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Determination of 2,4,6-tribromoaniline in the color additives D&C Red Nos. 21 and 22 (Eosin Y) using solid-phase microextraction and gas chromatography-mass spectrometry.
Weisz A, Andrzejewski D, Rasooly IR. Weisz A, et al. J Chromatogr A. 2004 Nov 19;1057(1-2):185-91. doi: 10.1016/j.chroma.2004.09.065. J Chromatogr A. 2004. PMID: 15584238
The present work demonstrates the presence of an impurity, 2,4,6-tribromoaniline (TBA), in the color additives D&C Red Nos. 21 and 21 lake (21L) and describes the determination of TBA in certified lots of D&C Red Nos. 21, 21L and 22 (Eosin Y). …
The present work demonstrates the presence of an impurity, 2,4,6-tribromoaniline (TBA), in the color additives D …
Degradation kinetics and formation of regulated and emerging disinfection by-products during chlorination of two expectorants ambroxol and bromhexine.
Wang W, Zhou Z, Ding S, Yang W, Jin W, Chu W, Xu Z. Wang W, et al. Water Res. 2023 May 15;235:119927. doi: 10.1016/j.watres.2023.119927. Epub 2023 Mar 29. Water Res. 2023. PMID: 37023645
During chlorination, a new class of aromatic nitrogenous disinfection by-products (DBPs) including 2-chloro-4, 6-dibromoaniline and 2, 4, 6-tribromoaniline were identified as the intermediate aromatic DBPs by gas chromatography-mass spectrometry. The e …
During chlorination, a new class of aromatic nitrogenous disinfection by-products (DBPs) including 2-chloro-4, 6-dibromoaniline and 2 …
DFT computational study of trihalogenated aniline derivative's adsorption onto graphene/fullerene/fullerene-like nanocages, X12Y12 (X = Al, B, and Y = N, P).
Al-Otaibi JS, Mary YS, Mary YS, Kaya S, Serdaroglu G. Al-Otaibi JS, et al. J Biomol Struct Dyn. 2022;40(19):8630-8643. doi: 10.1080/07391102.2021.1914172. Epub 2021 Apr 20. J Biomol Struct Dyn. 2022. PMID: 33876711
Adsorption of 2,4,6-tribromoaniline (BA), 2,4,6-trifluoroaniline (FA) and 2,4,6-trichloroaniline (CA) onto the surface of coronene/fullerene/fullerene-like nanocages was investigated by theoretical calculations. ...
Adsorption of 2,4,6-tribromoaniline (BA), 2,4,6-trifluoroaniline (FA) and 2,4,6-trichloroaniline (CA) onto the s …
Facile and sensitive spectrophotometric determination of carbosulfan in formulations and environmental samples.
Kumar KS, Suvardhan K, Rekha D, Kiran K, Rao GC, Jayaraj B, Janardhanam K, Chiranjeevi P. Kumar KS, et al. Environ Monit Assess. 2007 Jun;129(1-3):271-6. doi: 10.1007/s10661-006-9360-0. Epub 2006 Sep 7. Environ Monit Assess. 2007. PMID: 16957837
The method was based on acid and alkaline hydrolysis of the carbosulfan pesticide, and the resultant hydrolysis product of carbosulfan was coupled with 2,6-dibromo-4-methylaniline to give a yellow color product with lambda(max) of 464 nm or interaction with 2,6-dibromo-4-nitroani …
The method was based on acid and alkaline hydrolysis of the carbosulfan pesticide, and the resultant hydrolysis product of carbosulfan was c …
Composite Flame Retardants Based on Conjugated Microporous Polymer Hollow Nanospheres with Excellent Flame Retardancy.
Ma C, Su M, Zhu Z. Ma C, et al. ACS Omega. 2024 Feb 22;9(9):10478-10487. doi: 10.1021/acsomega.3c08597. eCollection 2024 Mar 5. ACS Omega. 2024. PMID: 38463341 Free PMC article.
Herein, conjugated microporous polymers hollow nanospheres (CMPs-HNS) were prepared by Sonogashira-Hagihara cross-coupling reaction with 1,3,5-triacetylenebenzene, 3-amino-2,6-dibromopyridine, and 2,4,6-tribromoaniline as building blocks using SiO(2) n …
Herein, conjugated microporous polymers hollow nanospheres (CMPs-HNS) were prepared by Sonogashira-Hagihara cross-coupling reaction with 1,3 …
Halogenated anilines as novel natural products from a marine biofilm forming microalga.
Baumeister TUH, Staudinger M, Wirgenings M, Pohnert G. Baumeister TUH, et al. Chem Commun (Camb). 2019 Oct 1;55(79):11948-11951. doi: 10.1039/c9cc05992j. Chem Commun (Camb). 2019. PMID: 31531452
The toxic halogenated anilines 2,4,6-tribromoaniline, 2,4,6-trichloroaniline and their dibromochloro and bromodichloro derivatives were considered as compounds of exclusive synthetic origin. ...
The toxic halogenated anilines 2,4,6-tribromoaniline, 2,4,6-trichloroaniline and their dibromochloro and bromodi …
Development of simple and sensitive spectrophotometric method for the determination of bendiocarb in its formulations and environmental samples.
Kumar KS, Suvardhan K, Rekha D, Kiran K, Jayaraj B, Janardhanam K, Chiranjeevi P. Kumar KS, et al. Environ Monit Assess. 2007 Apr;127(1-3):67-72. doi: 10.1007/s10661-006-9259-9. Epub 2006 Aug 5. Environ Monit Assess. 2007. PMID: 16897507
The method was based on alkaline hydrolysis of the bendiocarb pesticide, and the resultant hydrolysis product of bendiocarb was coupled with 2,6-dibromo-4-methylaniline to give a yellow color product with lambda max of 457 nm or coupling with 2, 6-dibromo-4-nitroaniline to produc …
The method was based on alkaline hydrolysis of the bendiocarb pesticide, and the resultant hydrolysis product of bendiocarb was coupled with …
Titrimetric determination of aminobenzoic acids.
Amin D, El-Samman FM, Abdulahed-Malalla H. Amin D, et al. Talanta. 1985 Jan;32(1):66-77. doi: 10.1016/0039-9140(85)80022-9. Talanta. 1985. PMID: 18963792
A novel titrimetric method for determination of aminobenzoic acids is based on their reaction with excess of bromine to form N-bromo-2,4,6-tribromoaniline, which liberates an equivalent amount of iodine when treated with iodide. ...
A novel titrimetric method for determination of aminobenzoic acids is based on their reaction with excess of bromine to form N-bromo-2 …
Halogenated organic contaminants in sediments of the Havel and Spree rivers (Germany). Part 5 of organic compounds as contaminants of the Elbe river and its tributaries.
Schwarzbauer J, Ricking M, Franke S, Francke W. Schwarzbauer J, et al. Environ Sci Technol. 2001 Oct 15;35(20):4015-25. doi: 10.1021/es010084r. Environ Sci Technol. 2001. PMID: 11686361
A third group of halogen compounds emitted at this site consisted of the pesticides bromopropylate, methoxychlor, and chlorfensone as well as specific brominated aromatics including 2,4,6-tribromoaniline, 4,4'-dibromobenzophenone, and brominated benzen …
A third group of halogen compounds emitted at this site consisted of the pesticides bromopropylate, methoxychlor, and chlorfensone as well a …