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Atomically precise gold nanoclusters as new model catalysts.
Li G, Jin R. Li G, et al. Acc Chem Res. 2013 Aug 20;46(8):1749-58. doi: 10.1021/ar300213z. Epub 2013 Mar 27. Acc Chem Res. 2013. PMID: 23534692
Thus, nanoclusters become semiconductors and possess a sizable bandgap (e.g., ~1.3 eV for Au₂₅(SR)₁₈). In addition, Aun(SR)m can be doped with a single atom of other metals, which is of great interest for catalysis, because the catalytic properties of nanoclusters can be t …
Thus, nanoclusters become semiconductors and possess a sizable bandgap (e.g., ~1.3 eV for Au₂₅(SR)₁₈). In addition, Aun(SR)m can be d …
Photocatalytic hydrogen generation system using a nickel-thiolate hexameric cluster.
Kagalwala HN, Gottlieb E, Li G, Li T, Jin R, Bernhard S. Kagalwala HN, et al. Inorg Chem. 2013 Aug 5;52(15):9094-101. doi: 10.1021/ic4013069. Epub 2013 Jul 18. Inorg Chem. 2013. PMID: 23865570
Experimental and Mechanistic Understanding of Aldehyde Hydrogenation Using Au25 Nanoclusters with Lewis Acids: Unique Sites for Catalytic Reactions.
Li G, Abroshan H, Chen Y, Jin R, Kim HJ. Li G, et al. J Am Chem Soc. 2015 Nov 18;137(45):14295-304. doi: 10.1021/jacs.5b07716. Epub 2015 Nov 6. J Am Chem Soc. 2015. PMID: 26498698
The catalytic activity of Au25(SR)18 nanoclusters (R = C2H4Ph) for the aldehyde hydrogenation reaction in the presence of a base, e.g., ammonia or pyridine, and transition-metal ions M(z+), such as Cu(+), Cu(2+), Ni(2+) and Co(2+), as a Lewis acid is studied. ...
The catalytic activity of Au25(SR)18 nanoclusters (R = C2H4Ph) for the aldehyde hydrogenation reaction in the presence of a base, e.g
Photomediated Oxidation of Atomically Precise Au25(SC2H4Ph)18(-) Nanoclusters.
Kauffman DR, Alfonso D, Matranga C, Li G, Jin R. Kauffman DR, et al. J Phys Chem Lett. 2013 Jan 3;4(1):195-202. doi: 10.1021/jz302056q. Epub 2012 Dec 26. J Phys Chem Lett. 2013. PMID: 26291231
Synthesis of ultrasmall platinum nanoparticles and structural relaxation.
Liu C, Li G, Kauffman DR, Pang G, Jin R. Liu C, et al. J Colloid Interface Sci. 2014 Jun 1;423:123-8. doi: 10.1016/j.jcis.2014.02.022. Epub 2014 Feb 28. J Colloid Interface Sci. 2014. PMID: 24703677
Chiral Ag23 nanocluster with open shell electronic structure and helical face-centered cubic framework.
Liu C, Li T, Abroshan H, Li Z, Zhang C, Kim HJ, Li G, Jin R. Liu C, et al. Nat Commun. 2018 Feb 21;9(1):744. doi: 10.1038/s41467-018-03136-9. Nat Commun. 2018. PMID: 29467372 Free PMC article.
No counter ion (e.g., Na(+) and NO(3)(-)) is found in the single-crystal and the absence of such ions is also confirmed by X-ray photoelectron spectroscopy analysis, indicating electrical neutrality of the nanocluster. ...
No counter ion (e.g., Na(+) and NO(3)(-)) is found in the single-crystal and the absence of such ions is also confirmed by X-ray phot …
Tailoring the Electronic and Catalytic Properties of Au25 Nanoclusters via Ligand Engineering.
Li G, Abroshan H, Liu C, Zhuo S, Li Z, Xie Y, Kim HJ, Rosi NL, Jin R. Li G, et al. ACS Nano. 2016 Aug 23;10(8):7998-8005. doi: 10.1021/acsnano.6b03964. Epub 2016 Jul 26. ACS Nano. 2016. PMID: 27442235
The unsupported [Au25(SNap)18](-) nanoclusters show high thermal and antioxidation stabilities (e.g., at 80 °C in the present of O2, excess H2O2, or TBHP) due to the effects of aromatic ligands on stabilization of the nanocluster's frontier orbitals (HOMO and LUMO). ...
The unsupported [Au25(SNap)18](-) nanoclusters show high thermal and antioxidation stabilities (e.g., at 80 °C in the present of O2, …
Observation of Body-Centered Cubic Gold Nanocluster.
Liu C, Li T, Li G, Nobusada K, Zeng C, Pang G, Rosi NL, Jin R. Liu C, et al. Angew Chem Int Ed Engl. 2015 Aug 17;54(34):9826-9. doi: 10.1002/anie.201502667. Epub 2015 Jul 1. Angew Chem Int Ed Engl. 2015. PMID: 26136241
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