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Page 1
Preparation of Azinones from (Cyclopropylmethoxy)azine Ethers.
Londregan AT, Curto JM, Hastry E, Rose CR, Berritt S. Londregan AT, et al. J Org Chem. 2023 May 5;88(9):5671-5675. doi: 10.1021/acs.joc.3c00145. Epub 2023 Apr 18. J Org Chem. 2023. PMID: 37071494
A general and convenient procedure for the synthesis of azinones is presented. Cyclopropylmethanol is readily introduced onto various azines where it functions as both a protecting group and surrogate for hydroxyl. ...
A general and convenient procedure for the synthesis of azinones is presented. Cyclopropylmethanol is readily introduced onto various …
Strategic hazard mitigation of waste furniture boards via pyrolysis: Pyrolysis behavior, mechanisms, and value-added products.
Foong SY, Liew RK, Lee CL, Tan WP, Peng W, Sonne C, Tsang YF, Lam SS. Foong SY, et al. J Hazard Mater. 2022 Jan 5;421:126774. doi: 10.1016/j.jhazmat.2021.126774. Epub 2021 Jul 29. J Hazard Mater. 2022. PMID: 34364214
This result indicates that WFBs are not recommended to be burned directly as fuel, however, they can be pyrolyzed and converted into solid pyrolytic products such as biochar with improved properties for fuel application. Hazardous components, such as cyclopropylmethanol, w …
This result indicates that WFBs are not recommended to be burned directly as fuel, however, they can be pyrolyzed and converted into solid p …
RIFM fragrance ingredient safety assessment, cyclopropanemethanol, 1-methyl-2-[(1,2,2-trimethylbicyclo[3.1.0]hex-3-yl)methyl]-, CAS Registry Number 198404-98-7.
Api AM, Belsito D, Biserta S, Botelho D, Bruze M, Burton GA Jr, Buschmann J, Cancellieri MA, Dagli ML, Date M, Dekant W, Deodhar C, Fryer AD, Gadhia S, Jones L, Joshi K, Kumar M, Lapczynski A, Lavelle M, Lee I, Liebler DC, Moustakas H, Na M, Penning TM, Ritacco G, Romine J, Sadekar N, Schultz TW, Selechnik D, Siddiqi F, Sipes IG, Sullivan G, Thakkar Y, Tokura Y. Api AM, et al. Food Chem Toxicol. 2021 Jul;153 Suppl 1:112168. doi: 10.1016/j.fct.2021.112168. Epub 2021 Apr 6. Food Chem Toxicol. 2021. PMID: 33831501 Review. No abstract available.
RIFM fragrance ingredient safety assessment, cyclopropanemethanol, 1-methyl-2-[[(1R,3R)-2,2,3-trimethylcyclopentyl]methyl]-, (1R,2R)-, CAS Registry Number 1181244-95-0.
Api AM, Belsito D, Biserta S, Botelho D, Bruze M, Burton GA Jr, Buschmann J, Cancellieri MA, Dagli ML, Date M, Dekant W, Deodhar C, Fryer AD, Gadhia S, Jones L, Joshi K, Kumar M, Lapczynski A, Lavelle M, Lee I, Liebler DC, Moustakas H, Na M, Penning TM, Ritacco G, Romine J, Sadekar N, Schultz TW, Selechnik D, Siddiqi F, Sipes IG, Sullivan G, Thakkar Y, Tokura Y. Api AM, et al. Food Chem Toxicol. 2021 Jul;153 Suppl 1:112203. doi: 10.1016/j.fct.2021.112203. Epub 2021 Apr 16. Food Chem Toxicol. 2021. PMID: 33872727 Review. No abstract available.
Characterization of a novel cyfluthrin-degrading bacterial strain Brevibacterium aureum and its biochemical degradation pathway.
Chen S, Dong YH, Chang C, Deng Y, Zhang XF, Zhong G, Song H, Hu M, Zhang LH. Chen S, et al. Bioresour Technol. 2013 Mar;132:16-23. doi: 10.1016/j.biortech.2013.01.002. Epub 2013 Jan 11. Bioresour Technol. 2013. PMID: 23395753
The bacterium degraded cyfluthrin by cleavage of both the carboxylester linkage and diaryl bond to form 2,2,3,3-tetramethyl-cyclopropanemethanol, 4-fluoro-3-phenexy-benzoic acid, 3,5-dimethoxy phenol, and phenol, and subsequently transformed these compounds with a maximum …
The bacterium degraded cyfluthrin by cleavage of both the carboxylester linkage and diaryl bond to form 2,2,3,3-tetramethyl-cyclopropanem
Stereodivergent carbometalation reactions of cyclopropenylcarbinol derivatives.
Simaan S, Marek I. Simaan S, et al. Org Lett. 2007 Jun 21;9(13):2569-71. doi: 10.1021/ol070974x. Epub 2007 May 31. Org Lett. 2007. PMID: 17536813
The diastereoselective formation of cyclopropylcarbinol from cyclopropenylcarbinol is very sensitive to the nature of the organometallic used for the carbometalation reaction. ...
The diastereoselective formation of cyclopropylcarbinol from cyclopropenylcarbinol is very sensitive to the nature of the organometal …
Cyclopropenylcarbinol derivatives as new versatile intermediates in organic synthesis: application to the formation of enantiomerically pure alkylidenecyclopropane derivatives.
Simaan S, Masarwa A, Zohar E, Stanger A, Bertus P, Marek I. Simaan S, et al. Chemistry. 2009 Aug 24;15(34):8449-8464. doi: 10.1002/chem.200901074. Chemistry. 2009. PMID: 19609999
To gain further insight into the reaction mechanism of the carbometalation, the diastereoselective formation of cyclopropylcarbinol was also achieved and was found to be very sensitive to the nature of the organometallic species used for the addition reaction. Cycloprop
To gain further insight into the reaction mechanism of the carbometalation, the diastereoselective formation of cyclopropylcarbinol w …
Total synthesis of zincophorin and its methyl ester.
Defosseux M, Blanchard N, Meyer C, Cossy J. Defosseux M, et al. J Org Chem. 2004 Jul 9;69(14):4626-47. doi: 10.1021/jo0496042. J Org Chem. 2004. PMID: 15230584
The route features an intramolecular oxymercuration of a cyclopropanemethanol and a Carroll-Claisen rearrangement for the respective elaboration of the C1-C12 and C13-C25 subunits, which have been assembled by using a highly diastereoselective titanium-mediated aldol conde …
The route features an intramolecular oxymercuration of a cyclopropanemethanol and a Carroll-Claisen rearrangement for the respective …
Anesthetic cutoff in cycloalkanemethanols. A test of current theories.
Raines DE, Korten SE, Hill AG, Miller KW. Raines DE, et al. Anesthesiology. 1993 May;78(5):918-27. doi: 10.1097/00000542-199305000-00017. Anesthesiology. 1993. PMID: 8489064 Free article.
The change in order parameter induced by cycloalkanemethanols and n-alkanols in lipid bilayers made of egg phosphatidylcholine and cholesterol was measured with electron paramagnetic resonance spectroscopy. RESULTS: On ascending the series from cyclopropanemethanol (EC50 = …
The change in order parameter induced by cycloalkanemethanols and n-alkanols in lipid bilayers made of egg phosphatidylcholine and cholester …
Structural and functional characterization of an anesthetic binding site in the second cysteine-rich domain of protein kinase Cδ*.
Shanmugasundararaj S, Das J, Sandberg WS, Zhou X, Wang D, Messing RO, Bruzik KS, Stehle T, Miller KW. Shanmugasundararaj S, et al. Biophys J. 2012 Dec 5;103(11):2331-40. doi: 10.1016/j.bpj.2012.10.034. Biophys J. 2012. PMID: 23283232 Free PMC article.
We solved the structure of the phorbol-binding domain (C1B) of PKCdelta complexed with an ether (methoxymethylcycloprane) and with an alcohol (cyclopropylmethanol) at 1.36-A resolution. The cyclopropane rings of both agents displace a single water molecule in a surface poc …
We solved the structure of the phorbol-binding domain (C1B) of PKCdelta complexed with an ether (methoxymethylcycloprane) and with an alcoho …
33 results