Strong Ferromagnetic Exchange Coupling and Single-Molecule Magnetism in MoS43--Bridged Dilanthanide Complexes.
Darago LE, Boshart MD, Nguyen BD, Perlt E, Ziller JW, Lukens WW, Furche F, Evans WJ, Long JR.
Darago LE, et al.
J Am Chem Soc. 2021 Jun 9;143(22):8465-8475. doi: 10.1021/jacs.1c03098. Epub 2021 May 24.
J Am Chem Soc. 2021.
PMID: 34029482
UV-Vis-NIR diffuse reflectance spectra and DFT calculations of 1-Ln reveal a low-energy metal-to-metal charge transfer transition assigned to charge transfer from the singly occupied 4d(z(2)) orbital of Mo(V) to the empty 5d orbitals of the lanthanides (4d in the case of 1 …
UV-Vis-NIR diffuse reflectance spectra and DFT calculations of 1-Ln reveal a low-energy metal-to-metal charge transfer transition assigned t …