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Coexistence of chrysanthenone, filifolone and (Z)-isogeranic acid in hydrodistillates. Artefacts!
Asfaw N, Storesund HJ, Skattebøl L, Aasen AJ. Asfaw N, et al. Phytochemistry. 2001 Oct;58(3):489-92. doi: 10.1016/s0031-9422(01)00254-0. Phytochemistry. 2001. PMID: 11557082
Hydrodistilled oil from leaves of the Ethiopian plant Laggera tomentosa has been shown to contain (-)-chrysanthenone (5%), (-)/(+)-filifolone (92:8; 8%) and (Z)-isogeranic acid (8%)-all likely to be artefacts. The main constituent of the oil, (+)-chrysantheno …
Hydrodistilled oil from leaves of the Ethiopian plant Laggera tomentosa has been shown to contain (-)-chrysanthenone (5%), (-)/(+)-filifolon …
A new, ring closing metathesis-based synthesis of (-)-fumagillol.
Boiteau JG, Van de Weghe P, Eustache J. Boiteau JG, et al. Org Lett. 2001 Aug 23;3(17):2737-40. doi: 10.1021/ol016343z. Org Lett. 2001. PMID: 11506622
The synthesis also features an efficient preparation of isogeraniol and isogeranic acid....
The synthesis also features an efficient preparation of isogeraniol and isogeranic acid....