Molecular-Level Insights into the Notorious CO Poisoning of Platinum Catalyst.
Chen W, Cao J, Fu W, Zhang J, Qian G, Yang J, Chen D, Zhou X, Yuan W, Duan X.
Chen W, et al.
Angew Chem Int Ed Engl. 2022 Apr 11;61(16):e202200190. doi: 10.1002/anie.202200190. Epub 2022 Feb 23.
Angew Chem Int Ed Engl. 2022.
PMID: 35132761
The stepwise defunctionalization of carbon support is adopted to fine-tune the 5d electronic structure of supported Pt nanoparticles. Excluding other promotional mechanisms, the increase of Pt 5d band energy strengthens the competitive adsorption of hydrogen against …
The stepwise defunctionalization of carbon support is adopted to fine-tune the 5d electronic structure of supported Pt nanoparticles. …