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Page 1
What a difference a chlorine makes: The remarkable unimolecular ion chemistry of phenyl formate and phenyl chloroformate.
Lowe B, Cardona AL, Salas J, Bodi A, Mayer PM, Burgos Paci MA. Lowe B, et al. J Mass Spectrom. 2024 Feb;59(2):e5004. doi: 10.1002/jms.5004. J Mass Spectrom. 2024. PMID: 38311470
Imaging photoelectron photoion coincidence (iPEPICO) spectroscopy and tandem mass spectrometry were employed to explore the ionisation and dissociative ionisation of phenyl formate (PF) and phenyl chloroformate (PCF). The threshold photoelectron spectra of both comp …
Imaging photoelectron photoion coincidence (iPEPICO) spectroscopy and tandem mass spectrometry were employed to explore the ionisation and d …
Correlation of the rates of solvolysis of neopentyl chloroformate-a recommended protecting agent.
D'Souza MJ, Carter SE, Kevill DN. D'Souza MJ, et al. Int J Mol Sci. 2011 Feb 15;12(2):1161-74. doi: 10.3390/ijms12021161. Int J Mol Sci. 2011. PMID: 21541050 Free PMC article.
Linear free energy relationship (LFER) comparison of the specific rates of solvolysis of 1 with those for phenyl chloroformate and those for n-propyl chloroformate are helpful in the mechanistic considerations, as is also the treatment in terms of the Extended Grunw …
Linear free energy relationship (LFER) comparison of the specific rates of solvolysis of 1 with those for phenyl chloroformate
LFER Studies Evaluating Solvent Effects on an α-Chloro-and two β,β,β-Trichloro-Ethyl Chloroformate Esters.
D'Souza MJ, Sandosky B, Fernandez-Bueno GA, McAneny MJ, Kevill DN. D'Souza MJ, et al. Can Chem Trans. 2014 Feb 3;2(2):160-174. doi: 10.13179/canchemtrans.2014.02.02.0093. Can Chem Trans. 2014. PMID: 24812595 Free PMC article.
To provide insight and to identify the occurrence of mechanistic changes in relation to variance in solvent-type, the solvent effects on the rates of solvolysis of three substrates, 2,2,2-trichloro-1,1-dimethylethyl chloroformate, 2,2,2-trichloroethyl chloroformate, and 1-chloroe …
To provide insight and to identify the occurrence of mechanistic changes in relation to variance in solvent-type, the solvent effects on the …
Synthesis of Polyanionic Cellulose Carbamates by Homogeneous Aminolysis in an Ionic Liquid/DMF Medium.
Bui CV, Rosenau T, Hettegger H. Bui CV, et al. Molecules. 2022 Feb 18;27(4):1384. doi: 10.3390/molecules27041384. Molecules. 2022. PMID: 35209171 Free PMC article.
These intermediates were subjected to aminolysis, for which both the reactivity of different chloroformates towards C6-OH and the reactivity/suitability of the respective carbonate half-ester in the aminolysis were comprehensively studied. Phenyl chloroformate and 4 …
These intermediates were subjected to aminolysis, for which both the reactivity of different chloroformates towards C6-OH and the reactivity …
Direct synthesis of cyanate anion from dinitrogen catalysed by molybdenum complexes bearing pincer-type ligand.
Itabashi T, Arashiba K, Egi A, Tanaka H, Sugiyama K, Suginome S, Kuriyama S, Yoshizawa K, Nishibayashi Y. Itabashi T, et al. Nat Commun. 2022 Oct 24;13(1):6161. doi: 10.1038/s41467-022-33809-5. Nat Commun. 2022. PMID: 36280675 Free PMC article.
A molybdenum-carbamate complex bearing a pyridine-based 2,6-bis(di-tert-butylphosphinomethyl)pyridine (PNP)-pincer ligand is synthesized from the reaction of a molybdenum-nitride complex with phenyl chloroformate. The conversion between the molybdenum-carbamate comp …
A molybdenum-carbamate complex bearing a pyridine-based 2,6-bis(di-tert-butylphosphinomethyl)pyridine (PNP)-pincer ligand is synthesized fro …
Development of chiral thiourea catalysts and its application to asymmetric catalytic reactions.
Takemoto Y. Takemoto Y. Chem Pharm Bull (Tokyo). 2010 May;58(5):593-601. doi: 10.1248/cpb.58.593. Chem Pharm Bull (Tokyo). 2010. PMID: 20460782 Free article. Review.
We also discovered that multifunctional thiourea catalyst, bearing an 1,2-amino alcohol moiety, significantly accelerated the Petasis-type reaction of alkenylboronic acids to N-phenoxycarbonyl quinolinium salts, prepared from quinolines and phenyl chloroformate, to …
We also discovered that multifunctional thiourea catalyst, bearing an 1,2-amino alcohol moiety, significantly accelerated the Petasis-type r …
Indium mediated allylation of quinoline and isoquinoline activated by phenyl chloroformate.
Lee SH, Park YS, Nam MH, Yoon CM. Lee SH, et al. Org Biomol Chem. 2004 Aug 7;2(15):2170-2. doi: 10.1039/b405217j. Epub 2004 Jul 9. Org Biomol Chem. 2004. PMID: 15280950
Quinoline and isoquinoline activated by phenyl chloroformate were allylated using indium and allyl bromides in THF at room temperature to give the corresponding allyldihydroquinoline and allyldihydroisoquinoline in good to high yields....
Quinoline and isoquinoline activated by phenyl chloroformate were allylated using indium and allyl bromides in THF at room tem …
A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate.
D'Souza MJ, Darrington AM, Kevill DN. D'Souza MJ, et al. ISRN Org Chem. 2011;2011:767141. doi: 10.5402/2011/767141. ISRN Org Chem. 2011. PMID: 21666878 Free PMC article.
A plot of the rates of solvolysis of 1 against those previously reported for phenyl chloroformate (2) results in a correlation coefficient (R) of 0.996, a slope of 0.86, and an F-test value of 2161. ...
A plot of the rates of solvolysis of 1 against those previously reported for phenyl chloroformate (2) results in a correlation …
Influence of sulfur for oxygen substitution in the solvolytic reactions of chloroformate esters and related compounds.
D'Souza MJ, Kevill DN. D'Souza MJ, et al. Int J Mol Sci. 2014 Oct 10;15(10):18310-32. doi: 10.3390/ijms151018310. Int J Mol Sci. 2014. PMID: 25310653 Free PMC article.
The replacement of oxygen within a chloroformate ester (ROCOCl) by sulfur can lead to a chlorothioformate (RSCOCl), a chlorothionoformate (ROCSCl), or a chlorodithioformate (RSCSCl). Phenyl chloroformate (PhOCOCl) reacts over the full range of solvents usually inclu …
The replacement of oxygen within a chloroformate ester (ROCOCl) by sulfur can lead to a chlorothioformate (RSCOCl), a chlorothionoformate (R …
Synthesis of cellulose tricarbonates in 1-butyl-3-methylimidazolium chloride/pyridine.
Elschner T, Kötteritzsch M, Heinze T. Elschner T, et al. Macromol Biosci. 2014 Feb;14(2):161-5. doi: 10.1002/mabi.201300345. Epub 2013 Sep 20. Macromol Biosci. 2014. PMID: 24519785
Even cellulose phenyl carbonates with high degree of substitution are accessible at low molar ratio very efficiently. The reagent phenyl chloroformate is inert in the mixture, which is different from the solvent N,N-dimethylacetamide/LiCl that is usually applied. .. …
Even cellulose phenyl carbonates with high degree of substitution are accessible at low molar ratio very efficiently. The reagent phenyl
32 results