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Page 1
Stand up for Electrostatics: The Disiloxane Case.
Martín-Fernández C, Alkorta I, Montero-Campillo MM, Elguero J. Martín-Fernández C, et al. Chemphyschem. 2022 May 4;23(9):e202200088. doi: 10.1002/cphc.202200088. Epub 2022 Mar 23. Chemphyschem. 2022. PMID: 35235247
The basicity of the simplest silicone, disiloxane (H(3) Si-O-SiH(3) ), is strongly affected by the Si-O-Si angle (alpha). ...Our results clearly point out that this increase can be explained through the MEP, as the interactions between oxygen from disiloxane and the …
The basicity of the simplest silicone, disiloxane (H(3) Si-O-SiH(3) ), is strongly affected by the Si-O-Si angle (alpha). ...Our resu …
Bis(η-penta-methyl-cyclo-penta-dien-yl)cobalt(II).
Clark MM, Brennessel WW, Holland PL. Clark MM, et al. Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 11;65(Pt 4):m391. doi: 10.1107/S1600536809007971. Acta Crystallogr Sect E Struct Rep Online. 2009. PMID: 21582340 Free PMC article.
High-quality single crystals were grown from a cold saturated hexa-methyl-disiloxane solution. The structure is related to the manganese and iron analogs. ...
High-quality single crystals were grown from a cold saturated hexa-methyl-disiloxane solution. The structure is related to the mangan …
Properties of Dicationic Disiloxane Ionic Liquids.
Krasovskiy VG, Kapustin GI, Gorbatsevich OB, Glukhov LM, Chernikova EA, Koroteev AA, Kustov LM. Krasovskiy VG, et al. Molecules. 2020 Jun 26;25(12):2949. doi: 10.3390/molecules25122949. Molecules. 2020. PMID: 32604885 Free PMC article.
A number of dicationic ionic liquids with a disiloxane linker between imidazolium cations and bis(trifluoromethylsulfonyl)imide anion were synthesized and characterized. ...
A number of dicationic ionic liquids with a disiloxane linker between imidazolium cations and bis(trifluoromethylsulfonyl)imide anion …
Study of carbamate-modified disiloxane in porous PVDF-HFP membranes: new electrolytes/separators for lithium-ion batteries.
Jeschke S, Mutke M, Jiang Z, Alt B, Wiemhöfer HD. Jeschke S, et al. Chemphyschem. 2014 Jun 23;15(9):1761-71. doi: 10.1002/cphc.201400065. Epub 2014 Apr 15. Chemphyschem. 2014. PMID: 24737746
FTIR spectroscopy reveals interactions between LiTFSI and the carbonyl moiety of the disiloxane. No interactions between LiTFSI and PVDF-HFP or between disiloxane and PVDF-HFP are detected by FTIR spectroscopy. Furthermore, the distribution of the alpha and beta/gam …
FTIR spectroscopy reveals interactions between LiTFSI and the carbonyl moiety of the disiloxane. No interactions between LiTFSI and P …
Anion recognition by silanetriol in acetonitrile.
Kondo SI, Okada N, Abe S, Tanaka R, Yamamura M, Unno M. Kondo SI, et al. Org Biomol Chem. 2022 Nov 23;20(45):8925-8931. doi: 10.1039/d2ob01596j. Org Biomol Chem. 2022. PMID: 36321688
The anion recognition ability of silanetriol 5 was greater than those of the structurally related silanediols and silanemono-ol, although less effective than those of 1,3-disiloxane-1,3-diol and 1,3-disiloxane-1,1,3,3-tetraol. From the comparison of the association …
The anion recognition ability of silanetriol 5 was greater than those of the structurally related silanediols and silanemono-ol, although le …
Chemoselective Reduction of Phosphine Oxides by 1,3-Diphenyl-Disiloxane.
Buonomo JA, Eiden CG, Aldrich CC. Buonomo JA, et al. Chemistry. 2017 Oct 17;23(58):14434-14438. doi: 10.1002/chem.201703875. Epub 2017 Sep 18. Chemistry. 2017. PMID: 28840623 Free PMC article.
Herein, we report the discovery of the most powerful chemoselective reductant for this transformation to date, 1,3-diphenyl-disiloxane (DPDS). Additive-free DPDS selectively reduces both secondary and tertiary phosphine oxides with retention of configuration even in the pr …
Herein, we report the discovery of the most powerful chemoselective reductant for this transformation to date, 1,3-diphenyl-disiloxane
Borate-Functionalized Disiloxane as Effective Electrolyte Additive for 4.5 V LiNi(0.8)Co(0.1)Mn(0.1)O(2)/Graphite Batteries.
Chen C, Guo J, Wu C, Duan X, Zhang L. Chen C, et al. ACS Appl Mater Interfaces. 2024 Feb 21;16(7):8733-8741. doi: 10.1021/acsami.3c16531. Epub 2024 Feb 12. ACS Appl Mater Interfaces. 2024. PMID: 38345337
To further improve the cycle lifespan of NCM811 batteries to meet the requirement of driving range for the electric vehicle market, it is vital to design a novel electrolyte additive that can enhance the stability of the cathode/electrolyte interface at a wide range of voltage. H …
To further improve the cycle lifespan of NCM811 batteries to meet the requirement of driving range for the electric vehicle market, it is vi …
2-Acetyl-amino-1,3,4,6-tetra-O-(tri-methyl-silyl)-2-de-oxy-α-d-gluco-pyran-ose.
Cheng ZD, Cui YL, Mao JW. Cheng ZD, et al. Acta Crystallogr Sect E Struct Rep Online. 2013 May 18;69(Pt 6):o917. doi: 10.1107/S160053681301266X. Print 2013 Jun 1. Acta Crystallogr Sect E Struct Rep Online. 2013. PMID: 23795087 Free PMC article.
The title compound, C20H47NO6Si4, was synthesized by per-O-tri-methyl-silylation of N-acetyl-d-glucosa-mine using chloro-tri-methyl-silane in the presence of hexa-methyl-disiloxane. The tri-methyl-silyl group and acetamido group are located on the same side of the pyran ri …
The title compound, C20H47NO6Si4, was synthesized by per-O-tri-methyl-silylation of N-acetyl-d-glucosa-mine using chloro-tri-methyl-silane i …
Cu(II)/Guanidine Functionalized Disiloxane Complex of Supramolecular Structures for Visible Light-Driven Photocatalysis of Congo Red.
Fortună ME, Pricop L, Zaltariov M, Popovici D, Ignat M, Harabagiu V, Simionescu BC. Fortună ME, et al. Polymers (Basel). 2022 Feb 20;14(4):817. doi: 10.3390/polym14040817. Polymers (Basel). 2022. PMID: 35215730 Free PMC article.
The present study focuses on the synthesis of a new guanidine-functionalized disiloxane used as a ligand to obtain copper(II) complexes linked through hydrogen bonding into supramolecular structures. ...In the second step, DS-PMO derivative was modified with 1,1,3,3-tetram …
The present study focuses on the synthesis of a new guanidine-functionalized disiloxane used as a ligand to obtain copper(II) complex …
High-Frequency Surface Insulation Strength with Nanoarchitectonics of Disiloxane Modified Polyimide Films.
Xing Z, Zhang C, Xue N, Li Z, Li F, Wan X, Guo S, Hao J. Xing Z, et al. Polymers (Basel). 2021 Dec 31;14(1):146. doi: 10.3390/polym14010146. Polymers (Basel). 2021. PMID: 35012168 Free PMC article.
However, creeping discharge will cause insulation failure, therefore, it is necessary to use disiloxane for the purpose of modifying the molecular structure of polyimide. ...
However, creeping discharge will cause insulation failure, therefore, it is necessary to use disiloxane for the purpose of modifying …
164 results