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An experimental and computational analysis of the formation of the terminal nitrido complex (eta3-Cp*)2Mo(N)(N3) by elimination of N2 from Cp*2Mo(N3)2: the barrier to elimination is strongly influenced by the exo versus endo configuration of the azide ligand.
Shin JH, Bridgewater BM, Churchill DG, Baik MH, Friesner RA, Parkin G. Shin JH, et al. Among authors: bridgewater bm. J Am Chem Soc. 2001 Oct 17;123(41):10111-2. doi: 10.1021/ja011416v. J Am Chem Soc. 2001. PMID: 11592896 No abstract available.
The electronic influence of ring substituents and ansa bridges in zirconocene complexes as probed by infrared spectroscopic, electrochemical, and computational studies.
Zachmanoglou CE, Docrat A, Bridgewater BM, Parkin G, Brandow CG, Bercaw JE, Jardine CN, Lyall M, Green JC, Keister JB. Zachmanoglou CE, et al. Among authors: bridgewater bm. J Am Chem Soc. 2002 Aug 14;124(32):9525-46. doi: 10.1021/ja020236y. J Am Chem Soc. 2002. PMID: 12167048 Free article.