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Page 1
History and recent advances in elemental analysis of germanium-based functional materials.
Guselnikova TY. Guselnikova TY. Talanta. 2023 Jan 1;251:123792. doi: 10.1016/j.talanta.2022.123792. Epub 2022 Aug 5. Talanta. 2023. PMID: 35964517 Review.
This article is devoted to a review of studies on the determination of trace elements in germanium and germanium dioxide. For this purpose, methods both with and without preliminary matrix separation procedure have been developed and applied. ...On the other hand, t …
This article is devoted to a review of studies on the determination of trace elements in germanium and germanium dioxide. For …
Elemental distributions of solid waste collected from the germanium extraction process.
Tian Q, Wei D, Pan Y, Zhang H. Tian Q, et al. Environ Sci Pollut Res Int. 2024 Mar;31(12):18485-18493. doi: 10.1007/s11356-024-32316-y. Epub 2024 Feb 12. Environ Sci Pollut Res Int. 2024. PMID: 38347351
The solid waste produced from the germanium extraction process has attached much attention to its potential germanium sources. However, the elemental distribution of solid waste is still unclear. Therefore, the solid waste was studied using a sequential extra …
The solid waste produced from the germanium extraction process has attached much attention to its potential germanium sources. …
Elemental Germanium Activation and Catalysis Enabled by Mechanical Force.
Guo G, Zhou J, He X, Li N, Lin N, Zhang X, Lian Z. Guo G, et al. Angew Chem Int Ed Engl. 2025 Jan 16:e202421446. doi: 10.1002/anie.202421446. Online ahead of print. Angew Chem Int Ed Engl. 2025. PMID: 39822029
Despite its significant role in advanced technological applications, the potential of elemental germanium as a catalyst remains unexplored. Leveraging recent developments in mechanochemistry, this study introduces a groundbreaking approach to activate elemental
Despite its significant role in advanced technological applications, the potential of elemental germanium as a catalyst remain …
The Reactivity of Germanium Phosphanides with Chalcogens.
Harris LM, Tam EC, Cummins SJ, Coles MP, Fulton JR. Harris LM, et al. Inorg Chem. 2017 Mar 6;56(5):3087-3094. doi: 10.1021/acs.inorgchem.6b03109. Epub 2017 Feb 17. Inorg Chem. 2017. PMID: 28211684
The reactivity of germanium phosphanido complexes with elemental chalcogens is reported. Addition of sulfur to [(BDI)GePCy(2)] (BDI = CH{(CH(3))CN-2,6-iPr(2)C(6)H(3)}(2)) results in oxidation at germanium to form germanium(IV) sulfide [(BDI)Ge(S)PCy(2) …
The reactivity of germanium phosphanido complexes with elemental chalcogens is reported. Addition of sulfur to [(BDI)GePCy(2)] …
Emerging Applications of Elemental 2D Materials.
Glavin NR, Rao R, Varshney V, Bianco E, Apte A, Roy A, Ringe E, Ajayan PM. Glavin NR, et al. Adv Mater. 2020 Feb;32(7):e1904302. doi: 10.1002/adma.201904302. Epub 2019 Oct 31. Adv Mater. 2020. PMID: 31667920 Review.
As elemental main group materials (i.e., silicon and germanium) have dominated the field of modern electronics, their monolayer 2D analogues have shown great promise for next-generation electronic materials as well as potential game-changing properties for optoelect …
As elemental main group materials (i.e., silicon and germanium) have dominated the field of modern electronics, their monolaye …
A chlorine-free protocol for processing germanium.
Glavinović M, Krause M, Yang L, McLeod JA, Liu L, Baines KM, Friščić T, Lumb JP. Glavinović M, et al. Sci Adv. 2017 May 5;3(5):e1700149. doi: 10.1126/sciadv.1700149. eCollection 2017 May. Sci Adv. 2017. PMID: 28508082 Free PMC article.
We describe a recyclable quinone/catechol redox platform that provides an innovative replacement for elemental chlorine and hydrochloric acid in the conversion of either germanium metal or germanium dioxide to a germanium tetrachloride substitute. G
We describe a recyclable quinone/catechol redox platform that provides an innovative replacement for elemental chlorine and hydrochlo …
Selective synthesis of germasila-adamantanes through germanium-silicon shift processes.
Kühn S, Köstler B, True C, Albers L, Wagner M, Müller T, Marschner C. Kühn S, et al. Chem Sci. 2023 Jul 31;14(33):8956-8961. doi: 10.1039/d3sc03301e. eCollection 2023 Aug 23. Chem Sci. 2023. PMID: 37621423 Free PMC article.
The SWM rearrangement allows also a deliberate shift of germanium atoms from the periphery and within the cage structures into the bridgehead positions. This opens the possibility for a synthesis of germasila-adamantanes of defined germanium content and controlled r …
The SWM rearrangement allows also a deliberate shift of germanium atoms from the periphery and within the cage structures into the br …
Alkaline-Earth-Metal-Induced Liberation of Rare Allotropes of Elemental Silicon and Germanium from N-Heterocyclic Metallylenes.
Blom B, Said A, Szilvási T, Menezes PW, Tan G, Baumgartner J, Driess M. Blom B, et al. Inorg Chem. 2015 Sep 8;54(17):8840-8. doi: 10.1021/acs.inorgchem.5b01643. Epub 2015 Aug 25. Inorg Chem. 2015. PMID: 26305163
Unexpectedly, the complexes undergo facile transformation to 1,4-diazabuta-1,3-diene Ae metal complexes of the type [(eta(5)-C5Me5)2Ae(kappa(2)-{N(t)BuCHCHN(t)Bu})] (Ae = Sr 10, Ae = Ba 11) or in the case of calcium to the dinuclear complex [(eta(5)-C5Me5)2Ca:N((t)Bu)CHCH((t)Bu)N …
Unexpectedly, the complexes undergo facile transformation to 1,4-diazabuta-1,3-diene Ae metal complexes of the type [(eta(5)-C5Me5)2Ae(kappa …
Optical properties and lattice dynamics of a novel allotrope of orthorhombic elemental germanium.
Litvinchuk AP, Gavrilenko VI, Tang Z, Guloy AM. Litvinchuk AP, et al. J Phys Condens Matter. 2019 Apr 3;31(13):135401. doi: 10.1088/1361-648X/aaffe9. Epub 2019 Jan 18. J Phys Condens Matter. 2019. PMID: 30658348
Optical and vibrational properties of a novel allotrope of elemental germanium Ge(oP32), which crystallizes in the structure corresponding to the orthorhombic space group Pbcm, are studied experimentally by means of absorption and polarized Raman scattering measurem …
Optical and vibrational properties of a novel allotrope of elemental germanium Ge(oP32), which crystallizes in the structure c …
A crystalline T-shaped planar group 14 anion.
Liu X, Dai Y, Bao M, Wang W, Li Q, Liu C, Wang X, Su Y. Liu X, et al. Chem Sci. 2023 May 3;14(21):5722-5727. doi: 10.1039/d2sc07006e. eCollection 2023 May 31. Chem Sci. 2023. PMID: 37265721 Free PMC article.
DFT calculations indicate that the tricoordinate germanium center features both an unoccupied 4p orbital and two lone pairs of electrons. Its electron-rich nature allows for the nucleophilic attack on the methyl iodine giving methyl-substituted complex 5 and facile oxidati …
DFT calculations indicate that the tricoordinate germanium center features both an unoccupied 4p orbital and two lone pairs of electr …
176 results