Excited-state structure of copper phenanthroline-based photosensitizers.
Guda A, Windisch J, Probst B, van Bokhoven JA, Alberto R, Nachtegaal M, Chen LX, Smolentsev G.
Guda A, et al.
Phys Chem Chem Phys. 2021 Dec 8;23(47):26729-26736. doi: 10.1039/d1cp02823e.
Phys Chem Chem Phys. 2021.
PMID: 34842872
We investigate the excited-state structure of [Cu(dmp)(2)](+) and [Cu(dsbtmp)(2)](+) (dmp = 2,9-dimethyl-1,10-phenanthroline, dsbtmp = 2,9-di-sec-butyl-3,4,7,8-tetramethyl-1,10-phenanthroline) using pump-probe X-ray absorption spectroscopy (XAS) and DFT. ...
We investigate the excited-state structure of [Cu(dmp)(2)](+) and [Cu(dsbtmp)(2)](+) (dmp = 2,9-dimethyl-1,10-phenanthroline, dsbtmp = 2,9- …