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Determination of the absolute structure of (+)-akaterpin.
Hosoi H, Kawai N, Hagiwara H, Suzuki T, Nakazaki A, Takao K, Umezawa K, Kobayashi S. Hosoi H, et al. Chem Pharm Bull (Tokyo). 2012;60(1):137-43. doi: 10.1248/cpb.60.137. Chem Pharm Bull (Tokyo). 2012. PMID: 22223385 Free article.
We describe the total synthesis and structural determination of (+)-akaterpin (1), an inhibitor of phosphatidylinositol-specific phospholipase C (PI-PLC). The key features of the synthetic strategy include the resolution of beta,gamma-unsaturated ketone ( )-2a with chiral …
We describe the total synthesis and structural determination of (+)-akaterpin (1), an inhibitor of phosphatidylinositol-specific phos …
[Screening of phosphatidylinositol turnover inhibitors and regulation of cell cycle progression].
Umezawa K, Deguchi A, Imoto M. Umezawa K, et al. Gan To Kagaku Ryoho. 1997 Sep;24(11):1578-84. Gan To Kagaku Ryoho. 1997. PMID: 9309157 Review. Japanese.
We have isolated pholipeptin and fluvirucin B2 from microorganisms and akaterpin from a marine sponge as PLC gamma inhibitors. We also isolated echiguanines from Streptomyces as PI4-kinase inhibitors. ...
We have isolated pholipeptin and fluvirucin B2 from microorganisms and akaterpin from a marine sponge as PLC gamma inhibitors. We als …