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Quoted phrase not found in phrase index: "t-butanethiol"
Page 1
Multi-ligand-directed synthesis of chiral silver nanoclusters.
Zou X, Jin S, Du W, Li Y, Li P, Wang S, Zhu M. Zou X, et al. Nanoscale. 2017 Nov 9;9(43):16800-16805. doi: 10.1039/c7nr06338e. Nanoscale. 2017. PMID: 29072749
Herein, we report the synthesis and total structure determination of [Ag(32)(Dppm)(5)(SAdm)(13)Cl(8)](3+) and [Ag(45)(Dppm)(4)(S-Bu(t))(16)Br(12)](3+) (where Dppm = bis(diphenyphosphino)methane, HSAdm = 1-adamantanethiol and HS-Bu(t) = tert-butyl mercaptan). …
Herein, we report the synthesis and total structure determination of [Ag(32)(Dppm)(5)(SAdm)(13)Cl(8)](3+) and [Ag(45)(Dppm)(4)(S-Bu(t))(16)B …
Synthesis of Four-Disulfide Insulin Analogs via Sequential Disulfide Bond Formation.
Wu F, Mayer JP, Gelfanov VM, Liu F, DiMarchi RD. Wu F, et al. J Org Chem. 2017 Apr 7;82(7):3506-3512. doi: 10.1021/acs.joc.6b03078. Epub 2017 Mar 27. J Org Chem. 2017. PMID: 28319665
We report here a straightforward and effective approach based on stepwise, sequentially directed disulfide bond formation, exemplified by the synthesis of four-disulfide bond-containing insulin analogs. Cysteine protection consisted of tert-butylthiol (StBu), thiol- …
We report here a straightforward and effective approach based on stepwise, sequentially directed disulfide bond formation, exemplified by th …
Eight-Electron Copper Nanoclusters for Photothermal Conversion.
Sun X, Yan B, Gong X, Xu Q, Guo Q, Shen H. Sun X, et al. Chemistry. 2024 May 17;30(28):e202400527. doi: 10.1002/chem.202400527. Epub 2024 Apr 2. Chemistry. 2024. PMID: 38470123
Reported in this work are novel copper nanoclusters of [XCu(54)Cl(12)((t)BuS)(20)(NO(3))(12)] (X=S or none, (t)BuSH=2-methyl-2-propanethiol), which exhibit high performance in photothermal conversion. ...
Reported in this work are novel copper nanoclusters of [XCu(54)Cl(12)((t)BuS)(20)(NO(3))(12)] (X=S or none, (t)BuSH=2-methyl- …
Observation of a bcc-like framework in polyhydrido copper nanoclusters.
Guo QL, Han BL, Sun CF, Wang Z, Tao Y, Lin JQ, Luo GG, Tung CH, Sun D. Guo QL, et al. Nanoscale. 2021 Dec 2;13(46):19642-19649. doi: 10.1039/d1nr05567d. Nanoscale. 2021. PMID: 34816855
In this contribution, we report the syntheses and total structure determination of six 28-nuclearity polyhydrido Cu NCs: [Cu(28)H(16)(dppp)(4)(RS)(4)(CF(3)CO(2))(8)] (dppp = 1,3-bis(diphenylphosphino)propane, RSH = cyclohexylthiol, 1; tert-butylthiol, 3; and 2-thiop …
In this contribution, we report the syntheses and total structure determination of six 28-nuclearity polyhydrido Cu NCs: [Cu(28)H(16)(dppp)( …
Portable chemical detection platform for on-site monitoring of odorant levels in natural gas.
Fung S, Contreras RP, Fung AG, Gibson P, LeVasseur MK, McCartney MM, Koch DT, Chakraborty P, Chew BS, Rajapakse MY, Chevy DA, Hicks TL, Davis CE. Fung S, et al. J Chromatogr A. 2023 Aug 30;1705:464151. doi: 10.1016/j.chroma.2023.464151. Epub 2023 Jun 18. J Chromatogr A. 2023. PMID: 37419015 Free PMC article.
Detection and quantification of six commonly used mercaptan compounds (ethyl mercaptan, dimethyl sulfide, n-propylmercaptan, isopropyl mercaptan, tert-butyl mercaptan, and tetrahydrothiophene) at typical odorizing concentrations of 0.1-5 ppm was performed usi …
Detection and quantification of six commonly used mercaptan compounds (ethyl mercaptan, dimethyl sulfide, n-propylmercaptan, isopropyl merca …
Controllable spontaneous resolution in ultrasmall Cu-Ag bimetallic cluster ion pairs from achiral components.
He J, Deng CL, Sun CF, Zhang XX, Cui Y, Wu SH, Luo GG. He J, et al. Chem Commun (Camb). 2022 Feb 1;58(10):1577-1580. doi: 10.1039/d1cc05135k. Chem Commun (Camb). 2022. PMID: 35014990
Bimetallic cluster ion pairs containing a quaternary phosphonium and an ultrasmall Cu(2)Ag(3) anionic cluster protected by thiolates: (PPh(3)R'')[Cu(2)Ag(3)(SR')(6)] (R'SH = cyclohexylthiol (CySH), R'' = Ph, 1; Me, 2; Et, 3; Pr, 4; R'SH = tert-butylthiol ((t)BuSH) a …
Bimetallic cluster ion pairs containing a quaternary phosphonium and an ultrasmall Cu(2)Ag(3) anionic cluster protected by thiolates: (PPh(3 …
Direct Synthesis of Highly Conductive tert-Butylthiol-Capped CuInS2 Nanocrystals.
Lefrançois A, Pouget S, Vaure L, Lopez-Haro M, Reiss P. Lefrançois A, et al. Chemphyschem. 2016 Mar 3;17(5):654-9. doi: 10.1002/cphc.201500800. Epub 2015 Oct 14. Chemphyschem. 2016. PMID: 26455437
tert-butylthiol (tBuSH) is used as the sulfur source, surface ligand and co-solvent in the synthesis of CuInS2 nanocrystals (NCs). ...
tert-butylthiol (tBuSH) is used as the sulfur source, surface ligand and co-solvent in the synthesis of CuInS2 nanocrystals (N
Effect of Different Aging Methods on the Formation of Aroma Volatiles in Beef Strip Loins.
Lee D, Lee HJ, Yoon JW, Kim M, Jo C. Lee D, et al. Foods. 2021 Jan 12;10(1):146. doi: 10.3390/foods10010146. Foods. 2021. PMID: 33445674 Free PMC article.
Most changes in the concentrations of aroma volatiles of dry-aged beef were associated with propanal, 2-methylbutanal, 2-methylpropanal, 1-butanamine, trimethylamine, 2-methyl-2-propanethiol, and ethyl propanoate, which were mainly produced by lipid ox …
Most changes in the concentrations of aroma volatiles of dry-aged beef were associated with propanal, 2-methylbutanal, 2-methylpropanal, 1-b …
Photoelectron spectroscopy and thermochemistry of the peroxyacetate anion.
Villano SM, Eyet N, Wren SW, Ellison GB, Bierbaum VM, Lineberger WC. Villano SM, et al. Eur J Mass Spectrom (Chichester). 2010;16(3):255-68. doi: 10.1255/ejms.1055. Eur J Mass Spectrom (Chichester). 2010. PMID: 20530835
The gas-phase acidity of trans-peroxyacetic acid was bracketed between the acidity of acetic acid and tert-butylthiol at Delta(a)G(298)(trans-CH(3)C(O)OOH)=1439 +/- 14 kJ mol(-1) and Delta(a)H(298)(trans-CH(3)C(O)OOH)=1467+/-14 kJ mol(-1). ...
The gas-phase acidity of trans-peroxyacetic acid was bracketed between the acidity of acetic acid and tert-butylthiol at Delta …
Multiple neighboring active sites of an atomically precise copper nanocluster catalyst for efficient bond-forming reactions.
Ghosh A, Sagadevan A, Murugesan K, Nastase SAF, Maity B, Bodiuzzaman M, Shkurenko A, Hedhili MN, Yin J, Mohammed OF, Eddaoudi M, Cavallo L, Rueping M, Bakr OM. Ghosh A, et al. Mater Horiz. 2024 May 20;11(10):2494-2505. doi: 10.1039/d4mh00098f. Mater Horiz. 2024. PMID: 38477151
Here, we introduce a core-shell copper nanocluster (CuNC), [Cu(29)(S(t)Bu)(13)Cl(5)(PPh(3))(4)H(10)](t)BuSO(3) (S(t)Bu: tert-butylthiol; PPh(3): triphenylphosphine), Cu(29)NC, with multiple accessible active sites on its shell. ...
Here, we introduce a core-shell copper nanocluster (CuNC), [Cu(29)(S(t)Bu)(13)Cl(5)(PPh(3))(4)H(10)](t)BuSO(3) (S(t)Bu: tert-butyl
54 results