Evidence for electrophilic catalysis in the 4-chlorobenzoyl-CoA dehalogenase reaction: UV, Raman, and 13C-NMR spectral studies of dehalogenase complexes of benzoyl-CoA adducts.
Taylor KL, Liu RQ, Liang PH, Price J, Dunaway-Mariano D, Tonge PJ, Clarkson J, Carey PR.
Taylor KL, et al. Among authors: liang ph.
Biochemistry. 1995 Oct 24;34(42):13881-8. doi: 10.1021/bi00042a020.
Biochemistry. 1995.
PMID: 7577982
The arylated enzyme is hydrolyzed to free enzyme plus 4-HBA-CoA by the addition of water at the acyl carbon [Yang, G., Liang, P.-H., & Dunaway-Mariano, D. (1994) Biochemistry 33, 8527]. ...The UV-visible spectra measured for 4-HBA-CoA in aqueous buffer at pH 7.5 …
The arylated enzyme is hydrolyzed to free enzyme plus 4-HBA-CoA by the addition of water at the acyl carbon [Yang, G., Liang, P.-H., …