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Blue-shift of Eu²⁺ emission in (Ba,Sr)₃Lu(PO₄)₃:Eu²⁺ eulytite solid-solution phosphors resulting from release of neighbouring-cation-induced stress.
Dalton Trans. 2014 Nov 28;43(44):16800-4. doi: 10.1039/c4dt02319f.
Dalton Trans. 2014.
PMID: 25287659
The blue-shift of the Eu(2+) emission with increasing Sr/Ba ratio was ascribed to the variation of the crystal field strength that the 5d orbital of Eu(2+) ion experiences, and a new model based on the Eu-O bond length and released neighboring-cation stress in disordered B …
The blue-shift of the Eu(2+) emission with increasing Sr/Ba ratio was ascribed to the variation of the crystal field strength that the 5d …
Structural phase transitions and photoluminescence properties of oxonitridosilicate phosphors under high hydrostatic pressure.
Lazarowska A, Mahlik S, Grinberg M, Li G, Liu RS.
Lazarowska A, et al.
Sci Rep. 2016 Oct 13;6:34010. doi: 10.1038/srep34010.
Sci Rep. 2016.
PMID: 27734847
Free PMC article.
This effect is explained by different interaction of the Eu(2+) 5d electron with the second coordination sphere around the impurity cations....
This effect is explained by different interaction of the Eu(2+) 5d electron with the second coordination sphere around the impurity c …
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