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Postoperative C5 Palsy after Anterior or Posterior Decompression for Degenerative Cervical Myelopathy: A Subgroup Analysis of the Multicenter, Prospective, Randomized, Phase III, CSM-Protect Clinical Trial.
Bak AB, Moghaddamjou A, Alvi M, Ahn H, Farhadi HF, Shaffrey CI, Nassr A, Mummaneni P, Arnold PM, Jacobs WB, Riew KD, Kelly M, Brodke DS, Vaccaro AR, Hilibrand AS, Wilson J, Harrop JS, Yoon ST, Kim KD, Fourney DR, Santaguida C, Massicotte EM, Kopjar B, Fehlings M. Bak AB, et al. Spine (Phila Pa 1976). 2024 Apr 15. doi: 10.1097/BRS.0000000000005007. Online ahead of print. Spine (Phila Pa 1976). 2024. PMID: 38616732
The total incidence of postoperative C5 palsy was 7.4% and was significantly higher in patients that underwent posterior decompression compared to anterior decompression (11.26% vs. 3.03%, P=0.008). After multivariable regression, posterior approach was independentl …
The total incidence of postoperative C5 palsy was 7.4% and was significantly higher in patients that underwent posterior decompressio …
Effect of La3+ on the Formation of Endohedral Zintl Clusters Featuring In/Bi Shells.
Pan F, Weinert B, Dehnen S. Pan F, et al. Inorg Chem. 2024 Apr 5. doi: 10.1021/acs.inorgchem.4c00192. Online ahead of print. Inorg Chem. 2024. PMID: 38580311
Investigating the interactions of f-block metal ions with p-block polyanions in multinary cluster compounds is becoming increasingly attractive but remains a challenge in terms of both the synthetic approach and the control of the structures that are formed during the synt …
Investigating the interactions of f-block metal ions with p-block polyanions in multinary cluster compounds is becoming increasingly …
Superatomic Aromaticity in Cyclic Superatomic Molecules: Ligand-Protected Penta-Icosahedral [M@Au11]5 (M = Au, Pt) Clusters.
Gao J, Zhou Y, Xu C, Cheng L. Gao J, et al. J Phys Chem A. 2024 Apr 18;128(15):2982-2988. doi: 10.1021/acs.jpca.4c00229. Epub 2024 Apr 5. J Phys Chem A. 2024. PMID: 38578691
As the first large-scale ring-like gold cluster, the report of [Au(60)Se(2)(Ph(3)P)(10)(SeR)(15)](+) has arisen much interest, where its Au(60) core is composed of five vertex-sharing gold icosahedra in a cyclic way. From electronic characters, this Au(60) core is a 40e cy …
As the first large-scale ring-like gold cluster, the report of [Au(60)Se(2)(Ph(3)P)(10)(SeR)(15)](+) has arisen much interest, where …
Assignment of individual structures from intermetalloid nickel gallium cluster ensembles.
Muhr M, Stephan J, Staiger L, Hemmer K, Schütz M, Heiß P, Jandl C, Cokoja M, Kratky T, Günther S, Huber D, Kahlal S, Saillard JY, Cador O, Da Silva ACH, Da Silva JLF, Mink J, Gemel C, Fischer RA. Muhr M, et al. Commun Chem. 2024 Feb 13;7(1):29. doi: 10.1038/s42004-024-01110-9. Commun Chem. 2024. PMID: 38351167 Free PMC article.
Our study case are the very similar nickel/gallium clusters of M(12), M(13) and M(14) core composition Ni(6+x)Ga(6+y) (x + y 2). The rationalization of structure, bonding and reactivity is built upon the organometallic superatom cluster [Ni(6)Ga(6)](Cp*)(6) = [Ga …
Our study case are the very similar nickel/gallium clusters of M(12), M(13) and M(14) core composition Ni(6+x)Ga(6+y) (x + y 2). The …
Selective conversion of carbon dioxide into heavy olefins over Ga modified delafossite-CuFeO(2).
Chen C, Wu X, Zhang S, Qing M, La M, Li J, Liu CL, Dong WS. Chen C, et al. Chem Commun (Camb). 2023 Oct 12;59(82):12286-12289. doi: 10.1039/d3cc03783e. Chem Commun (Camb). 2023. PMID: 37752883
Ga-modified CuFeO(2) used as an efficient catalyst for CO(2) hydrogenation to heavy olefins (C=5+) can achieve a high heavy olefin selectivity of 53.5%, which lies at a high level among reported catalysts, at a single pass CO(2) conversion of 41.5%. ...
Ga-modified CuFeO(2) used as an efficient catalyst for CO(2) hydrogenation to heavy olefins (C=5+) can achieve a high heavy olefin se …
Yttrium Complexes with Group 13 Heterobenzene-Type Ligands.
Lebon J, Barisic D, Maichle-Mössmer C, Anwander R. Lebon J, et al. Chemistry. 2023 Nov 21;29(65):e202302846. doi: 10.1002/chem.202302846. Epub 2023 Oct 9. Chemistry. 2023. PMID: 37747699
The yttrium gallabenzene complex [(1-Me-3,5-tBu(2) -C(5) H(3) Ga)(mu-Me)Y(2,4-dtbp)] is accessible from Y(GaMe(4) )(3) and K(2,4-dtbp) via a tandem salt metathesis/methane elimination (2,4-dtbp=2,4-di-tert-butyl-pentadienyl). ...The bonding features of the newly synthesize …
The yttrium gallabenzene complex [(1-Me-3,5-tBu(2) -C(5) H(3) Ga)(mu-Me)Y(2,4-dtbp)] is accessible from Y(GaMe(4) )(3) and K(2,4-dtbp …
Using Recombinant Superoxide Dismutase to Control Oxidative Stress in the Gastrointestinal Tract of Cyclic Heat-Stressed Pigs.
Le HH, Zhao W, Furness JB, Shakeri M, DiGiacomo K, Roura E, Renaudeau D, Gabler NK, Leury BJ, Dunshea FR, Wijffels G, Cottrell JJ. Le HH, et al. Animals (Basel). 2023 Aug 21;13(16):2681. doi: 10.3390/ani13162681. Animals (Basel). 2023. PMID: 37627472 Free PMC article.
After acclimation to the diet, pigs were then housed under thermoneutral (TN, 20 C, 35-50% relative humidity) or cyclic heat stress conditions ((C)HS, at 35 C: 9 a.m. to 5 p.m. and 28 C: 5 p.m. to 9 a.m., 35-50% relative humidity) for 3 days. Heat stress increased r …
After acclimation to the diet, pigs were then housed under thermoneutral (TN, 20 C, 35-50% relative humidity) or cyclic heat stress conditio …
Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition.
Sun X, Hinz A, Schulz S, Zimmermann L, Scheer M, Roesky PW. Sun X, et al. Chem Sci. 2023 Apr 17;14(18):4769-4776. doi: 10.1039/d3sc00806a. eCollection 2023 May 10. Chem Sci. 2023. PMID: 37181779 Free PMC article.
Insertion and functionalization of gallasilylenes [L(Ph)Si-Ga(Cl)L(BDI)] (L(Ph) = PhC(NtBu)(2); L(BDI) = [{2,6-iPr(2)C(6)H(3)NCMe}(2)CH]) into the cyclo-E(5) rings of [Cp*Fe(eta(5)-E(5))] (Cp* = eta(5)-C(5)Me(5); E = P, As) are reported. ...[(L(Ph)Si-Ga(Cl)L( …
Insertion and functionalization of gallasilylenes [L(Ph)Si-Ga(Cl)L(BDI)] (L(Ph) = PhC(NtBu)(2); L(BDI) = [{2,6-iPr(2)C(6)H(3)NCMe}(2) …
Intercalation of p-Aminopyridine and p-Ethylenediamine Molecules into Orthorhombic In(1.2)Ga(0.8)S(3) Single Crystals.
Rahimli AB, Amiraslanov IR, Jahangirli ZA, Aliyeva NH, Boulet P, Record MC, Aliev ZS. Rahimli AB, et al. Materials (Basel). 2023 Mar 15;16(6):2368. doi: 10.3390/ma16062368. Materials (Basel). 2023. PMID: 36984248 Free PMC article.
A single crystalline layered semiconductor In(1.2)Ga(0.8)S(3) phase was grown, and by intercalating p-aminopyridine (NH(2)-C(5)H(4)N or p-AP) molecules into this crystal, a new intercalation compound, In(1.2)Ga(0.8)S(3).0.5(NH(2)-C(5)H(4)N), was synthe …
A single crystalline layered semiconductor In(1.2)Ga(0.8)S(3) phase was grown, and by intercalating p-aminopyridine (NH(2)-C(5 …
Reverse Phase Protein Array Profiling Identifies Recurrent Protein Expression Patterns of DNA Damage-Related Proteins across Acute and Chronic Leukemia: Samples from Adults and the Children's Oncology Group.
Hoff FW, Griffen TL, Brown BD, Horton TM, Burger J, Wierda W, Hubner SE, Qiu Y, Kornblau SM. Hoff FW, et al. Int J Mol Sci. 2023 Mar 13;24(6):5460. doi: 10.3390/ijms24065460. Int J Mol Sci. 2023. PMID: 36982537 Free PMC article.

Most (96%) of the CLL cases clustered in one cluster; the other 4% were characterized by higher frequencies of deletion 13q and 17p, and fared poorly (p < 0.001). T-ALL predominated in C1 and AML in C5, but both occurred in all four acute-dominated clusters. Prot

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Most (96%) of the CLL cases clustered in one cluster; the other 4% were characterized by higher frequencies of deletion 13q and 17p, and far …
133 results