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Studies on the chirality of sulfoxidation catalyzed by bacterial flavoenzyme cyclohexanone monooxygenase and hog liver flavin adenine dinucleotide containing monooxygenase.
Light DR, Waxman DJ, Walsh C. Light DR, et al. Among authors: walsh c. Biochemistry. 1982 May 11;21(10):2490-8. doi: 10.1021/bi00539a031. Biochemistry. 1982. PMID: 7093199
The stereochemical outcome of oxygen transfer to the sulfur moiety of aryl alkyl sulfides catalyzed by two flavoenzyme monooxygenases has been determined by resolution of sulfoxide product enantionmers on a high-pressure liquid chromatography column [Pirkle, W. H., Finn, J. M. Sc …
The stereochemical outcome of oxygen transfer to the sulfur moiety of aryl alkyl sulfides catalyzed by two flavoenzyme monooxygenases has be …
Mechanistic studies with deuterated dihydroorotates on the dihydroorotate oxidase from Crithidia fasciculata.
Pascal RA Jr, Walsh CT. Pascal RA Jr, et al. Among authors: walsh ct. Biochemistry. 1984 Jun 5;23(12):2745-52. doi: 10.1021/bi00307a033. Biochemistry. 1984. PMID: 6087880
These substrates have been used with the FMN-containing biosynthetic dihydroorotate oxidase from Crithidia fasciculata [Pascal, R., Trang, N., Cerami, A., & Walsh, C. (1983) Biochemistry 22, 171] to probe stereochemistry and mechanism. ...When trideuterio (4RS)- …
These substrates have been used with the FMN-containing biosynthetic dihydroorotate oxidase from Crithidia fasciculata [Pascal, R., Trang, N …
Characteristics of beta, beta-difluoroalanine and beta, beta, beta -trifluoroalanine as suicide substrates for Escherichia coli B alanine racemase.
Wang EA, Walsh C. Wang EA, et al. Among authors: walsh c. Biochemistry. 1981 Dec 22;20(26):7539-46. doi: 10.1021/bi00529a032. Biochemistry. 1981. PMID: 7034778
The alanine racemase from Escherichia coli B has been shown to process DL isomers of beta -fluoroalanine as suicide substrates with an identical partitioning ratio for each enantiomer of 820 catalytic eliminations of HF per enzymatic inactivation event [Wang, E., & Walsh
The alanine racemase from Escherichia coli B has been shown to process DL isomers of beta -fluoroalanine as suicide substrates with an ident …
Cytochrome P-450 isozyme 1 from phenobarbital-induced rat liver: purification, characterization, and interactions with metyrapone and cytochrome b5.
Waxman DJ, Walsh C. Waxman DJ, et al. Among authors: walsh c. Biochemistry. 1983 Sep 27;22(20):4846-55. doi: 10.1021/bi00289a035. Biochemistry. 1983. PMID: 6626536
PB-1 was distinguished from the major PB-induced isozymes PB-4 and PB-5 [Waxman, D. J., & Walsh, C. (1982) J. Biol. Chem. 257, 10446-10457] by the absence of a Fe2+-metyrapone P446 complex, by its unique NH2-terminal sequence and distinct peptide maps, by the la …
PB-1 was distinguished from the major PB-induced isozymes PB-4 and PB-5 [Waxman, D. J., & Walsh, C. (1982) J. Biol. Chem. …
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