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1966 2
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70 results

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Page 1
Controlled Radical Copolymerization toward Well-Defined Fluoropolymers.
Chen K, Guo X, Chen M. Chen K, et al. Angew Chem Int Ed Engl. 2023 Nov 27;62(48):e202310636. doi: 10.1002/anie.202310636. Epub 2023 Aug 23. Angew Chem Int Ed Engl. 2023. PMID: 37581580 Review.
This minireview discusses challenges in controlled radical copolymerizations (CRCPs) of fluoroalkenes and provides a concise perspective on recent progress in CRCPs of fluoroalkenes (e.g., tetrafluoroethylene, chlorotrifluoroethylene, hexafluoropropene, perfluoroalkyl viny …
This minireview discusses challenges in controlled radical copolymerizations (CRCPs) of fluoroalkenes and provides a concise perspective on …
Are (Co)Polymers of 1,1,3,3,3-Pentafluoropropene Possible?
Boschet F, Kostov G, Raynova H, Améduri B. Boschet F, et al. Molecules. 2023 Jun 7;28(12):4618. doi: 10.3390/molecules28124618. Molecules. 2023. PMID: 37375173 Free PMC article.
The chosen fluoromonomers were vinylidene fluoride (VDF), 3,3,3-trifluoropropene (TFP), hexafluoropropene (HFP), perfluoromethylvinyl ether (PMVE), chlorotrifluoroethylene (CTFE) and tert-butyl-2-trifluoromethacrylate (MAF-TBE), while the hydrocarbon comonomers were vinyle …
The chosen fluoromonomers were vinylidene fluoride (VDF), 3,3,3-trifluoropropene (TFP), hexafluoropropene (HFP), perfluoromethylvinyl …
Toxicology of fluorine-containing monomers.
Kennedy GL Jr. Kennedy GL Jr. Crit Rev Toxicol. 1990;21(2):149-70. doi: 10.3109/10408449009089877. Crit Rev Toxicol. 1990. PMID: 2083033 Review.
Metabolism of hexafluoropropene. Evidence for bioactivation by glutathione conjugate formation in the kidney.
Koob M, Dekant W. Koob M, et al. Drug Metab Dispos. 1990 Nov-Dec;18(6):911-6. Drug Metab Dispos. 1990. PMID: 1981536
The results show that hexafluoropropene is metabolized to two different GSH-conjugates in rat liver and kidney. The data also suggest that hexafluoropropene metabolites formed in the liver and eliminated with bile are not translocated to the kidney and that intraren …
The results show that hexafluoropropene is metabolized to two different GSH-conjugates in rat liver and kidney. The data also suggest …
Poly(vinylidene fluoride-co-hexafluoropropene) (PVDF-HFP) membranes for ethyl acetate removal from water.
Tian X, Jiang X. Tian X, et al. J Hazard Mater. 2008 May 1;153(1-2):128-35. doi: 10.1016/j.jhazmat.2007.08.029. Epub 2007 Aug 17. J Hazard Mater. 2008. PMID: 17884287
In this study, poly(vinylidene fluoride-co-hexafluoropropene) (PVDF-HFP) with low crystallinity was applied as the membrane material for pervaporative separating ethyl acetate (EtAc) from its aqueous solutions. ...
In this study, poly(vinylidene fluoride-co-hexafluoropropene) (PVDF-HFP) with low crystallinity was applied as the membrane material …
Cross-Linked Poly(vinylidene fluoride-co-hexafluoropropene) (PVDF-co-HFP) Gel Polymer Electrolyte for Flexible Li-Ion Battery Integrated with Organic Light Emitting Diode (OLED).
Kim I, Kim BS, Nam S, Lee HJ, Chung HK, Cho SM, Luu THT, Hyun S, Kang C. Kim I, et al. Materials (Basel). 2018 Apr 2;11(4):543. doi: 10.3390/ma11040543. Materials (Basel). 2018. PMID: 29614800 Free PMC article.
Here, we fabricate poly(vinylidene fluoride-co-hexafluoropropene) (PVDF-co-HFP) by electrospinning for a gel polymer electrolyte (GPE) for use in flexible Li-ion batteries (LIBs). ...
Here, we fabricate poly(vinylidene fluoride-co-hexafluoropropene) (PVDF-co-HFP) by electrospinning for a gel polymer electrolyte (GPE …
Chemical, physical, and toxicological characterization of fumes produced by heating tetrafluoroethene homopolymer and its copolymers with hexafluoropropene and perfluoro(propyl vinyl ether).
Seidel WC, Scherer KV Jr, Cline D Jr, Olson AH, Bonesteel JK, Church DF, Nuggehalli S, Pryor WA. Seidel WC, et al. Chem Res Toxicol. 1991 Mar-Apr;4(2):229-36. doi: 10.1021/tx00020a017. Chem Res Toxicol. 1991. PMID: 1664259
These fumes may result from (a) pyrolysis of tetrafluoroethene homopolymer or tetrafluoroethene-hexafluoropropene copolymer or (b) evaporation, at 200-320 degrees C, of isolated low MW polymer or low MW polymer present in perfluoro polymer resins. ...
These fumes may result from (a) pyrolysis of tetrafluoroethene homopolymer or tetrafluoroethene-hexafluoropropene copolymer or (b) ev …
Organocatalytic C-F Bond Activation with Alanes.
Jaeger AD, Ehm C, Lentz D. Jaeger AD, et al. Chemistry. 2018 May 7;24(26):6769-6777. doi: 10.1002/chem.201706061. Epub 2018 Mar 30. Chemistry. 2018. PMID: 29443428
Depending on substrate and concentration, high selectivities can be achieved. For the prototypical hexafluoropropene, however, low selectivities are observed (E/Z2). DFT studies show that the preferred HDF mechanism for this substrate in the presence of donor solvents proc …
Depending on substrate and concentration, high selectivities can be achieved. For the prototypical hexafluoropropene, however, low se …
Mechanism of Reductive Fluorination by PTFE-Decomposition Fluorocarbon Gases for WO3.
Yamamoto H, Tada K, Hwang J, Hirai D, Hiroi Z, Matsumoto K, Hagiwara R. Yamamoto H, et al. Inorg Chem. 2023 Feb 6;62(5):2116-2127. doi: 10.1021/acs.inorgchem.2c03761. Epub 2023 Jan 23. Inorg Chem. 2023. PMID: 36690346
The gas-solid reaction paths are analyzed using infrared spectroscopy, which revealed tetrafluoroethylene (C(2)F(4)), hexafluoropropene (C(3)F(6)), and iso-octafluoroisobutene (i-C(4)F(8)) to be the reactive components in the PTFE-decomposition gas during the reactions wit …
The gas-solid reaction paths are analyzed using infrared spectroscopy, which revealed tetrafluoroethylene (C(2)F(4)), hexafluoropropene …
70 results