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Structural phase transitions and photoluminescence properties of oxonitridosilicate phosphors under high hydrostatic pressure.
Sci Rep. 2016 Oct 13;6:34010. doi: 10.1038/srep34010.
Sci Rep. 2016.
PMID: 27734847
Free PMC article.
This effect is explained by different interaction of the Eu(2+) 5d electron with the second coordination sphere around the impurity cations....
This effect is explained by different interaction of the Eu(2+) 5d electron with the second coordination sphere around the impurity c …
Blue-shift of Eu²⁺ emission in (Ba,Sr)₃Lu(PO₄)₃:Eu²⁺ eulytite solid-solution phosphors resulting from release of neighbouring-cation-induced stress.
Wang Z, Xia Z, Molokeev MS, Atuchin VV, Liu Q.
Wang Z, et al.
Dalton Trans. 2014 Nov 28;43(44):16800-4. doi: 10.1039/c4dt02319f.
Dalton Trans. 2014.
PMID: 25287659
The blue-shift of the Eu(2+) emission with increasing Sr/Ba ratio was ascribed to the variation of the crystal field strength that the 5d orbital of Eu(2+) ion experiences, and a new model based on the Eu-O bond length and released neighboring-cation stress in disordered B …
The blue-shift of the Eu(2+) emission with increasing Sr/Ba ratio was ascribed to the variation of the crystal field strength that the 5d …
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