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Major Mo(V) EPR signature of Rhodobacter sphaeroides periplasmic nitrate reductase arising from a dead-end species that activates upon reduction. Relation to other molybdoenzymes from the DMSO reductase family.
Fourmond V, Burlat B, Dementin S, Arnoux P, Sabaty M, Boiry S, Guigliarelli B, Bertrand P, Pignol D, Léger C. Fourmond V, et al. Among authors: dementin s. J Phys Chem B. 2008 Dec 4;112(48):15478-86. doi: 10.1021/jp807092y. J Phys Chem B. 2008. PMID: 19006273
Experimental approaches to kinetics of gas diffusion in hydrogenase.
Leroux F, Dementin S, Burlat B, Cournac L, Volbeda A, Champ S, Martin L, Guigliarelli B, Bertrand P, Fontecilla-Camps J, Rousset M, Léger C. Leroux F, et al. Among authors: dementin s. Proc Natl Acad Sci U S A. 2008 Aug 12;105(32):11188-93. doi: 10.1073/pnas.0803689105. Epub 2008 Aug 6. Proc Natl Acad Sci U S A. 2008. PMID: 18685111 Free PMC article.
Introduction of methionines in the gas channel makes [NiFe] hydrogenase aero-tolerant.
Dementin S, Leroux F, Cournac L, de Lacey AL, Volbeda A, Léger C, Burlat B, Martinez N, Champ S, Martin L, Sanganas O, Haumann M, Fernández VM, Guigliarelli B, Fontecilla-Camps JC, Rousset M. Dementin S, et al. J Am Chem Soc. 2009 Jul 29;131(29):10156-64. doi: 10.1021/ja9018258. J Am Chem Soc. 2009. PMID: 19580279
Relating diffusion along the substrate tunnel and oxygen sensitivity in hydrogenase.
Liebgott PP, Leroux F, Burlat B, Dementin S, Baffert C, Lautier T, Fourmond V, Ceccaldi P, Cavazza C, Meynial-Salles I, Soucaille P, Fontecilla-Camps JC, Guigliarelli B, Bertrand P, Rousset M, Léger C. Liebgott PP, et al. Among authors: dementin s. Nat Chem Biol. 2010 Jan;6(1):63-70. doi: 10.1038/nchembio.276. Epub 2009 Dec 6. Nat Chem Biol. 2010. PMID: 19966788
51 results