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Comparison of Cu3, Cu5, and Cu7 clusters as potential antioxidants: A theoretical quest.
Alipour B, Kassaee MZ. Alipour B, et al. J Mol Model. 2024 Apr 16;30(5):132. doi: 10.1007/s00894-024-05933-0. J Mol Model. 2024. PMID: 38625549
CONTEXT: Herein, we compare and contrast the dual roles of Cu(n) clusters (n = 3, 5, and 7 atoms) in scavenging or generating RO() free radicals from ROH at the theoretical levels (where R = H, methyl, ethyl, n-propyl, i-propyl, n-butyl, t-butyl, and phenyl). ...In the pre …
CONTEXT: Herein, we compare and contrast the dual roles of Cu(n) clusters (n = 3, 5, and 7 atoms) in scavenging or generating RO() free radi …
Surface-Diffusion-Induced Amorphization of Pt Nanoparticles over Ru Oxide Boost Acidic Oxygen Evolution.
Hu Y, Han X, Hu S, Yu G, Chao T, Wu G, Qu Y, Chen C, Liu P, Zheng X, Yang Q, Hong X. Hu Y, et al. Nano Lett. 2024 Apr 16. doi: 10.1021/acs.nanolett.4c01036. Online ahead of print. Nano Lett. 2024. PMID: 38624236
Water electrolyzer with amorphous Pt/RuO(2) achieves 1.0 A cm(-2) at 1.70 V and remains stable at 200 mA cm(-2) for over 80 h. The amorphous Pt layer not only optimized the *O binding but also enhanced the antioxidation ability of amorphous Pt/RuO(2), thereby boosting the …
Water electrolyzer with amorphous Pt/RuO(2) achieves 1.0 A cm(-2) at 1.70 V and remains stable at 200 mA cm(-2) for over 80 h. The amorphous …
Oxygen vacancy engineering of ultra-small CuWO4 nanoparticles for boosting photocatalytic organic pollutant degradation.
Xiang D, Jin X, Sun G, Zhong C, Gao S. Xiang D, et al. Dalton Trans. 2024 Apr 16. doi: 10.1039/d4dt00628c. Online ahead of print. Dalton Trans. 2024. PMID: 38624191
Besides, oxygen vacancies could provide more reaction active sites, conducive to the adsorption and activation of dye molecules and H(2)O. Degradation experiments reveal that the optimized photocatalyst CuWO(4)-OVs 350 shows outstanding photocatalytic activity, and the rem …
Besides, oxygen vacancies could provide more reaction active sites, conducive to the adsorption and activation of dye molecules and H(2)O
Synthesis of alkenylphosphine oxides via Tf(2)O promoted addition-elimination of ketones and secondary phosphine oxides.
Ma J, Wang L, Qiao A, Li Z, Zhao F, Wu J. Ma J, et al. Org Biomol Chem. 2024 Apr 16. doi: 10.1039/d4ob00318g. Online ahead of print. Org Biomol Chem. 2024. PMID: 38624160
Herein, we describe an efficient method for the synthesis of alkenylphosphine oxides via a Tf(2)O promoted addition-elimination process. Various diarylphosphine oxides and alkylarylphosphine oxides react with ketones smoothly and produce alkenylphosphine oxides in moderate …
Herein, we describe an efficient method for the synthesis of alkenylphosphine oxides via a Tf(2)O promoted addition-elimination proce …
Ferromagnetic Insulating Ground-State Resolved in Mixed Protons and Oxygen Vacancies-Doped La0.67Sr0.33CoO3 Thin Films via Ionic Liquid Gating.
Wu M, Shi J, Sa N, Wu R, Deng T, Yang R, Zhang KHL, Han P, Wang HQ, Kang J. Wu M, et al. ACS Appl Mater Interfaces. 2024 Apr 16. doi: 10.1021/acsami.4c00724. Online ahead of print. ACS Appl Mater Interfaces. 2024. PMID: 38624095
Furthermore, a hitherto-unreported ferromagnetic insulating phase with a remarkably high T(c) up to 180 K has been observed which can be attributed to the doping of H(+) and the formation of oxygen vacancies (V(O)). The chemical formula of the dual-ion migrated film has be …
Furthermore, a hitherto-unreported ferromagnetic insulating phase with a remarkably high T(c) up to 180 K has been observed which can be att …
DMSO promoted catalyst-free oxidative C-N/C-O couplings towards synthesis of imidazoles and oxazoles.
Bera D, Sarkar R, Dhar T, Saha P, Ghosh P, Mukhopadhyay C. Bera D, et al. Org Biomol Chem. 2024 Apr 16. doi: 10.1039/d4ob00383g. Online ahead of print. Org Biomol Chem. 2024. PMID: 38624070
Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C-N coupling and C-O coupling under oxidant-free conditions are outlined. This protocol is operationally simple and leads to various functionalized substituted imidazoles or oxazoles in good yields. To date, a very …
Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C-N coupling and C-O coupling under oxidant-free conditions are outlined. …
Deep Electron Redistributions Induced by Dual Junctions Facilitating Electroreduction of Dilute Nitrate to Ammonia.
Zhang LH, Zhang B, Hong Y, You Y, Zhou Y, Zhan J, Alonzo Poole D 3rd, Yu F. Zhang LH, et al. Small. 2024 Apr 16:e2402430. doi: 10.1002/smll.202402430. Online ahead of print. Small. 2024. PMID: 38623987
Herein, a deep electronic state regulation is achieved by constructing a novel double-heterojunctional Co/Co(3)O(4)@NC catalyst containing Co/Co(3)O(4) and Co(3)O(4)/NC heterojunctions. ...Experimental and theoretical results reveal that the dual junctions of …
Herein, a deep electronic state regulation is achieved by constructing a novel double-heterojunctional Co/Co(3)O(4)@NC catalyst conta …
Ultrathin, Mechanically Durable, and Scalable Polymer-in-Salt Solid Electrolyte for High-Rate Lithium Metal Batteries.
Pan L, Feng S, Sun H, Liu XX, Yuan P, Cao M, Gao M, Wang Y, Sun Z. Pan L, et al. Small. 2024 Apr 16:e2400272. doi: 10.1002/smll.202400272. Online ahead of print. Small. 2024. PMID: 38623970
Polymer-in-salt solid-state electrolytes (PIS SSEs) are emerging for high room-temperature ionic conductivity and facile handling, but suffer from poor mechanical durability and large thickness. Here, Al(2)O(3)-coated PE (PE/AO) separators are proposed as robust and large- …
Polymer-in-salt solid-state electrolytes (PIS SSEs) are emerging for high room-temperature ionic conductivity and facile handling, but suffe …
Vascular Ehlers-Danlos Syndrome: A Comprehensive Natural History Study in a Dutch National Cohort of 142 Patients.
Demirdas S, van den Bersselaar LM, Lechner R, Bos J, Alsters SIM, Baars MJH, Baas AF, Baysal Ö, van der Crabben SN, Dulfer E, Giesbertz NAA, Helderman-van den Enden ATJM, Hilhorst-Hofstee Y, Kempers MJE, Komdeur FL, Loeys B, Majoor-Krakauer D, Ockeloen CW, Overwater E, van Tintelen PJ, Voorendt M, de Waard V, Maugeri A, Brüggenwirth HT, van de Laar IMBH, Houweling AC. Demirdas S, et al. Circ Genom Precis Med. 2024 Apr 16:e003978. doi: 10.1161/CIRCGEN.122.003978. Online ahead of print. Circ Genom Precis Med. 2024. PMID: 38623759
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