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A P-H functionalized Al/P-based frustrated Lewis pair - hydrophosphination of nitriles, ring opening with cyclopropenones and evidence of P[double bond, length as m-dash]C double bond formation.
Keweloh L , Aders N , Hepp A , Pleschka D , Würthwein EU , Uhl W . Keweloh L , et al. Dalton Trans. 2018 Jun 25;47(25):8402-8417. doi: 10.1039/c8dt01836g. Dalton Trans. 2018. PMID: 29893387
The unique reactivity of 7 became evident from its reactions with the heteroatom substituted nitriles PhO-C[triple bond, length as m-dash]N, PhCH2S-C[triple bond, length as m-dash]N and H8C4N-C[triple bond, length as m-dash]N. ...Diphenylcyclopropenone and it …
The unique reactivity of 7 became evident from its reactions with the heteroatom substituted nitriles PhO-C[triple bond, length as m- …