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Synthesis of polyynes to model the sp-carbon allotrope carbyne.
Chalifoux WA, Tykwinski RR. Chalifoux WA, et al. Nat Chem. 2010 Nov;2(11):967-71. doi: 10.1038/nchem.828. Epub 2010 Sep 19. Nat Chem. 2010. PMID: 20966954
tert-Butyl-end-capped polyynes: crystallographic evidence of reduced bond-length alternation.
Chalifoux WA, McDonald R, Ferguson MJ, Tykwinski RR. Chalifoux WA, et al. Angew Chem Int Ed Engl. 2009;48(42):7915-9. doi: 10.1002/anie.200902760. Angew Chem Int Ed Engl. 2009. PMID: 19670283 No abstract available.
Polyyne synthesis using carbene/carbenoid rearrangements.
Chalifoux WA, Tykwinski RR. Chalifoux WA, et al. Chem Rec. 2006;6(4):169-82. doi: 10.1002/tcr.20081. Chem Rec. 2006. PMID: 16902994
Direct and highly regioselective and enantioselective allylation of β-diketones.
Chalifoux WA, Reznik SK, Leighton JL. Chalifoux WA, et al. Nature. 2012 Jul 5;487(7405):86-9. doi: 10.1038/nature11189. Nature. 2012. PMID: 22763452 Free PMC article.
Multicomponent Double Diels-Alder/Nazarov Tandem Cyclization of Symmetric Cross-Conjugated Diynones to Generate [6-5-6] Tricyclic Products.
Carmichael RA, Chalifoux WA. Carmichael RA, et al. Among authors: chalifoux wa. Chemistry. 2016 Jun 20;22(26):8781-5. doi: 10.1002/chem.201601850. Epub 2016 May 17. Chemistry. 2016. PMID: 27124516
Evidence for solution-state nonlinearity of sp-carbon chains based on IR and Raman spectroscopy: violation of mutual exclusion.
Lucotti A, Tommasini M, Fazzi D, Del Zoppo M, Chalifoux WA, Ferguson MJ, Zerbi G, Tykwinski RR. Lucotti A, et al. Among authors: chalifoux wa. J Am Chem Soc. 2009 Apr 1;131(12):4239-44. doi: 10.1021/ja078198b. J Am Chem Soc. 2009. PMID: 19199614
Mechanistic aspects of alkyne migration in alkylidene carbenoid rearrangements.
Bichler P, Chalifoux WA, Eisler S, Shi Shun AL, Chernick ET, Tykwinski RR. Bichler P, et al. Among authors: chalifoux wa. Org Lett. 2009 Feb 5;11(3):519-22. doi: 10.1021/ol8023665. Org Lett. 2009. PMID: 19128149
The Synthesis of Non-planar, Helically Coiled Graphene Nanoribbons.
Chalifoux WA. Chalifoux WA. Angew Chem Int Ed Engl. 2017 Jul 3;56(28):8048-8050. doi: 10.1002/anie.201702687. Epub 2017 May 9. Angew Chem Int Ed Engl. 2017. PMID: 28485487
Highly Regioselective Domino Benzannulation Reaction of Buta-1,3-diynes To Construct Irregular Nanographenes.
Yang W, Bam R, Catalano VJ, Chalifoux WA. Yang W, et al. Among authors: chalifoux wa. Angew Chem Int Ed Engl. 2018 Nov 5;57(45):14773-14777. doi: 10.1002/anie.201808043. Epub 2018 Sep 11. Angew Chem Int Ed Engl. 2018. PMID: 30117244
Pyrenes, Peropyrenes, and Teropyrenes: Synthesis, Structures, and Photophysical Properties.
Yang W, Monteiro JH, de Bettencourt-Dias A, Catalano VJ, Chalifoux WA. Yang W, et al. Among authors: chalifoux wa. Angew Chem Int Ed Engl. 2016 Aug 22;55(35):10427-30. doi: 10.1002/anie.201604741. Epub 2016 Jul 26. Angew Chem Int Ed Engl. 2016. PMID: 27457893
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