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A novel synthesis of enantiomerically pure 5,5,5,5',5',5'-hexafluoroleucine.
Xing X, Fichera A, Kumar K. Xing X, et al. Among authors: kumar k. Org Lett. 2001 May 3;3(9):1285-6. doi: 10.1021/ol015567e. Org Lett. 2001. PMID: 11348215
A coiled coil with a fluorous core.
Bilgiçer B, Fichera A, Kumar K. Bilgiçer B, et al. Among authors: kumar k. J Am Chem Soc. 2001 May 16;123(19):4393-9. doi: 10.1021/ja002961j. J Am Chem Soc. 2001. PMID: 11457223
Programmed self-sorting of coiled coils with leucine and hexafluoroleucine cores.
Bilgiçer B, Xing X, Kumar K. Bilgiçer B, et al. Among authors: kumar k. J Am Chem Soc. 2001 Nov 28;123(47):11815-6. doi: 10.1021/ja016767o. J Am Chem Soc. 2001. PMID: 11716746 No abstract available.
A simple and efficient method for the resolution of all four diastereomers of 4,4,4-trifluorovaline and 5,5,5-trifluoroleucine.
Xing X, Fichera A, Kumar K. Xing X, et al. Among authors: kumar k. J Org Chem. 2002 Mar 8;67(5):1722-5. doi: 10.1021/jo011097q. J Org Chem. 2002. PMID: 11871915 No abstract available.
Fluorinated amino acids in protein design and engineering.
Yoder NC, Kumar K. Yoder NC, et al. Among authors: kumar k. Chem Soc Rev. 2002 Nov;31(6):335-41. doi: 10.1039/b201097f. Chem Soc Rev. 2002. PMID: 12491748 Review.
A Highly stereospecific and efficient synthesis of homopentafluoro- phenylalanine.
Babu IR, Hamill EK, Kumar K. Babu IR, et al. Among authors: kumar k. J Org Chem. 2004 Aug 6;69(16):5468-70. doi: 10.1021/jo049206z. J Org Chem. 2004. PMID: 15287798
Just add water: a new fluorous capping reagent for facile purification of peptides synthesized on the solid phase.
Montanari V, Kumar K. Montanari V, et al. Among authors: kumar k. J Am Chem Soc. 2004 Aug 11;126(31):9528-9. doi: 10.1021/ja0479033. J Am Chem Soc. 2004. PMID: 15291542
Selective protein-protein interactions driven by a phenylalanine interface.
Yoder NC, Kumar K. Yoder NC, et al. Among authors: kumar k. J Am Chem Soc. 2006 Jan 11;128(1):188-91. doi: 10.1021/ja055494k. J Am Chem Soc. 2006. PMID: 16390146
Fluorination of mammalian cell surfaces via the sialic acid biosynthetic pathway.
Dafik L, d'Alarcao M, Kumar K. Dafik L, et al. Among authors: kumar k. Bioorg Med Chem Lett. 2008 Nov 15;18(22):5945-7. doi: 10.1016/j.bmcl.2008.09.010. Epub 2008 Sep 6. Bioorg Med Chem Lett. 2008. PMID: 18819798 Free PMC article.
Influence of selective fluorination on the biological activity and proteolytic stability of glucagon-like peptide-1.
Meng H, Krishnaji ST, Beinborn M, Kumar K. Meng H, et al. Among authors: kumar k. J Med Chem. 2008 Nov 27;51(22):7303-7. doi: 10.1021/jm8008579. J Med Chem. 2008. PMID: 18950150 Free PMC article.
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