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Reactivity of Tp(Me2) -supported yttrium alkyl complexes toward aromatic N-heterocycles: ring-opening or C-C bond formation directed by C-H activation.
Yi W, Zhang J, Huang S, Weng L, Zhou X. Yi W, et al. Chemistry. 2014 Jan 13;20(3):867-76. doi: 10.1002/chem.201303608. Epub 2013 Dec 11. Chemistry. 2014. PMID: 24339020
The scorpionate-anchored yttrium dialkyl complex [Tp(Me2) Y(CH2 Ph)2 (THF)] reacted with 1-methylimidazole in 1:2 molar ratio to give a rare hexanuclear 24-membered rare-earth metallomacrocyclic compound [Tp(Me2) Y(mu-N,C-Im)(eta(2) -N,C-Im)]6 (1; Im=1-methylimidazolyl) through t …
The scorpionate-anchored yttrium dialkyl complex [Tp(Me2) Y(CH2 Ph)2 (THF)] reacted with 1-methylimidazole in 1:2 molar ratio to give a rare …