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Quoted phrase not found in phrase index: "amyl hydride"
Page 1
Crystal structure of N,N,N',N'-tetra-methyl-ethane-di-amine.
Schrimpf T, Otte F, Strohmann C. Schrimpf T, et al. Acta Crystallogr E Crystallogr Commun. 2022 Jan 1;78(Pt 1):36-39. doi: 10.1107/S2056989021012457. eCollection 2022 Jan 1. Acta Crystallogr E Crystallogr Commun. 2022. PMID: 35079420 Free PMC article.
The title compound N,N,N',N'-tetra-methyl-ethanedi-amine, C(6)H(16)N(2), is a bidentate amine ligand commonly used in organolithium chemistry for deaggregation. Crystals were grown at 243 K from n-pentane solution. The complete mol-ecule is generated by a crystallog …
The title compound N,N,N',N'-tetra-methyl-ethanedi-amine, C(6)H(16)N(2), is a bidentate amine ligand commonly used in organolithium chemistr …
Trimethylscandium.
Barisic D, Diether D, Maichle-Mössmer C, Anwander R. Barisic D, et al. J Am Chem Soc. 2019 Sep 4;141(35):13931-13940. doi: 10.1021/jacs.9b06879. Epub 2019 Aug 20. J Am Chem Soc. 2019. PMID: 31362492
It cocrystallizes with AlMe(3) as [Sc(AlMe(4))(3)(Al(2)Me(6))(0.5)] and decomposes at ambient temperature in n-pentane via multiple C-H bond activations to the mixed methyl/methylidene complex [Sc(3)(mu(3)-CH(2))(2)(mu(2)-CH(3))(3)(AlMe(4))(2)(AlMe(3))(2)]. ...
It cocrystallizes with AlMe(3) as [Sc(AlMe(4))(3)(Al(2)Me(6))(0.5)] and decomposes at ambient temperature in n-pentane via mul …
Proton Affinities of Alkanes.
Fu Y, Li W, Manheim JM, Milton J, Kilaz G, Kenttämaa HI. Fu Y, et al. J Am Soc Mass Spectrom. 2022 Oct 5;33(10):1850-1857. doi: 10.1021/jasms.2c00152. Epub 2022 Sep 15. J Am Soc Mass Spectrom. 2022. PMID: 36106724
Here, the PAs of several n-alkanes and alkylcyclohexanes containing 5-8 carbon atoms, n-pentane, n-hexane, n-heptane, n-octane, cyclohexane, methylcyclohexane, and ethylcyclohexane, were determined via bracketing experiments by using a linear quadrupole ion trap mas …
Here, the PAs of several n-alkanes and alkylcyclohexanes containing 5-8 carbon atoms, n-pentane, n-hexane, n-heptane, n-octane …
Unimolecular Reactions of 2,4-Dimethyloxetanyl Radicals.
Doner AC, Zádor J, Rotavera B. Doner AC, et al. J Phys Chem A. 2023 Mar 23;127(11):2591-2600. doi: 10.1021/acs.jpca.2c08290. Epub 2023 Mar 10. J Phys Chem A. 2023. PMID: 36898134 Free PMC article.
For the range of temperature over which 2,4-dimethyloxetane forms during n-pentane oxidation, the following are the major channels: 2,4-dimethyloxetan-1-yl acetaldehyde + allyl, 2,4-dimethyloxetan-2-yl propene + acetyl, and 2,4-dimethyloxetan-3-yl 3-butenal + methyl …
For the range of temperature over which 2,4-dimethyloxetane forms during n-pentane oxidation, the following are the major chan …
Anesthetic synergy between two n-alkanes.
Brosnan RJ, Fukushima FB, Pham TL. Brosnan RJ, et al. Vet Anaesth Analg. 2017 May;44(3):577-588. doi: 10.1016/j.vaa.2016.07.003. Epub 2017 Jan 11. Vet Anaesth Analg. 2017. PMID: 28583773 Free PMC article.
OBJECTIVE: N-butane and n-pentane can both produce general anesthesia. Both compounds potentiate gamma-aminobutyric acid type A (GABA(A)) receptor function, but only butane inhibits N-methyl-d-aspartate (NMDA) receptors. ...Butane dose-dependently inhibited NMDA rec …
OBJECTIVE: N-butane and n-pentane can both produce general anesthesia. Both compounds potentiate gamma-aminobutyric acid type …
Rare-earth-metal trimethylsilylmethyl ate complexes.
Mortis A, Kracht F, Berger T, Lebon J, Maichle-Mössmer C, Anwander R. Mortis A, et al. Dalton Trans. 2022 Dec 20;52(1):44-51. doi: 10.1039/d2dt03491c. Dalton Trans. 2022. PMID: 36477971
En route to putative rare-earth-metal alkylidene complex Li[Lu(CH(2)SiMe(3))(2)(CHSiMe(3))], according to Schumann's original protocol, the reaction of YCl(3) with LiCH(2)SiMe(3) in a mixture of diethyl ether and n-pentane afforded a neosilyl ate complex of composit …
En route to putative rare-earth-metal alkylidene complex Li[Lu(CH(2)SiMe(3))(2)(CHSiMe(3))], according to Schumann's original protocol, the …
n-Pentane. CAS# 109-66-0.
Galvin JB, Marashi F. Galvin JB, et al. J Toxicol Environ Health A. 1999 Sep 10-24;58(1-2):35-56. doi: 10.1080/009841099157412. J Toxicol Environ Health A. 1999. PMID: 10537371 Review. No abstract available.
Bis[1,2-bis-(4-tert-butyl-phen-yl)ethyl-ene-1,2-di-thiol-ato(1-)]nickel(II) pentane 0.25-solvate.
Das Gupta T, Applebaum J, Broussard W, Mack C, Wu C, Mague JT, Donahue JP. Das Gupta T, et al. Acta Crystallogr E Crystallogr Commun. 2023 Feb 17;79(Pt 3):182-186. doi: 10.1107/S205698902300097X. eCollection 2023 Feb 1. Acta Crystallogr E Crystallogr Commun. 2023. PMID: 36910003 Free PMC article.
The title compound, [Ni(C(22)H(26)S(2))(2)], 1, is a square-planar D (2h) -symmetric compound that occurs on a general position in non-centrosymmetric tetra-gonal P4(1)2(1)2 (No. 92) with eq of n-pentane (C(5)H(12)) as co-crystallite. Intra-ligand bond lengths show …
The title compound, [Ni(C(22)H(26)S(2))(2)], 1, is a square-planar D (2h) -symmetric compound that occurs on a general position in non-centr …
Vapor-phase nucleation of n-pentane, n-hexane, and n-heptane: Critical cluster properties.
Ogunronbi KE, Wyslouzil BE. Ogunronbi KE, et al. J Chem Phys. 2019 Oct 21;151(15):154307. doi: 10.1063/1.5123284. J Chem Phys. 2019. PMID: 31640360
Here, we report the size n(*) and excess internal energy E(x)(n(*)) of n-pentane, n-hexane, and n-heptane critical clusters when particles form under the highly supersaturated conditions present in supersonic expansions. ...
Here, we report the size n(*) and excess internal energy E(x)(n(*)) of n-pentane, n-hexane, and n-heptane critical clusters wh …
Synthesis of Carborane-Backbone Metallacycles for Highly Selective Capture of n-Pentane.
Guo ST, Cui PF, Liu XR, Jin GX. Guo ST, et al. J Am Chem Soc. 2022 Dec 7;144(48):22221-22228. doi: 10.1021/jacs.2c10201. Epub 2022 Nov 28. J Am Chem Soc. 2022. PMID: 36442076
Here, rectangular carborane-based metallacycles were designed to selectively encapsulate n-pentane from n-pentane, iso-pentane, and cyclo-pentane mixtures in a simple-to-operate and more energy-efficient way. ...Besides, the removal of …
Here, rectangular carborane-based metallacycles were designed to selectively encapsulate n-pentane from n-pentane
2,754 results