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Total synthesis and stereochemistry of cytoblastin.
Moreno OA, Kishi Y. Moreno OA, et al. Bioorg Med Chem. 1998 Aug;6(8):1243-54. doi: 10.1016/s0968-0896(98)00113-8. Bioorg Med Chem. 1998. PMID: 9784866
The first total synthesis and stereochemical assignment of cytoblastin were reported. Key steps included the palladium-mediated coupling of N-SEM-7-bromoindolactam V ((-)-11) with allylstannane c-13, and osmium tetroxide-mediated dihydroxylation of 14, both of which were s …
The first total synthesis and stereochemical assignment of cytoblastin were reported. Key steps included the palladium-mediated coupl …
Low molecular weight immunomodulators produced by microorganisms.
Ishizuka M, Kawatsu M, Yamashita T, Ueno M, Takeuchi T. Ishizuka M, et al. Int J Immunopharmacol. 1995 Feb;17(2):133-39. doi: 10.1016/0192-0561(94)00086-4. Int J Immunopharmacol. 1995. PMID: 7657405
In order to develop a new class of low molecular weight immunomodulators for the treatment of incurable diseases involving cancer, hematologic diseases and inflammation, we have sought cytokine inducers and inhibitors of cell adhesion to the extracellular matrix among the low mol …
In order to develop a new class of low molecular weight immunomodulators for the treatment of incurable diseases involving cancer, hematolog …