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Proton Conductive Luminescent Thermometer Based on Near-Infrared Emissive {YbCo2} Molecular Nanomagnets
Wang J, et al. J Am Chem Soc 2020. Among authors: Nakabayashi K. PMID 32017548
The resulting Yb(III) complexes present a slow magnetic relaxation below 6 K and room temperature NIR 4f-centered photoluminescence sensitized by [Co(CN)(6)](3-) ions. ...Moreover, the emission pattern is strongly temperature-dependent which was utilized in achieving a highly sensitive single-center luminescent thermometer with a relative thermal sensitivity, S(r) > 1% K(-1) in the 50-175 K range. ...
The resulting Yb(III) complexes present a slow magnetic relaxation below 6 K and room temperature NIR 4f-centered photoluminescence s …
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