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340 results

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Quoted phrases not found in phrase index: "methyl formiate", "methyl methanoate"
Page 1
Concentrated Formic Acid from CO2 Electrolysis for Directly Driving Fuel Cell.
Zhang C, Hao X, Wang J, Ding X, Zhong Y, Jiang Y, Wu MC, Long R, Gong W, Liang C, Cai W, Low J, Xiong Y. Zhang C, et al. Angew Chem Int Ed Engl. 2024 Mar 22;63(13):e202317628. doi: 10.1002/anie.202317628. Epub 2024 Feb 20. Angew Chem Int Ed Engl. 2024. PMID: 38305482
To assess the practicality of this system, we perform a comprehensive techno-economic analysis and life cycle assessment, showing that our approach can potentially substitute conventional methyl formate hydrolysis for industrial formic acid production. Furthermore, …
To assess the practicality of this system, we perform a comprehensive techno-economic analysis and life cycle assessment, showing that our a …
Selective oxidation conversion of methanol/dimethyl ether.
Gao X, Zhang J, Song F, Zhang Q, Han Y, Tan Y. Gao X, et al. Chem Commun (Camb). 2022 Apr 12;58(30):4687-4699. doi: 10.1039/d1cc07276e. Chem Commun (Camb). 2022. PMID: 35302128 Review.
In this feature article, we have summarized the recent advances in the synthesis of formaldehyde, methyl formate, dimethoxymethane, and polyoxymethylene dimethyl ethers, from the selective oxidation of methanol/DME, and further discussed the adsorption and activatio …
In this feature article, we have summarized the recent advances in the synthesis of formaldehyde, methyl formate, dimethoxymet …
Analytical method development, validation, and out-of-specification investigations for polyethylene glycol.
Huang TC, Chu G, Singh S. Huang TC, et al. J Pharm Biomed Anal. 2023 Oct 25;235:115613. doi: 10.1016/j.jpba.2023.115613. Epub 2023 Jul 31. J Pharm Biomed Anal. 2023. PMID: 37544274
During the OOS root cause investigations, we observed a PEG degradant and identified it as methyl formate, which co-elutes with ethylene oxide using the GC (gas chromatography) methods published in current USP-NF and Ph. ...With this new method, ethylene oxide, a kn …
During the OOS root cause investigations, we observed a PEG degradant and identified it as methyl formate, which co-elutes wit …
Photocatalytic Aqueous Reforming of Methyl Formate.
Zuo D, Pradhan S, Banerjee M, Rockstroh N, Bartling S, Rabee AIM, Tian X, Skorynina A, Jaworski A, Simonelli L, Rabeah J, Jiao H, Beller M, Das S. Zuo D, et al. Adv Mater. 2025 Oct;37(39):e2509890. doi: 10.1002/adma.202509890. Epub 2025 Jul 11. Adv Mater. 2025. PMID: 40643033 Free PMC article.
This study aims to report on the first example of a 3d-metal-based (Cu) heterogeneous photocatalytic system to produce green hydrogen via dehydrogenation of methyl formate (MF), a reaction previously known to require 4d/5d transition metals. Employing a Cu-based ato …
This study aims to report on the first example of a 3d-metal-based (Cu) heterogeneous photocatalytic system to produce green hydrogen via de …
Methyl 2,2'-dimethyl-4'-[2-(methyl-sulfan-yl)eth-yl]-1,3-dioxo-2,3-dihydro-1H,4'H-spiro-[isoquinoline-4,5'-oxazole]-4'-carboxyl-ate.
Fun HK, Quah CK, Huang C, Yu H. Fun HK, et al. Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2216-7. doi: 10.1107/S1600536811030133. Epub 2011 Aug 2. Acta Crystallogr Sect E Struct Rep Online. 2011. PMID: 22058900 Free PMC article.
In the isoquinoline ring system of the title mol-ecule, C(18)H(20)N(2)O(5)S, the fused N-heterocyclic ring is distorted towards a half-boat conformation. The methyl formate moiety is disordered over two sets of sites with refined occupancies of 0.882 (5) and 0.118 ( …
In the isoquinoline ring system of the title mol-ecule, C(18)H(20)N(2)O(5)S, the fused N-heterocyclic ring is distorted towards a half-boat …
A Spontaneously Electrical State of Matter.
Cassidy A, McCoustra MRS, Field D. Cassidy A, et al. Acc Chem Res. 2023 Jul 18;56(14):1909-1919. doi: 10.1021/acs.accounts.3c00094. Epub 2023 Jun 9. Acc Chem Res. 2023. PMID: 37294136
Species as diverse as carbon monoxide, nitrous oxide, freons, simple alcohols, and cis-methyl formate have been demonstrated to spontaneously generate electric fields. We have reported electric fields more than 10(8) V m(-1), have shown how field strength varies wit …
Species as diverse as carbon monoxide, nitrous oxide, freons, simple alcohols, and cis-methyl formate have been demonstrated t …
Urinary methanol and formic acid as indicators of occupational exposure to methyl formate.
Berode M, Sethre T, Läubli T, Savolainen H. Berode M, et al. Int Arch Occup Environ Health. 2000 Aug;73(6):410-4. doi: 10.1007/s004200000160. Int Arch Occup Environ Health. 2000. PMID: 11007345
OBJECTIVE: To evaluate the validity of methanol (MeOH) and formic acid (FA) in urine as biological indicators of methyl formate (MF) exposure in experimental and field situations. METHODS: The subjects were 28 foundrymen and two groups of volunteers (20 control and …
OBJECTIVE: To evaluate the validity of methanol (MeOH) and formic acid (FA) in urine as biological indicators of methyl formate …
Synthesis of porritoxin.
Cornella I, Kelly TR. Cornella I, et al. J Org Chem. 2004 Mar 19;69(6):2191-3. doi: 10.1021/jo0356210. J Org Chem. 2004. PMID: 15058971
A key reaction was the use of iron pentacarbonyl to formylate an aryllithium when DMF and methyl formate proved insufficiently reactive....
A key reaction was the use of iron pentacarbonyl to formylate an aryllithium when DMF and methyl formate proved insufficiently …
Towards biotechnological production of bio-based low molecular weight esters: a patent review.
Zago M, Branduardi P, Serra I. Zago M, et al. RSC Adv. 2024 Sep 18;14(40):29472-29489. doi: 10.1039/d4ra04131c. eCollection 2024 Sep 12. RSC Adv. 2024. PMID: 39297040 Free PMC article. Review.
Low molecular weight (LMW) esters, like ethyl acetate, methyl formate or butyl acetate, are widespread bulk chemicals in many industries. Each of them is currently produced in huge amounts (millions of tons per year scale) starting from fossil-based feedstock and th …
Low molecular weight (LMW) esters, like ethyl acetate, methyl formate or butyl acetate, are widespread bulk chemicals in many …
Polyoxometalate-Modified Amphiphilic Polystyrene-block-poly(2-(dimethylamino)ethyl methacrylate) Membranes for Heterogeneous Glucose to Formic Acid Methyl Ester Oxidation.
Utievskyi Y, Neumann C, Sindlinger J, Schutjajew K, Oschatz M, Turchanin A, Ueberschaar N, Schacher FH. Utievskyi Y, et al. Nanomaterials (Basel). 2023 Sep 5;13(18):2498. doi: 10.3390/nano13182498. Nanomaterials (Basel). 2023. PMID: 37764527 Free PMC article.
Herein, we present a new heterogeneous catalyst active toward glucose to formic acid methyl ester oxidation. The catalyst was fabricated via electrostatic immobilization of the inorganic polyoxometalate HPA-5 catalyst H(8)[PMo(7)V(5)O(40)] onto the por …
Herein, we present a new heterogeneous catalyst active toward glucose to formic acid methyl ester oxidation. The …
340 results