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Page 1
Kinetics, product distribution and atmospheric implications of the gas-phase oxidation of allyl sulfides by OH radicals.
Cardona AL, Gibilisco RG, Rivela CB, Blanco MB, Patroescu-Klotz I, Illmann N, Wiesen P, Teruel MA. Cardona AL, et al. Chemosphere. 2022 Feb;288(Pt 2):132546. doi: 10.1016/j.chemosphere.2021.132546. Epub 2021 Oct 12. Chemosphere. 2022. PMID: 34653479
Relative rate coefficients of the OH radical -initiated oxidation of allyl methyl sulfide (AMS, H(2)CCHCH(2)SCH(3)) and allyl ethyl sulfide (AES, H(2)CCHCH(2)SCH(2)CH(3)) have been measured at atmospheric pressure of synthetic air and 298 K: k(AMS)= (4 …
Relative rate coefficients of the OH radical -initiated oxidation of allyl methyl sulfide (AMS, H(2)CCHCH(2)SCH(3)) and allyl ethyl s …
Atmospheric Fate of a New Polyfluoroalkyl Building Block, C(3)F(7)OCHFCF(2)SCH(2)CH(2)OH.
Joudan S, Orlando JJ, Tyndall GS, Furlani TC, Young CJ, Mabury SA. Joudan S, et al. Environ Sci Technol. 2022 May 17;56(10):6027-6035. doi: 10.1021/acs.est.0c07584. Epub 2021 Apr 22. Environ Sci Technol. 2022. PMID: 33886306
Experiments performed in a stainless-steel chamber interfaced to an FTIR were used to determine reaction kinetics and gas-phase products. We report reaction rate constants of k(Cl + FESOH) = (1.5 0.6) 10(-11) cm(3) molecule(-1) s(-1) and k(OH + FESOH) = (4.2 2.0) 10 …
Experiments performed in a stainless-steel chamber interfaced to an FTIR were used to determine reaction kinetics and gas-phase products. We …
Characterization of human liver enzymes involved in the biotransformation of boceprevir, a hepatitis C virus protease inhibitor.
Ghosal A, Yuan Y, Tong W, Su AD, Gu C, Chowdhury SK, Kishnani NS, Alton KB. Ghosal A, et al. Drug Metab Dispos. 2011 Mar;39(3):510-21. doi: 10.1124/dmd.110.036996. Epub 2010 Dec 1. Drug Metab Dispos. 2011. PMID: 21123164
Boceprevir (SCH 503034), a protease inhibitor, is under clinical development for the treatment of human hepatitis C virus infections. ...
Boceprevir (SCH 503034), a protease inhibitor, is under clinical development for the treatment of human hepatitis C virus infections. …
Kinetics of acid-catalyzed O-atom transfer from a hydroperoxorhodium complex to organic and inorganic substrates.
Lemma K, Bakac A. Lemma K, et al. Inorg Chem. 2004 Oct 4;43(20):6224-7. doi: 10.1021/ic049421y. Inorg Chem. 2004. PMID: 15446867
The third-order rate constants were determined in aqueous solutions at 25 degrees C for (CH(2))(5)S (k = 430 M(-)(2) s(-)(1), micro = 0.10 M), (CH(2))(4)S(2) (182, micro = 0.10 M), CH(3)CH(2)SH (8.0, micro = 0.20 M), (en)(2)Co(SCH(2)CH(2)NH(2))(2+) (711, micro = 0.2 …
The third-order rate constants were determined in aqueous solutions at 25 degrees C for (CH(2))(5)S (k = 430 M(-)(2) s(-)(1), micro = …
Issues of microscopic reversibility and an isomeric intermediate in ligand substitution reactions of five-coordinate oxorhenium(V) dithiolate complexes.
Lahti DW, Espenson JH. Lahti DW, et al. J Am Chem Soc. 2001 Jun 27;123(25):6014-24. doi: 10.1021/ja004145h. J Am Chem Soc. 2001. PMID: 11414835
Ligand substitution reactions between five-coordinate oxorhenium(V) dithiolates, [CH(3)ReO(SCH(2)C(6)H(4)S)X], or MeReO(mtp)X, and entering ligands Y have been studied; Y is a phosphine and X is a phosphine (usually) or a pyridine. ...The structures of all the isolated pro …
Ligand substitution reactions between five-coordinate oxorhenium(V) dithiolates, [CH(3)ReO(SCH(2)C(6)H(4)S)X], or MeReO(mtp)X, and en …
Studies on the effect of SCH-34826 and thiorphan on [Met5]enkephalin levels and release in rat spinal cord.
Yaksh TL, Chipkin RE. Yaksh TL, et al. Eur J Pharmacol. 1989 Aug 29;167(3):367-73. doi: 10.1016/0014-2999(89)90445-7. Eur J Pharmacol. 1989. PMID: 2806377
SCH-34826 and thiorphan are inhibitors of the neutral endopeptidase (NEP; E.C. 3.4.24.11;) that cleaves the opiate peptides [Met5]- and [Leu5]enkephalin at the glycinylphenylalanine bond. These compounds were evaluated for their ability to affect the levels of [Met5]enkeph …
SCH-34826 and thiorphan are inhibitors of the neutral endopeptidase (NEP; E.C. 3.4.24.11;) that cleaves the opiate peptides [Met5]- a …