Field-Induced Slow Magnetic Relaxation in a Mononuclear Manganese(III)-Porphyrin Complex.
Pascual-Álvarez A, Vallejo J, Pardo E, Julve M, Lloret F, Krzystek J, Armentano D, Wernsdorfer W, Cano J.
Pascual-Álvarez A, et al.
Chemistry. 2015 Nov 23;21(48):17299-307. doi: 10.1002/chem.201502637. Epub 2015 Oct 20.
Chemistry. 2015.
PMID: 26481722
We report on a novel manganese(III)-porphyrin complex with the formula [Mn(III) (TPP)(3,5-Me2 pyNO)2 ]ClO4 CH3 CN (2; 3,5-Me2 pyNO=3,5-dimethylpyridine N-oxide, H2 TPP=5,10,15,20-tetraphenylporphyrin), in which the Mn(III) ion is six-coordinate with two mono …
We report on a novel manganese(III)-porphyrin complex with the formula [Mn(III) (TPP)(3,5-Me2 pyNO)2 ]ClO4 CH3 CN (2; 3,5-Me2 pyNO=3 …