyl radical, including dimethyl ether, ethyl methyl ether, propyl methyl ether, isopropyl methyl ether, butyl methyl ether, and isobutyl methyl ether, in order to test …
In this work, we detail hydrogen atom abstraction reactions from six ethers by the hydroperoxyl radical, including dimethyl ether, ethyl met …
16 results