Dioxane promoted photochemical O-alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C-H and C-C bonds.
Zhou X, Jiang J, Zhang M, Wu Q, Zhu K, Shi D, Hou S, Zhao J, Li P.
Zhou X, et al.
Chem Commun (Camb). 2024 Mar 28. doi: 10.1039/d4cc00778f. Online ahead of print.
Chem Commun (Camb). 2024.
PMID: 38545739
A photochemical synthesis of enol ethers and furan-3(2H)-ones from 1,3-dicarbonyl compounds and aryl diazoacetates has been developed. Significantly, 1,4-dioxane promoted O-alkylation of various 1,3-dicarbonyl compounds beyond previous carbene insertion into C-H and C-C bo …
A photochemical synthesis of enol ethers and furan-3(2H)-ones from 1,3-dicarbonyl compounds and aryl diazoacetates has been developed. Signi …