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Liquid-liquid miscibility gaps and hydrate formation in drug-water binary systems: pressure-temperature phase diagram of lidocaine and pressure-temperature-composition phase diagram of the lidocaine-water system.
Ceolin R, Barrio M, Tamarit JL, Veglio N, Perrin MA, Espeau P. Ceolin R, et al. Among authors: espeau p. J Pharm Sci. 2010 Jun;99(6):2756-65. doi: 10.1002/jps.22039. J Pharm Sci. 2010. PMID: 20039392
The pressure-temperature (P-T) melting curve of lidocaine was determined (dP/dT = 3.56 MPa K(-1)), and the lidocaine-water system was investigated as a function of temperature and pressure. ...The thermodynamic conditions of its stability were inferred from the location of …
The pressure-temperature (P-T) melting curve of lidocaine was determined (dP/dT = 3.56 MPa K(-1)), and the lidocaine-water system was …
Polymorphism of progesterone: relative stabilities of the orthorhombic phases I and II inferred from topological and experimental pressure-temperature phase diagrams.
Barrio M, Espeau P, Tamarit JL, Perrin MA, Veglio N, Ceolin R. Barrio M, et al. Among authors: espeau p. J Pharm Sci. 2009 May;98(5):1657-70. doi: 10.1002/jps.21541. J Pharm Sci. 2009. PMID: 18837014
With these results, a topological pressure-temperature (P-T) phase diagram accounting for the thermodynamic relationships between these phases has been constructed by way of the Clapeyron equation. ...It was found that, upon increasing the pressure, the melting curves conv …
With these results, a topological pressure-temperature (P-T) phase diagram accounting for the thermodynamic relationships between the …
Overall monotropic behavior of a metastable phase of biclotymol, 2,2'-methylenebis(4-chloro-3-methyl-isopropylphenol), inferred from experimental and topological construction of the related P-T state diagram.
Céolin R, Tamarit JL, Barrio M, López DO, Nicolaï B, Veglio N, Perrin MA, Espeau P. Céolin R, et al. Among authors: espeau p. J Pharm Sci. 2008 Sep;97(9):3927-41. doi: 10.1002/jps.21285. J Pharm Sci. 2008. PMID: 18200530
The melting curves, obtained from differential thermal analyses at various pressures ranging from 0 to 85 MPa, diverge as the pressure increases ((dP/dT)(fusI) = 2.54 +/- 0.07 MPa K(-1), (dP/dT)(fusII) = 5.14 +/- 0.85 MPa K(-1)). A topological P-T diagram with no stable ph …
The melting curves, obtained from differential thermal analyses at various pressures ranging from 0 to 85 MPa, diverge as the pressure incre …
Polymorphism of paracetamol: relative stabilities of the monoclinic and orthorhombic phases inferred from topological pressure-temperature and temperature-volume phase diagrams.
Espeau P, Céolin R, Tamarit JL, Perrin MA, Gauchi JP, Leveiller F. Espeau P, et al. J Pharm Sci. 2005 Mar;94(3):524-39. doi: 10.1002/jps.20261. J Pharm Sci. 2005. PMID: 15627255
This curve goes through the I-II-liquid triple point whose coordinates (p approximately 234 MPa, T approximately 505 K) correspond to the crossing point of the melting curves, for which dp/dT values of +3.75 MPa x K(-1) (I) and +3.14 MPa x K(-1) (II) were calculated from e …
This curve goes through the I-II-liquid triple point whose coordinates (p approximately 234 MPa, T approximately 505 K) correspond to …
Polymorphism of even-numbered carbon atom n-alkanes revisited through topological P-T diagrams.
Espeau P, Céolin R. Espeau P, et al. J Phys Chem B. 2008 Feb 21;112(7):2063-9. doi: 10.1021/jp0737348. Epub 2008 Jan 25. J Phys Chem B. 2008. PMID: 18217741
It is shown that the R(I) phase behaves monotropically whatever the pressure and temperature (i.e., the R(I) phase exhibits no stable pressure-temperature (P-T) region). Then, the incidence of the overall monotropic behavior of the R(I) phase on the construction of the tem …
It is shown that the R(I) phase behaves monotropically whatever the pressure and temperature (i.e., the R(I) phase exhibits no stable pressu …